On the controls of mineral assemblages and textures in alkaline springs, Samail Ophiolite, Oman

Interactions between meteoric water and ultramafic rocks in the Oman Ophiolite generate waters of variable physicochemical characteristics. The discharge of these waters forms complex alkaline pool networks, in which mineral precipitation is triggered by mixing, evaporation, and uptake of atmospheric CO2. A systematic and colocalized sampling of waters and solids in two individual spring sites allowed us to determine the saturation state of a range of minerals and correlate them to the different water and precipitate types. We subdivided the waters of the spring sites into three distinctive types: i) Mg-type; moderately alkaline (7.9<pH<9.5), Mg2+–HCO3 −- rich waters, ii) Ca-type; hyperalkaline (pH>11.6), Ca2+–OH−-rich waters, and iii) Mix-type; alkaline to hyperalkaline (9.6 < pH < 11.5) waters with intermediate chemical composition. We first report the occurrence of hydrated magnesium (hydroxy-) carbonate phases in Mg-type waters. Nesquehonite forms in these waters via evaporation and transforms into dypingite and hydromagnesite under CO2-rich conditions. In Ca-type waters, the coupling of atmospheric CO2 uptake with evaporation leads to the formation of a calcitic crystalline crust on the air-water interface. The crusts are aragonite- and brucite-bearing, where Mg-type and Ca-type waters discharge and vigorously mix at the same pool. Unlike the Mg-type and Ca-type waters, the pools of Mix-type waters host massive aragonite-dominated deposits due to high Mg/Ca ratio that favors the growth of aragonite over calcite. The hydrodynamics during mixing spatially control brucite precipitation and restrict its formation and accumulation around specific mixing zones, where a continuous supply of Mg of inflowing Mg-type waters takes place. Crystal morphologies record the effect on the values of supersaturation and supersaturation rates in the pools due to mixing processes, evaporation and CO2 uptake. In Ca-type waters, CO2 uptake and evaporation dictate the textural characteristics of calcite both in crystalline crusts and rock coatings. Textural evolution of aragonite from crystalline sheaves to spheroidal shapes underlines the different supersaturation rates of calcium carbonate crystallization in flocculent material of Mix-type waters. Geochemical models of mixing between Mgtype and Ca-type waters revealed the evolution of mineral saturation indices under various mixing proportions, and their relation to the observed mineralogy and geochemistry of the pool waters. The thorough documentation of mineral assemblages and crystal morphologies enabled us to provide a more detailed account of how water composition, mixing, and mineral precipitation co-evolve in the alkaline spring systems, where CO2 is sequestered.The present research has been funded by the European Union Seventh Framework Programme FP7/2007-2013 under the FP7 People Program (Marie Curie Action– ITN “Abyss”) under REA grant agreement no. 608001, and the F7 Ideas: European Research Council grant PROMETHEUS under grant agreement no. 340863

Climate change and glacier retreat drive shifts in an Antarctic benthic ecosystem

The Antarctic Peninsula (AP) is one of the three places on Earth that registered the most intense warming in the last 50 years, almost five times the global mean. This warming has strongly affected the cryosphere, causing the largest ice-shelf collapses ever observed and the retreat of 87% of glaciers. Ecosystem responses, although increasingly predicted, have been mainly reported for pelagic systems. However, and despite most Antarctic species being benthic, responses in the Antarctic benthos have been detected in only a few species, and major effects at assemblage level are unknown. This is probably due to the scarcity of baselines against which to assess change. We performed repeat surveys of coastal benthos in 1994, 1998, and 2010, analyzing community structure and environmental variables at King George Island, Antarctica. We report a marked shift in an Antarctic benthic community that can be linked to ongoing climate change. However, rather than temperature as the primary factor, we highlight the resulting increased sediment runoff, triggered by glacier retreat, as the potential causal factor. The sudden shift from a “filter feeders–ascidian domination” to a “mixed assemblage” suggests that thresholds (for example, of tolerable sedimentation) and alternative equilibrium states, depending on the reversibility of the changes, could be possible traits of this ecosystem. Sedimentation processes will be increasing under the current scenario of glacier retreat, and attention needs to be paid to its effects along the AP

Thurston Island (West Antarctica) between Gondwana subduction and continental separation: a multi-stage evolution revealed by apatite thermochronology

