Characterization of Doum Palm Seed Kernel as Natural Sorbent for Metal Ions Removal from Gombe Ternary Wastewater

Water pollution is one of the major challenges in cities and industrialized areas of the world. The effluent from Gombe ternary wastewater pollutes the surrounding waters thereby constituting health threat to the populace within its vicinity. In view of the above, a bio-sorption study of zinc and lead ions from Gombe ternary wastewater using doum palm seed kernel was carried out. The wastewater was characterized and was found to contain 0.03 mg/l lead metal ion and 0.81 mg/l zinc ion. The doum palm kernel bio-sorbent was obtained after oil extraction from the seed and processed as contained in the method mentioned in this paper. The kernel residue was characterized for functional groups using FTIR, surface morphology using SEM, surface area using BET, and elemental composition using XRF. The results indicated that the doum palm kernel is harmless, and possesses functional groups on its surface, which may be substituted with the metallic ions present in the wastewater. This gives the kernel the ability to adsorb positively charged ions on its surface by simple chemisorption. This mechanism is supported by the rough surface observed in the scanning electron microscopy. Adsorption and desorption of nitrogen was made at STP and the curve indicated very high correlation of close to unity. The surface area measured by multi BET method was recorded as 13.464 m2/g. This value is not high enough to adsorb metals by physical adsorption

Fourier Transform Infrared Spectroscopy and Scanning Electron Microscopy Characterization of Adhesive Produced From Polystyrene Waste

In this study, the optimized adhesive formulated from polystyrene waste was characterized for Fourier transform infrared (FTIR) spectra, Scanning Electron Microscopy (SEM) / Energy Dispersive X-ray (EDX) spectroscopy, solubility, density and water absorption for identification of existing functional group(s), morphology, elemental compositions, etc. The results revealed that polystyrene, unsaturated hydrocarbon has been degraded to form a new product containing aromatic compounds. SEM morphology showed well mixed blended adhesive with silver-like appearance due to additives and EDX revealed 12 existing elemental compositions with their corresponding percentage atomic weights as follows; carbon 93.14 %, hafnium 1.44 %, vanadium 1.66 %, chromium 1.40 %, bromine 0.47 %, palladium 0.26 %, copper 0.43 %, nickel 0.31 %, cobalt 0.29 %, potassium 0.38 %, iron 0.15 % and manganese 0.08 %. The produced polystyrene adhesive was sparsely soluble in water after 30 minutes; it has a density of 1041 kg/m3 and does not absorb moisture. Because of these results, the adhesive from polystyrene waste could serve as green adhesive, since there are no threats of toxic substance emission from the spectral analysis since most of the elements are used as a supplement in pharmaceuticals and catalyst in process industries

Bio-Fertilizers via Co-Digestion: a Review

In diversifying the economies of most oil producing countries especially in regions with arable lands, Agriculture becomes the next choice aside mineral deposits. This has led to a search for an alternative to inorganic fertilizers, the alternatives are the biofertilizers. The paper discussed the classification of the anaerobic co-digestion process based on the application of inoculants to the biodigester feedstock to speed up the digestion process and the absence of inoculants. Biodigester feedstock also looked at the various mechanisms in the digestion process which includes hydrolysis, acidogenesis, acetogenesis, and methanogenesis, the pathways were illustrated with chemical equations and various microorganisms that take part in the anaerobic process were mentioned and tabulated. The types of biofertilizers, merits, and demerits, the difference between biofertilizers and organic fertilizers were comprehensively discussed. Current trends on the application of the co-digestion technique to improve the yield, nutrient, and safety of biofertilizers and also the recent progression on the technique were mentioned

A survey of the fisheries of River Niger at Yauri, Kebbi State

A survey of the fisheries of river Niger at Yauri was conducted with the aid of questionnaires administered randomly at four (4) landing sites of Tashan Kasuwa (main market), Gidan-ruwa, Yabon-ruwa and Hutawa. A total of fifty (50) questionnaires were administered in all the villages. From the research work it was found that 76 % of the fishermen operate on full time basis while 24 % operate on part time basis. Out of the 50 fishermen interviewed only 46% were licensed to operate there. The type of fishing gears and equipments used in Yauri are hook and line, cast net, gill net and seine net. About 46 % of the fishermen were found using mesh size less than 2.0 cm. The dominant fish species caught during flood and dry seasons include Clarias spp., Lates niloticus respectively. Higher catches are made in the months of March and April. All the fishermen interviewed (100%) do not process their fish but disposed them off fresh. Sixty percent of the fishermen belong to different cooperative societies, while 40% do not belong to any cooperative society. The problem associated with fishing operation at Yauri includes that of lack of credit facilities, lack of extension agents, and high cost of fishing items, poor road network and remote location of the fishing village

Comparative analysis of physicochemical characteristics of ABU and Zaria Dam

The physical and chemical parameters of ABU Dam and Zaria Dam were carried out between September and October 2009. The results obtained in the two water bodies were temperature 27.7 0C, pH (7.5 and 7.3), dissolved oxygen (5.8 mg/l and 5.0 mg/l), biochemical oxygen demand (1.74 mg/l and 2. 16 mg/l), alkalinity (58 mg CaC03/l and 49 mgCaCO3/l) P04-P (2.47 mg/l and 1.59 mg/l) NO3-N (3.67 mg/l and 3.47 mg/l), conductivity (54.70 ~ks-1 and 42.48 ~ks-1), total hydrocarbon (TH) (47.66 mg/l) and 48.00 mg/l) and total dissolved solids (32.68 mg/l and 25.35 mg/l) respectively. There was no significant difference in the mean values of the parameters (P>0.05) except conductivity and total dissolved solids. The water bodies were found to be neutral with high conductivity. All the properties in the water bodies were in conformity with international standards both for drinking and aquatic life

