Synthesis and Characterization of Large Stereoregular Organosiloxane Cycles

The large stereoregular phenyltrimethylsiloxysiloxane macrocycles of general formula [PhSi(OSiMe3)O]n (n=6 and 12) have been selectively obtained with high yields by trimethylsilylation of cage-like oligophenylmetallasiloxanes (OPMS) which we described earlier. The compounds 3 (n=6) and 4 (n=12) have been characterized by NMR-spectroscopy method and by single crystal X-ray analysis. This investigation showed unambiguously that the siloxane macrocycles keep their size and configuration (the same as in the initial OPMS) during the trimethylsilylation. Thus a synthetic route for obtaining large stereoregular siloxane macrocycles has been developed

Phylogenetics and Mitogenome Organisation in Black Corals (Anthozoa: Hexacorallia: Antipatharia): An Order-Wide Survey Inferred From Complete Mitochondrial Genomes

Black corals (Anthozoa: Antipatharia) are an ecologically and culturally important group of deep-sea cnidarians. However, as the majority of species inhabit depths >50 m, they are relatively understudied. The inaccessibility of well-preserved tissue for species of interest has limited the scope of molecular analysis, and as a result only a small number of antipatharian mitochondrial genomes have been published. Using next generation sequencing, 18 complete and five partial antipatharian mitochondrial genomes were assembled, increasing the number of complete mitochondrial genomes to 22. This includes species from six antipatharian families, four of which were previously unrepresented, enabling the first family-level, full mitochondrial gene analysis over the whole order. The circular mitogenomes ranged in size from 17,681 to 21,669 bp with the large range in size due to the addition of an intron in COX1 in some species and size variation of intergenic regions. All mitogenomes contained the genes standard to all hexacoral mitogenomes (13 protein coding genes, two rRNAs and two tRNAs). The only difference in gene content is the presence of the COX1 intron in five families. The most variable mitochondrial gene is ND4 which may have implications for future barcoding studies. Phylogenetic analysis confirms that Leiopathidae is sister to all other families. Families Antipathidae, Cladopathidae and Schizopathidae are polyphyletic, supporting previous studies that call for a taxonomic revision

Torsional nodeless vibrations of quaking neutron star restored by combined forces of shear elastic and magnetic field stresses

Within the framework of Newtonian magneto-solid-mechanics, relying on equations appropriate for a perfectly conducting elastic continuous medium threaded by a uniform magnetic field, the asteroseismic model of a neutron star undergoing axisymmetric global torsional nodeless vibrations under the combined action of Hooke's elastic and Lorentz magnetic forces is considered with emphasis on a toroidal Alfv\'en mode of differentially rotational vibrations about the dipole magnetic moment axis of the star. The obtained spectral equation for frequency is applied to $\ell$-pole identification of quasi-periodic oscillations (QPOs) of X-ray flux during the giant flares of SGR 1806-20 and SGR 1900+14. Our calculations suggest that detected QPOs can be consistently interpreted, within the framework of this model, as produced by global torsional nodeless vibrations of quaking magnetar if they are considered to be restored by the joint action of bulk forces of shear elastic and magnetic field stresses.Comment: 18 pages, 5 figures; accepted in Ap

One-step synthesis of γ-Fe₂ O₃/Fe₃ O₄ nanocomposite for sensitive electrochemical detection of hydrogen peroxide

Maghemite/magnetite nanocomposite ( γ-Fe₂ O₃/Fe₃ O₄ ) was prepared via an electrochemical method using pulse alternating current and applied for electrocatalytic reduction and sensing of hydrogen peroxide. The structural and compositional analysis of the γ-Fe₂ O₃/Fe₃ O₄ was characterized by XRD, SEM, TEM and XPS. Its thermal decomposition behavior was studied using TG/DSC. The mechanism for γ- Fe₂ O₃/Fe₃ O₄ nanocomposite formation was propose

Atomic and electronic structure of nanostructured few-layer graphene with self-aligned boundaries synthesized on SiC/Si(001) wafers

This work was partially supported by the Russian Academy of Sciences, Russian Foundation for Basic Research (grant № 17-02-01139, 17-02-01291), Beijing Institute of Technology Research Fund Program for Young Scholars, and Science Foundation Ireland

Transport properties of copper phthalocyanine based organic electronic devices

Ambipolar charge carrier transport in Copper phthalocyanine (CuPc) is studied experimentally in field-effect transistors and metal-insulator-semiconductor diodes at various temperatures. The electronic structure and the transport properties of CuPc attached to leads are calculated using density functional theory and scattering theory at the non-equilibrium Green's function level. We discuss, in particular, the electronic structure of CuPc molecules attached to gold chains in different geometries to mimic the different experimental setups. The combined experimental and theoretical analysis explains the dependence of the mobilityand the transmission coefficient on the charge carrier type (electrons or holes) and on the contact geometry. We demonstrate the correspondence between our experimental results on thick films and our theoretical studies of single molecule contacts. Preliminary results for fluorinated CuPc are discussed.Comment: 18 pages, 16 figures; to be published in Eur. Phys. J. Special Topic

Особенности организации помощи и диспансерное наблюдение взрослых, больных муковисцидозом

Based on the long-term surveillance of 127 patients older than 15 yrs and 173 children aged 3 months to 15 yrs we concluded of the survival age of cystic fibrosis patients in Russia (16.9 ±1.1 yrs). Patients older than 15 yrs take 30.1 % of all the investigated patients. Under the adequate surveillance and treatment conditions 82.4 % of adult patients keep their social activity and only 17.6 % of the patients do not work and do not study.На основании многолетнего наблюдения за 127 пациентами старше 15 лет и 173 детьми в возрасте от 3 мес. до 15 лет делаются выводы о возрасте выживаемости больных муковисцидозом в России (16,9 ± 1,1 год), лица старше 15 лет среди всех обследованных составляют 30,1 % . При правильно организованном диспансерном наблюдении и лечении 82,4 % взрослых сохраняют социальную активность и только 17,6 % не работают и не учатся

Frequency spectrum of toroidal Alfv\'en mode in a neutron star with Ferraro's form of nonhomogeneous poloidal magnetic field

Using the energy variational method of magneto-solid-mechanical theory of a perfectly conducting elastic medium threaded by magnetic field, the frequency spectrum of Lorentz-force-driven global torsional nodeless vibrations of a neutron star with Ferraro's form of axisymmetric poloidal nonhomogeneous internal and dipole-like external magnetic field is obtained and compared with that for this toroidal Alfv\'en mode in a neutron star with homogeneous internal and dipolar external magnetic field. The relevance of considered asteroseismic models to quasi-periodic oscillations of the X-ray flux during the ultra powerful outbursts of SGR 1806-20 and SGR 1900+14 is discussed.Comment: Accepted for publication in Astrophysics & Space Scienc