6,584 research outputs found
Polymer Dissolution Model: An Energy Adaptation Of The Critical Ionization Theory
The current scale of features size in the microelectronics industry has reached the point where molecular level interactions affect process fidelity and produce excursions from the continuum world like line edge roughness (LER). Here we present a 3D molecular level model based on the adaptation of the critical ionization (CI) theory using a fundamental interaction energy approach. The model asserts that it is the favorable interaction between the ionized part of the polymer and the developer solution which renders the polymer soluble. Dynamic Monte Carlo methods were used in the current model to study the polymer dissolution phenomenon. The surface ionization was captured by employing an electric double layer at the interface, and polymer motion was simulated using the Metropolis algorithm. The approximated interaction parameters, for different species in the system, were obtained experimentally and used to calibrate the simulated dissolution rate response to polymer molecular weight and developer concentration. The predicted response is in good agreement with experimental dissolution rate data. The simulation results support the premise of the CI theory and provide an insight into the CI model from a new prospective. This model may provide a means to study the contribution of development to LER and other related defects based on molecular level interactions between distinct components in the polymer and the developer.Chemical Engineerin
PEPSI deep spectra. III. A chemical analysis of the ancient planet-host star Kepler-444
We obtained an LBT/PEPSI spectrum with very high resolution and high
signal-to-noise ratio (S/N) of the K0V host Kepler-444, which is known to host
5 sub-Earth size rocky planets. The spectrum has a resolution of R=250,000, a
continuous wavelength coverage from 4230 to 9120A, and S/N between 150 and
550:1 (blue to red). We performed a detailed chemical analysis to determine the
photospheric abundances of 18 chemical elements, in order to use the abundances
to place constraints on the bulk composition of the five rocky planets. Our
spectral analysis employs the equivalent width method for most of our spectral
lines, but we used spectral synthesis to fit a small number of lines that
require special care. In both cases, we derived our abundances using the MOOG
spectral analysis package and Kurucz model atmospheres. We find no correlation
between elemental abundance and condensation temperature among the refractory
elements. In addition, using our spectroscopic stellar parameters and isochrone
fitting, we find an age of 10+/-1.5 Gyr, which is consistent with the
asteroseismic age of 11+/-1 Gyr. Finally, from the photospheric abundances of
Mg, Si, and Fe, we estimate that the typical Fe-core mass fraction for the
rocky planets in the Kepler-444 system is approximately 24 per cent. If our
estimate of the Fe-core mass fraction is confirmed by more detailed modeling of
the disk chemistry and simulations of planet formation and evolution in the
Kepler-444 system, then this would suggest that rocky planets in more
metal-poor and alpha-enhanced systems may tend to be less dense than their
counterparts of comparable size in more metal-rich systems.Comment: in press, 11 pages, 3 figures, data available from pepsi.aip.d
Small ruminant production under pressure: The example of goats in southeast Nigeria
Presents preliminary assessment of animals' performance under a free-roaming and movement-restricted production system and farmers' responses to changed husbandry practices in southeast Nigeria; with particular reference to flock dynamics & male to female ratio; reproductive performance; growth rate; mortality; and farmers management & breeding strategy
Phonon driven spin distribution due to the spin-Seebeck effect
Here we report on measurements of the spin-Seebeck effect of GaMnAs over an
extended temperature range alongside the thermal conductivity, specific heat,
magnetization, and thermoelectric power. The amplitude of the spin-Seebeck
effect in GaMnAs scales with the thermal conductivity of the GaAs substrate and
the phonon-drag contribution to the thermoelectric power of the GaMnAs,
demonstrating that phonons drive the spin redistribution. A phenomenological
model involving phonon-magnon drag explains the spatial and temperature
dependence of the measured spin distribution.Comment: 12 pages, 3 figure
Drift and Diffusion of Spins Generated by the Spin Hall Effect
Electrically generated spin accumulation due to the spin Hall effect is
imaged in n-GaAs channels using Kerr rotation microscopy, focusing on its
spatial distribution and time-averaged behavior in a magnetic field.
Spatially-resolved imaging reveals that spin accumulation observed in
transverse arms develops due to longitudinal drift of spin polarization
produced at the sample boundaries. One- and two-dimensional drift-diffusion
modeling is used to explain these features, providing a more complete
understanding of observations of spin accumulation and the spin Hall effect.Comment: 9 pages, 3 figure
Optical frequency combs from high-order sideband generation
We report on the generation of frequency combs from the recently-discovered
phenomenon of high-order sideband generation (HSG). A near-band gap
continuous-wave (cw) laser with frequency was transmitted
through an epitaxial layer containing GaAs/AlGaAs quantum wells that were
driven by quasi-cw in-plane electric fields between 4 and 50
kV/cm oscillating at frequencies between 240 and 640 GHz.
Frequency combs with teeth at
( even) were produced, with maximum reported , corresponding to a
maximum comb span THz. Comb spectra with the identical product
were found to have similar spans and shapes
in most cases, as expected from the picture of HSG as a scattering-limited
electron-hole recollision phenomenon. The HSG combs were used to measure the
frequency and linewidth of our THz source as a demonstration of potential
applications
Terahertz electron-hole recollisions in GaAs/AlGaAs quantum wells: robustness to scattering by optical phonons and thermal fluctuations
Electron-hole recollisions are induced by resonantly injecting excitons with
a near-IR laser at frequency into quantum wells driven by a
~10 kV/cm field oscillating at THz. At K, up to
18 sidebands are observed at frequencies , with . Electrons and holes recollide with
total kinetic energies up to 57 meV, well above the meV
threshold for longitudinal optical (LO) phonon emission. Sidebands with order
up to persist up to room temperature. A simple model shows that LO
phonon scattering suppresses but does not eliminate sidebands associated with
kinetic energies above .Comment: 5 pages, 4 figure
Electrical spin protection and manipulation via gate-locked spin-orbit fields
The spin-orbit (SO) interaction couples electron spin and momentum via a
relativistic, effective magnetic field. While conveniently facilitating
coherent spin manipulation in semiconductors, the SO interaction also
inherently causes spin relaxation. A unique situation arises when the Rashba
and Dresselhaus SO fields are matched, strongly protecting spins from
relaxation, as recently demonstrated. Quantum computation and spintronics
devices such as the paradigmatic spin transistor could vastly benefit if such
spin protection could be expanded from a single point into a broad range
accessible with in-situ gate-control, making possible tunable SO rotations
under protection from relaxation. Here, we demonstrate broad, independent
control of all relevant SO fields in GaAs quantum wells, allowing us to tune
the Rashba and Dresselhaus SO fields while keeping both locked to each other
using gate voltages. Thus, we can electrically control and simultaneously
protect the spin. Our experiments employ quantum interference corrections to
electrical conductivity as a sensitive probe of SO coupling. Finally, we
combine transport data with numerical SO simulations to precisely quantify all
SO terms.Comment: 5 pages, 4 figures (color), plus supplementary information 18 pages,
8 figures (color) as ancillary arXiv pd
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