The first low‐temperature thermochronological data from Thurston Island, West Antarctica, provide insights into the poorly constrained thermo‐tectonic evolution of the paleo‐Pacific margin of Gondwana since the Late Paleozoic. Here we present the first apatite fission track (AFT) and apatite (U‐Th‐Sm)/He (AHe) data from Carboniferous to mid‐Cretaceous (meta‐) igneous rocks from the Thurston Island area. Thermal history modeling of AFT dates of 145–92 Ma and AHe dates of 112–71 Ma, in combination with kinematic indicators, geological information and thermobarometrical measurements, indicate a complex thermal history with at least six episodes of cooling and reheating. Thermal history models are interpreted to reflect Late Paleozoic to Early Mesozoic tectonic uplift of pre‐Jurassic arc sequences, prior to the formation of an extensional Jurassic–Early Cretaceous back‐arc basin up to 4.5 km deep, which was deepened during intrusion and rapid exhumation of rocks of the Late Jurassic granite suite. Overall Early to mid‐Cretaceous exhumation and basin inversion coincided with an episode of intensive magmatism and crustal thickening and was followed by exhumation during formation of the Zealandia‐West Antarctica rift and continental break‐up. Final exhumation since the Oligocene was likely triggered by activity of the West Antarctic rift system and by glacial erosion

Benthic meltwater fjord habitats formed by rapid glacier recession on King George Island, Antarctica

The coasts of West Antarctic Peninsula are strongly influenced by glacier meltwater discharge. The spatial structure and biogeochemical composition of inshore habitats is shaped by large quantities of terrigenous particulate material deposited in the vicinity of the coast, which impacts the pelagic and benthic ecosystems. We used a multitude of geochemical and environmental variables to identify the radius extension of meltwater impact of Fourcade Glacier into the fjord system of Potter Cove, King George Island. K-means cluster algorithm, canonical correspondence analysis, variance analysis and post-hoc Tukey's multiple comparison test were applied to define and cluster coastal meltwater habitats. A minimum of 10 clusters was needed to classify the 8 km2 study area into meltwater fjord habitats (MFH), fjord habitats and marine habitats. Strontium content in surface sediments is the main geochemical indicator for lithogenic creek discharge in Potter Cove. Furthermore, bathymetry, glacier distance and geomorphic positioning are the essential habitat explaining variables. Mean and maximum MFH extent amounted to 1 km and 2 km, respectively. Extrapolation of the identified meltwater impact ranges to King George Island coastlines which are presently ice-covered bays and fjord areas indicate an overall coverage of 200–400 km2 MFH, underpinning the importance to better understand the biology and biogeochemistry in terrestrial marine transition zones

Impurity-Induced Quasiparticle Transport and Universal Limit Wiedemann-Franz Violation in d-Wave Superconductors

Due to the node structure of the gap in a d-wave superconductor, the presence of impurities generates a finite density of quasiparticle excitations at zero temperature. Since these impurity-induced quasiparticles are both generated and scattered by impurities, prior calculations indicate a universal limit (\Omega -> 0, T -> 0) where the transport coefficients obtain scattering-independent values, depending only on the velocity anisotropy v_f/v_2. We improve upon prior results, including the contributions of vertex corrections and Fermi liquid corrections in our calculations of universal limit electrical, thermal, and spin conductivity. We find that while vertex corrections modify electrical conductivity and Fermi liquid corrections renormalize both electrical and spin conductivity, only thermal conductivity maintains its universal value, independent of impurity scattering or Fermi liquid interactions. Hence, low temperature thermal conductivity measurements provide the most direct means of obtaining the velocity anisotropy for high T_c cuprate superconductors.Comment: 22 pages, 6 figures; revised version to be published in Phys Rev

Microwave Conductivity due to Scattering from Extended Linear Defects in d-Wave Superconductors

Recent microwave conductivity measurements of detwinned, high-purity, slightly overdoped YBa$_{2}$Cu$_{3}$O$_{6.993}$ crystals reveal a linear temperature dependence and a near-Drude lineshape for temperatures between 1 and 20 K and frequencies ranging from 1 to 75 GHz. Prior theoretical work has shown that simple models of scattering by point defects (impurities) in d-wave superconductors are inconsistent with these results. It has therefore been suggested that scattering by extended defects such as twin boundary remnants, left over from the detwinning process, may also be important. We calculate the self-energy and microwave conductivity in the self-consistent Born approximation (including vertex corrections) for a d-wave superconductor in the presence of scattering from extended linear defects. We find that in the experimentally relevant limit ($\Omega, 1/\tau \ll T \ll \Delta_{0}$), the resulting microwave conductivity has a linear temperature dependence and a near-Drude frequency dependence that agrees well with experiment.Comment: 13 pages, 7 figure