390 research outputs found

    The boson peak in structural and orientational glasses of simple alcohols: Specific heat at low temperatures

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    We review in this work specific-heat experiments, that we have conducted on different hydrogen-bonded glasses during last years. Specifically, we have measured the low-temperature specific heat Cp for a set of glassy alcohols: normal and fully-deuterated ethanol, 1- and 2- propanol, and glycerol. Ethanol exhibits a very interesting polymorphism presenting three different solid phases at low temperature: a fully-ordered (monoclinic) crystal, an orientationally-disordered (cubic) crystal or 'orientational glass', and the ordinary structural glass. By measuring and comparing the low-temperature specific heat of the three phases, in the 'boson peak' range 2-10 K as well as in the tunneling-states range below 1K, we are able to provide a quantitative confirmation that ''glassy behavior'' is not an exclusive property of amorphous solids. On the other hand, propanol is the simplest monoalcohol with two different stereoisomers (1- and 2-propanol), what allows us to study directly the influence of the spatial rearrangement of atoms on the universal properties of glasses. We have measured the specific heat of both isomers, finding a noteworthy quantitative difference between them. Finally, low-temperature specific-heat data of glassy glycerol have also been obtained. Here we propose a simple method based upon the soft-potential model to analyze low-temperature specific-heat measurements, and we use this method for a quantitative comparison of all these data of glassy alcohols and as a stringent test of several universal correlations and scaling laws suggested in the literature. In particular, we find that the interstitialcy model for the boson peak [A. V. Granato, Phys. Rev. Lett. 68 (1992) 974] gives a very good account of the temperature at which the maximum in Cp/T^3 occurs.Comment: 16 pages, 2 figures, Proceedings of the 4th International Discussion Meeting on Relaxations in Complex Systems, Hersonissos (Crete), June 2001. Journal of Non-Crystalline Solids (accepted for publication

    Transparent conductive oxide TCO buffer layer effect on the resistive switching process in metal TCO TiO2 metal assemblies

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    The effect of transparent conductive oxide TCO buffer layer on the insulator matrix and on the resistive switching process in the metal TiO2 TCO metal assembly was studied depending on the material of TCO ITO In2O3 0.9 SnO2 0.1 or SnO2 or ZnO . First time electro physical studies and near edge x ray absorption fine structure NEXAFS studies were carried out jointly and in the same point of the sample providing the direct experimental evidence that switching process influences strongly the lowest unoccupied bands and local atomic structure of the TiO2 layers. It was established that TCO layer in metal TiO2 TCO metal assembly is an additional source of oxygen vacancies for TiO2 film. The RL RH states are achieved presumably with formation rupture of electrically conductive path of oxygen vacancies. The inserting the Al2O3 thin layer between TiO2 and TCO layers restricts to some extent processes of migration of oxygen ions and vacancies and does not permit to realize the anti clockwise bipolar resistive switching in Au TiO2 Al2O3 ITO Au assembly. The greatest value of the ratio RH RL is observed for assembly with SnO2 buffer layer that will provide to implement the maximum set of intermediate states recording analog data and increases the density of information recording in this cas

    Limits on the monopole magnetic field from measurements of the electric dipole moments of atoms, molecules and the neutron

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    A radial magnetic field can induce a time invariance violating electric dipole moment (EDM) in quantum systems. The EDMs of the Tl, Cs, Xe and Hg atoms and the neutron that are produced by such a field are estimated. The contributions of such a field to the constants, χ\chi of the T,P-odd interactions χeNs/s\chi_e {\bf N} \cdot {\bf s}/s and χNNI/I\chi_N {\bf N} \cdot {\bf I}/I are also estimated for the TlF, HgF and YbF molecules (where s{\bf s} (I{\bf I}) is the electron (nuclear) spin and N{\bf N} is the molecular axis). The best limit on the contact monopole field can be obtained from the measured value of the Tl EDM. The possibility of such a field being produced from polarization of the vacuum of electrically charged magnetic monopoles (dyons) by a Coulomb field is discussed, as well as the limit on these dyons. An alternative mechanism involves chromomagnetic and chromoelectric fields in QCD.Comment: Uses RevTex, 16 pages, 4 postscript figures. An explanation of why there is no orbital contribution to the EDM has been added, and the presentation has been improved in genera

    On possibility of measurement of the electron beam energy using absorption of radiation by electrons in a magnetic field

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    The possibility of the precise measurement of the electron beam energy using absorption of radiation by electrons in a static and homogeneous magnetic field in a range up to a few hundred GeV energies, was considered in [1]. With the purpose of experimental checking of this method in a range of several tens MeV energies, the possibility of measurement of absolute energy of the electron beam energy with relative accuracy up to 10^{-4} is examined in details.Comment: 14 pages, 10 figure
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