3,380 research outputs found
Coordination chemistry in fused-salt solutions
Spectrophotometric work on structural determinations with fused-salt solutions is reviewed. Constraints placed on the method, as well as interpretation of the spectra, are discussed with parallels drawn to aqueous spectrophotometric curves of the same materials
Resampling images in Fourier domain
When simulating sky images, one often takes a galaxy image defined by
a set of pixelized samples and an interpolation kernel, and then wants to
produce a new sampled image representing this galaxy as it would appear with a
different point-spread function, a rotation, shearing, or magnification, and/or
a different pixel scale. These operations are sometimes only possible, or most
efficiently executed, as resamplings of the Fourier transform of
the image onto a -space grid that differs from the one produced by a
discrete Fourier transform (DFT) of the samples. In some applications it is
essential that the resampled image be accurate to better than 1 part in ,
so in this paper we first use standard Fourier techniques to show that
Fourier-domain interpolation with a wrapped sinc function yields the exact
value of in terms of the input samples and kernel. This operation
scales with image dimension as and can be prohibitively slow, so we next
investigate the errors accrued from approximating the sinc function with a
compact kernel. We show that these approximations produce a multiplicative
error plus a pair of ghost images (in each dimension) in the simulated image.
Standard Lanczos or cubic interpolators, when applied in Fourier domain,
produce unacceptable artifacts. We find that errors part in can be
obtained by (1) 4-fold zero-padding of the original image before executing the
DFT, followed by (2) resampling to the desired grid using
a 6-point, piecewise-quintic interpolant that we design expressly to minimize
the ghosts, then (3) executing the DFT back to domain.Comment: Typographical and one algebraic correction, to appear in PASP March
201
New class of compounds have very low vapor pressures
Magnesium hexahydrate tetrachlorometallates are 50-volume-percent water, have a high melting point and possess a low vapor pressure. These new compounds are relatively noncorrosive, thermally stable, and water soluble but not hygroscopic. They may have potential applications as cooling fluids
Implementation of robust image artifact removal in SWarp through clipped mean stacking
We implement an algorithm for detecting and removing artifacts from
astronomical images by means of outlier rejection during stacking. Our method
is capable of addressing both small, highly significant artifacts such as
cosmic rays and, by applying a filtering technique to generate single frame
masks, larger area but lower surface brightness features such as secondary
(ghost) images of bright stars. In contrast to the common method of building a
median stack, the clipped or outlier-filtered mean stacked point-spread
function (PSF) is a linear combination of the single frame PSFs as long as the
latter are moderately homogeneous, a property of great importance for weak
lensing shape measurement or model fitting photometry. In addition, it has
superior noise properties, allowing a significant reduction in exposure time
compared to median stacking. We make publicly available a modified version of
SWarp that implements clipped mean stacking and software to generate single
frame masks from the list of outlier pixels.Comment: PASP accepted; software for download at
http://www.usm.uni-muenchen.de/~dgruen
Optimizing weak lensing mass estimates for cluster profile uncertainty
Weak lensing measurements of cluster masses are necessary for calibrating
mass-observable relations (MORs) to investigate the growth of structure and the
properties of dark energy. However, the measured cluster shear signal varies at
fixed mass M_200m due to inherent ellipticity of background galaxies,
intervening structures along the line of sight, and variations in the cluster
structure due to scatter in concentrations, asphericity and substructure. We
use N-body simulated halos to derive and evaluate a weak lensing circular
aperture mass measurement M_ap that minimizes the mass estimate variance <(M_ap
- M_200m)^2> in the presence of all these forms of variability. Depending on
halo mass and observational conditions, the resulting mass estimator improves
on M_ap filters optimized for circular NFW-profile clusters in the presence of
uncorrelated large scale structure (LSS) about as much as the latter improve on
an estimator that only minimizes the influence of shape noise. Optimizing for
uncorrelated LSS while ignoring the variation of internal cluster structure
puts too much weight on the profile near the cores of halos, and under some
circumstances can even be worse than not accounting for LSS at all. We briefly
discuss the impact of variability in cluster structure and correlated
structures on the design and performance of weak lensing surveys intended to
calibrate cluster MORs.Comment: 11 pages, 5 figures; accepted by MNRA
Cosmic variance of the galaxy cluster weak lensing signal
Intrinsic variations of the projected density profiles of clusters of
galaxies at fixed mass are a source of uncertainty for cluster weak lensing. We
present a semi-analytical model to account for this effect, based on a
combination of variations in halo concentration, ellipticity and orientation,
and the presence of correlated haloes. We calibrate the parameters of our model
at the 10 per cent level to match the empirical cosmic variance of cluster
profiles at M_200m=10^14...10^15 h^-1 M_sol, z=0.25...0.5 in a cosmological
simulation. We show that weak lensing measurements of clusters significantly
underestimate mass uncertainties if intrinsic profile variations are ignored,