Formulation and Characterization of Adhesive Produced From Polystyrene Waste Using Response Surface Optimization

Polystyrene is extensively used in building and construction industry, packaging and transportation of fragile equipment due its low density, high melting point, low thermal conductivity, low water absorption, etc. Polystyrene after usage is usually discarded thereby causing environmental problems. The post-usage of polystyrene has, therefore, been a subject of intense research in recent times. The aim of this work is to produce adhesive from polystyrene wastes. Polystyrene waste (PS) was collected, processed and dissolved in tackifyer and formulated with diphnyle amine and diethylene glycol dibenzoate additives to produce adhesive using 3 levels variables factors and 4 levels testing factors of design expert optimization software. The produced adhesive was further characterized for viscosity, pH, percentages solid and moisture contents for their response surfaces. The results showed that the best fit viscosity for each run was Run 1B> Run 5A > Run 5D> Run 5B>Run 4D based on the regression analysis and analysis of variance (ANOVA). The pH values obtained ranged from 4.0 to 6.3; percentage moisture content was in the order of Run 1B < 5A<4D<4B and percentage solid content was in the order of Run 1B<5A<4D. The best fitted adhesive was run 1B with 5.93 % moisture content; 5A has 7.57 % moisture content and 4D with 8.76% moisture content. The percentage solid content; Run 1B has 67.19 %, 5A has 68.16 % and 4D has 75.50 %. The produced adhesives were found within the standard range of adhesives used in production of particleboard

Development of Bench Scale Water Treatment Unit for the Treatment of Medium Turbid Water: The Use of Natural Coagulant

Water purification is a process used to enhance water quality and make it more acceptable for specific end-use. The rising increase for portable drinking water has made natural coagulant application for water purification a welcome development. Most reported researches were on the use of natural coagulants in a laboratory batch scale. Because of those above, a bench-scale laboratory study was carried out on the application of Balanites Aegyptiaca seed as a natural coagulant. The outcome showed its usefulness toward water purification. This paper reported the developed bench-scale water treatment plant's performance utilising Balanites Aegyptiaca seed stock solution and the powdered kennel as bio-coagulant. Some design equations were adopted. The treatment units considered include coagulation/flocculation, sedimentation, and filtration. The total tank design capacity was 20 litres with the overflow area's actual size for sedimentation of 7.46 litres. 0.5 Hp electric motor with a speed of 600 rpm and a speed gear drop of 120 rpm were selected. 0.0127 m pipe flow line diameter connecting the tanks with a corresponding pipe flow velocity of 0.108 m/s was obtained from the design. However, in both the coagulation, sedimentation and filtration units, the material balance obtained showed a steadiness in the material flow across sedimentation and filtration units. However, among the parameters tested in the raw turbid water, the turbid water revealed turbidity of 514 NTU, the colour of 5600 CTU, the conductivity of 276 µs/cm, pH of 7.10 and total coliform bacteria count of 85 CFU/100 mL which were above the recommended set standard of WHO and NIS. The result of the treated water using the stock solution and the powdered kennel (bio-coagulant) on the developed water treatment unit showed a remarkable reduction in the tested parameters in the raw turbid water used for the treatment process. Total coliform count reduces from 85 CFU/100 ml to 10 CFU/ml in both cases. It was observed that conductivity increases after the treatment, but other inorganic constituents reduce significantly though not to WHO and NIS's recommended set standard. The 0-dosage treatment conducted also showed a reduction in all the tested parameters

Direct estimation of cause-specific mortality fractions from verbal autopsies: multisite validation study using clinical diagnostic gold standards

<p>Abstract</p> <p>Background</p> <p>Verbal autopsy (VA) is used to estimate the causes of death in areas with incomplete vital registration systems. The King and Lu method (KL) for direct estimation of cause-specific mortality fractions (CSMFs) from VA studies is an analysis technique that estimates CSMFs in a population without predicting individual-level cause of death as an intermediate step. In previous studies, KL has shown promise as an alternative to physician-certified verbal autopsy (PCVA). However, it has previously been impossible to validate KL with a large dataset of VAs for which the underlying cause of death is known to meet rigorous clinical diagnostic criteria.</p> <p>Methods</p> <p>We applied the KL method to adult, child, and neonatal VA datasets from the Population Health Metrics Research Consortium gold standard verbal autopsy validation study, a multisite sample of 12,542 VAs where gold standard cause of death was established using strict clinical diagnostic criteria. To emulate real-world populations with varying CSMFs, we evaluated the KL estimations for 500 different test datasets of varying cause distribution. We assessed the quality of these estimates in terms of CSMF accuracy as well as linear regression and compared this with the results of PCVA.</p> <p>Results</p> <p>KL performance is similar to PCVA in terms of CSMF accuracy, attaining values of 0.669, 0.698, and 0.795 for adult, child, and neonatal age groups, respectively, when health care experience (HCE) items were included. We found that the length of the cause list has a dramatic effect on KL estimation quality, with CSMF accuracy decreasing substantially as the length of the cause list increases. We found that KL is not reliant on HCE the way PCVA is, and without HCE, KL outperforms PCVA for all age groups.</p> <p>Conclusions</p> <p>Like all computer methods for VA analysis, KL is faster and cheaper than PCVA. Since it is a direct estimation technique, though, it does not produce individual-level predictions. KL estimates are of similar quality to PCVA and slightly better in most cases. Compared to other recently developed methods, however, KL would only be the preferred technique when the cause list is short and individual-level predictions are not needed.</p