98 research outputs found

    Instrumentation of sprint and long jump tracks of an indoor athletics field to study athletes’ performances

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    Introduction: The in-depth study of the performances of athletes is crucial to evaluate and improve their technique. However, collecting representative data is not trivial, as several factors could affect the measurements. Laboratory measurements can lack in realism (artificial environment, athlete’s lack of challenge), whereas data collected in-field using on-board devices can be influenced by the instrumentation itself (weight, encumbrance) [1-2]. The aim of this work is the design of an instrumented track, which will allow to collect kinematic and kinetic data of able bodied and paralimpic athletes in their natural environment, ensuring that the influence of the sensory apparatus is negligible. Methods: The instrumentation set-up of the indoor athletics track of Padova (Padova, 35136, Italy) is represented in the plan view of figure 1a. Seven 60x90 cm and two 40x60 cm force platforms (AMTI, BMS600900 and BMS400600) will be installed following the disposition depicted in figure 1b on the eighth lane of the sprint track, leading to a total of 6.9 metres of force sensing lane. The two smaller force platforms will be installed side-by-side to allow the possibility of mounting one single starting block on each force transducer to collect separate right and left ground reaction forces during the starting phase of sprinting. An additional 60x90 cm force platform will be installed on the long jump track at 1.6 metres from the sand pit in order to collect the last step of the athlete before the flight phase of the long jump (figure 1c). Kinematic data will be collected using 10 optoelectronic motion capture cameras (Vicon, Vantage5), which will be installed on a double portal structure made of aluminium trusses with an overall size of 13 x 7 x 3.5 metres (length x width x height). The structure size allows more than one athlete to run simultanesously, in order to recreate the “challenge effect” typical of official races. Compared to other motion capture mounting solutions, such as using tripods to support each individual camera [3], the use of this single support structure offers the advantage of allowing to rigidly translate the motion capture calibrated volume in different part of the athletics field using wheels. This feature reduces drastically the set-up time of the motion capture system, particularly when the data collection focus has to be moved between the sprint and the long jump area. Moreover, this structure allows to avoid the presence of any cable on the track, as wires will pass through the trusses and descend via the vertical columns. Results and discussion: The design of the sensorized athletics track is complete and the installation of the instrumentation will take place in the next few months. This track will allow to collect insightfull in-field data regarding able bodied and paralimpic athletes performances outside the laboratory environment. Examples of these data will be presented in June at the ISEA 2022 conference

    effect of environmental conditions on the durability of polycarbonate for the protection of cultural heritage sites

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    Polycarbonate is a good material for covering and protecting cultural heritage sites because of its durability, mechanical properties, and transparency. However, polycarbonate degrades under environmental weathering with a significant decrease of physical and mechanical properties and loss of transparency. In this work, the contemporary presence of ultraviolet irradiation and different temperature and moisture conditions have been taken into account to study the environmental degradation of this polymer with regard to its mechanical and optical properties. The photo-oxidation reactions cause a decrease in the molecular weight and the formation of many oxygenated species. The hydrolytic scission, instead, gives rise to a remarkable reduction in the molecular weight. These two different degradation mechanisms do not seem interconnected because at the lowest degradation temperature and high humidity levels, the reduction of the molecular weight is more pronounced than that observed at the highest temperature but at a lower humidity level. Transparency decreases with the degradative processes, but even after severe degradation the loss of transparency is only about 10%. The yellowness index increases during the first stages of degradation, which has been attributed to the fast formation of carbonyl groups due to photo-oxidation

    effect of cold drawing on mechanical properties of biodegradable fibers

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    The use of biodegradable polymers is increasingly attracting interest over the last years, since they can reduce the environmental effects related to disposal of traditional plastics and, in general, the use of fossil, non-renewable resources. One of the most promising applications is represented by fibers production. However, the orientation and the crystallinity degrees can significantly affect the mechanical properties. Therefore, it is of interest to investigate on the optimum processing conditions, in order to improve the mechanical properties. In particular, while crystallinity can be slightly modified by the processing, orientation can be significantly improved. In this work, the effects of hot stretching on the mechanical and structural properties of fibers made from two different families of biodegradable blends were investigated. The orientation proved to significantly change the mechanical properties, and it was shown that factors such as the different relaxation times, the different crystallization temperatures and the cooling rate can give opposite effects in the three investigated polymer systems with significant consequences on the mechanical behaviour of the fibers. In particular, the behaviour during fiber production in hot stretching, and the orientation mechanisms were studied and explained on the basis of rheological and thermal properties of the polymers