and that our model can be used to provide correct mass likelihoods. Effects on
the achievable accuracy of weak lensing cluster mass measurements are
particularly strong for the most massive clusters and deep observations (with
~20 per cent uncertainty from cosmic variance alone at M_200m=10^15 h^-1 M_sol
and z=0.25), but significant also under typical ground-based conditions. We
show that neglecting intrinsic profile variations leads to biases in the
mass-observable relation constrained with weak lensing, both for intrinsic
scatter and overall scale (the latter at the 15 per cent level). These biases
are in excess of the statistical errors of upcoming surveys and can be avoided
if the cosmic variance of cluster profiles is accounted for.Comment: 14 pages, 6 figures; submitted to MNRA
Simultaneous dual-element analyses of refractory metals in naturally occurring matrices using resonance ionization of sputtered atoms
The combination of secondary neutral mass spectrometry (SNMS) and resonance ionization spectroscopy (RIS) has been shown to be a powerful tool for the detection of low levels of elemental impurities in solids. Drawbacks of the technique have been the laser-repetition-rate-limited, low duty cycle of the analysis and the fact that RIS schemes are limited to determinations of a single element. These problems have been addressed as part of an ongoing program to explore the usefulness of RIS/SNMS instruments for the analysis of naturally occurring samples. Efficient two-color, two-photon (1+1) resonance ionization schemes were identified for Mo and for four platinum-group elements (Ru, Os, Ir, and Re). Careful selection of the ionization schemes allowed Mo or Ru to be measured simultaneously with Re, Os, or Ir, using two tunable dye lasers and an XeCl excimer laser. Resonance frequencies could be switched easily under computer control, so that all five elements can be rapidly analyzed. In situ measurements of these elements in metal grains from five meteorites were conducted. From the analyses, estimates of the precision and the detection limit of the instrument were made. The trade-off between lower detection limits and rapid multielement RIS analyses is discussed
Characterization and correction of charge-induced pixel shifts in DECam
Interaction of charges in CCDs with the already accumulated charge
distribution causes both a flux dependence of the point-spread function (an
increase of observed size with flux, also known as the brighter/fatter effect)
and pixel-to-pixel correlations of the Poissonian noise in flat fields. We
describe these effects in the Dark Energy Camera (DECam) with charge dependent
shifts of effective pixel borders, i.e. the Antilogus et al. (2014) model,
which we fit to measurements of flat-field Poissonian noise correlations. The
latter fall off approximately as a power-law r^-2.5 with pixel separation r,
are isotropic except for an asymmetry in the direct neighbors along rows and
columns, are stable in time, and are weakly dependent on wavelength. They show
variations from chip to chip at the 20% level that correlate with the silicon
resistivity. The charge shifts predicted by the model cause biased shape
measurements, primarily due to their effect on bright stars, at levels
exceeding weak lensing science requirements. We measure the flux dependence of
star images and show that the effect can be mitigated by applying the reverse
charge shifts at the pixel level during image processing. Differences in
stellar size, however, remain significant due to residuals at larger distance
from the centroid.Comment: typo and formatting fixes, matches version published in JINS
Geographic Variation in Informed Consent Law: Two Standards for Disclosure of Treatment Risks
We analyzed 714 jury verdicts in informed consent cases tried in 25 states in 1985â2002 to determine whether the applicable standard of care (âpatientâ vs. âprofessionalâ standard) affected the outcome. Verdicts for plaintiffs were significantly more frequent in states with a patient standard than in states with a professional standard (27 percent vs. 17 percent, P = 0.02). This difference in outcomes did not hold for other types of medical malpractice litigation (36 percent vs. 37 percent, P = 0.8). The multivariate odds of a plaintiffâs verdict were more than twice as high in states with a patient standard than in states with a professional standard (odds ratio = 2.15, 95% confidence interval = 1.32â3.50). The lawâs expectations of clinicians with respect to risk disclosure appear to vary geographically
MC: Subaru and Hubble Space Telescope Weak-Lensing Analysis of the Double Radio Relic Galaxy Cluster PLCK G287.0+32.9
The second most significant detection of the Planck Sunyaev Zel'dovich
survey, PLCK~G287.0+32.9 () boasts two similarly bright radio relics
and a radio halo. One radio relic is located kpc northwest of the
X-ray peak and the other Mpc to the southeast. This large difference
suggests that a complex merging scenario is required. A key missing puzzle for
the merging scenario reconstruction is the underlying dark matter distribution
in high resolution. We present a joint Subaru Telescope and {\it Hubble Space
Telescope} weak-lensing analysis of the cluster. Our analysis shows that the
mass distribution features four significant substructures. Of the
substructures, a primary cluster of mass
$M_{200\text{c}}=1.59^{+0.25}_{-0.22}\times 10^{15} \ h^{-1}_{70} \
\text{M}_{\odot}M_{200\text{c}}=1.16^{+0.15}_{-0.13}\times 10^{14} \ h^{-1}_{70} \
\text{M}_{\odot}\sim 400\sim 2M_{200\text{c}}=1.68^{+0.22}_{-0.20}\times
10^{14} \ h^{-1}_{70} \ \text{M}_{\odot}M_{200\text{c}}=1.87^{+0.24}_{-0.22}\times 10^{14} \ h^{-1}_{70} \
\text{M}_{\odot}$, is northwest of the X-ray peak and beyond the NW radio
relic.Comment: 19 pages, 14 figures; Accepted to Ap
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