    Compatibilization of Polypropylene/Polyamide 6 Blend Fibers Using Photo-Oxidized Polypropylene

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    The use of polyamide/polyolefin blends has gained importance and concern for years, but they also show some issues to be adequately addressed, such as the incompatibility between the two components. This is usually overcome by using suitable compatibilizers, typically based on functionalized polyolefins. However, there is only little information about the use of a degraded polyolefins to induce compatibilization. This is even truer, as far as polyamide 6/polypropylene (PA6/PP) blends are concerned. In this work, compatibilization of PA6/PP blends by using small amounts of photo-oxidized PP was investigated; furthermore, the effects due to the presence of the photo-oxidized PP were studied also in relationship to the spinning operation, where the existence of the non-isothermal elongational flow can lead to significant, further morphological changes. It was found that isotropic samples showed significant enhancements of the tensile properties upon adding the photo-oxidized PP. Under non-isothermal elongational flow conditions, the presence of the photo-oxidized PP was particularly effective in improving the mechanical properties in comparison to the uncompatibilized blend fibers. Furthermore, an important result was found: The elongational-flow processing allowed obtaining anisotropic samples where the improvements of the properties, in comparison to the isotropic samples, were similar to those achieved by using a compatibilizer

    Effect of a compatibilizer on the morphology and properties of polypropylene/polyethylentherephthalate spun fibers

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    Fibers spun by melt spinning of binary and ternary polypropylene/ polyethylenetherephthalate blends have been produced and characterized in order to investigate the effect of a compatibilizer on their morphology and mechanical properties. The compatibilizer was a maleic anhydride-functionalized rubber copolymer. The effect of the compatibilizer was well evident in the isotropic state, as the morphology became very fine, the size of the dispersed particles was very small, and the adhesion was better. The effect of the compatibilizer on the mechanical properties is very relevant, especially in the elongation at break. On the contrary, no relevant effect was observed in the anisotropic oriented fibers. Although the average diameter of the microfibrils of the dispersed phase of the compatibilized blend generated during the hot drawing was much smaller than that of the microfibrils of the same particles of the uncompatibilized blend, the mechanical properties were almost the same. This behavior has been attributed to the length of the smaller microfibrils of the ternary blends, which was lower that of the microfibrils of the binary blend. This has been explained in terms of reduced initial droplet size, and therefore of lesser possibility of stretching the droplets to very long fibrils in these samples

    Mechanical, thermomechanical and reprocessing behavior of green composites from biodegradable polymer and wood flour

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    The rising concerns in terms of environmental protection and the search for more versatile polymer-based materials have led to an increasing interest in the use of polymer composites filled with natural organic fillers (biodegradable and/or coming from renewable resources) as a replacement for traditional mineral inorganic fillers. At the same time, the recycling of polymers is still of fundamental importance in order to optimize the utilization of available resources, reducing the environmental impact related to the life cycle of polymer-based items. Green composites from biopolymer matrix and wood flour were prepared and the investigation focused on several issues, such as the effect of reprocessing on the matrix properties, wood flour loading effects on virgin and reprocessed biopolymer, and wood flour effects on material reprocessability. Tensile, Dynamic-mechanical thermal (DMTA), differential scanning calorimetry (DSC) and creep tests were performed, pointing out that wood flour leads to an improvement of rigidity and creep resistance in comparison to the pristine polymer, without compromising other properties such as the tensile strength. The biopolymer also showed a good resistance to multiple reprocessing; the latter even allowed for improving some properties of the obtained green composites

    Climate Change Impact on Corrosion of Reinforced Concrete Bridges and Their Seismic Performance

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    As a consequence of climate change impact, a significant variation in terms of temperature, atmospheric humidity, and carbon dioxide concentration levels is happening. This condition leads to several negative effects on the safety and the life cycle of existing concrete structures, such as the increase in the rate of material degradation, due to corrosion phenomena. In fact, the presence of carbonation and corrosion phenomena significantly influence the load-bearing capacity of existing reinforced concrete (RC) structures, under both static and dynamic loads. Among the wide range of existing RC constructions, bridges stand out for their importance. Furthermore, as structures directly exposed to the weather effects, they are more susceptible to these phenomena. In this paper, the influence of corrosion on existing RC motorway viaducts’ seismic behavior, considering the impact of climate change, is investigated, by means of an efficient procedure based on the implementation of 3D simplified finite element models and the use of analytical relations to obtain the amount of reduction in the steel reinforcement area as a function of the age of the bridge and of the different corrosion scenarios analyzed. Several scenarios for the expected variations in CO2 concentrations, temperature, and relative humidity are evaluated, considering that most of the viaducts present in the Italian motorway network were built between the 1960s and the 1970s. The results obtained using the projection of climate change impacts are compared with those calculated considering the corrosion scenarios resulting from the DuraCrete research project, to understand if the evolution of climate change leads to worse scenarios than those previously assessed

    Structure–property relationships in bionanocomposites for pipe extrusion applications

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    In this work, bionanocomposites based on different biodegradable polymers and two types of nanofillers, namely a nanosized calcium carbonate and an organomodified nanoclay, were produced through melt extrusion, with the aim to evaluate the possible applications of these materials as a potential alternative to traditional fossil fuel-derived polyolefins, for the production of irrigation pipes. The rheological behavior of the formulated systems was thoroughly evaluated by exploiting different flow regimes, and the obtained results indicated a remarkable effect of the introduced nanofillers on the low-frequency rheological response, especially in nanoclay-based bionanocomposites. Conversely, the shear viscosity at a high shear rate was almost unaffected by the presence of both types of nanofillers, as well as the rheological response under nonisothermal elongational flow. In addition, the analysis of the mechanical properties of the formulated materials indicated that the embedded nanofillers increased the elastic modulus when compared to the unfilled counterparts, notwithstanding a slight decrease of the material ductility. Finally, the processing behavior of unfilled biopolymers and bionanocomposites was evaluated, allowing for selecting the most suitable material and thus fulfilling the processability requirements for pipe extrusion applications

    Bionanocomposite blown films: insights on the theological and mechanical behavior

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    In this work, bionanocomposites based on two different types of biopolymers belonging to the MaterBi® family and containing two kinds of modified nanoclays were compounded in a twin-screw extruder and then subjected to a film blowing process, aiming at obtaining sustainable films potentially suitable for packaging applications. The preliminary characterization of the extruded bionanocomposites allowed establishing some correlations between the obtained morphology and the material rheological and mechanical behavior. More specifically, the morphological analysis showed that, regardless of the type of biopolymeric matrix, a homogeneous nanofiller dispersion was achieved; furthermore, the established biopolymer/nanofiller interactions caused a restrain of the dynamics of the biopolymer chains, thus inducing a significant modification of the material rheological response, which involves the appearance of an apparent yield stress and the amplification of the elastic feature of the viscoelastic behavior. Besides, the rheological characterization under non-isothermal elongational flow revealed a marginal effect of the embedded nanofillers on the biopolymers behavior, thus indicating their suitability for film blowing processing. Additionally, the processing behavior of the bionanocomposites was evaluated and compared to that of similar systems based on a low-density polyethylene matrix: this way, it was possible to identify the most suitable materials for film blowing operations. Finally, the assessment of the mechanical properties of the produced blown films documented the potential exploitation of the selected materials for packaging applications, also at an industrial level

    Three vs. Four Cycles of Neoadjuvant Chemotherapy for Localized Muscle Invasive Bladder Cancer Undergoing Radical Cystectomy: A Retrospective Multi-Institutional Analysis

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    Three or four cycles of cisplatin-based chemotherapy is the standard neoadjuvant treatment prior to cystectomy in patients with muscle-invasive bladder cancer. Although NCCN guidelines recommend 4 cycles of cisplatin-gemcitabine, three cycles are also commonly administered in clinical practice. In this multicenter retrospective study, we assessed a large and homogenous cohort of patients with urothelial bladder cancer (UBC) treated with three or four cycles of neoadjuvant cisplatin-gemcitabine followed by radical cystectomy, in order to explore whether three vs. four cycles were associated with different outcomes
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