14,137 research outputs found
Seasonal variation of aliphatic amines in marine sub-micrometer particles at the Cape Verde islands
Monomethylamine (MA), dimethylamine (DMA) and diethylamine (DEA) were detected at non-negligible concentrations in sub-micrometer particles at the Cap Verde Atmospheric Observatory (CVAO) located on the island of São Vicente in Cape Verde during algal blooms in 2007. The concentrations of these amines in five stage impactor samples ranged from 0–30 pg m−3 for MA, 130–360 pg m−3 for DMA and 5–110 pg m−3 for DEA during the spring bloom in May 2007 and 2–520 pg m−3 for MA, 100–1400 pg m−3 for DMA and 90–760 pg m−3 for DEA during an unexpected winter algal bloom in December 2007. Anomalously high Saharan dust deposition and intensive ocean layer deepening were found at the Atmospheric Observatory and the associated Ocean Observatory during algal bloom periods. The highest amine concentrations in fine particles (impactor stage 2, 0.14–0.42 μm) indicate that amines are likely taken up from the gas phase into the acidic sub-micrometer particles. The contribution of amines to the organic carbon (OC) content ranged from 0.2–2.5% C in the winter months, indicating the importance of this class of compounds to the carbon cycle in the marine environment. Furthermore, aliphatic amines originating from marine biological sources likely contribute significantly to the nitrogen content in the marine atmosphere. The average contribution of the amines to the detected nitrogen species in sub-micrometer particles can be non-negligible, especially in the winter months (0.1% N–1.5% N in the sum of nitrate, ammonium and amines). This indicates that these smaller aliphatic amines can be important for the carbon and the nitrogen cycles in the remote marine environment
Near-Infrared Spectroscopy of McNeil's Nebula Object
We present 0.8-5.2 micron spectroscopy of the compact source at the base of a
variable nebula (McNeil's Nebula Object) in the Lynds 1630 dark cloud that went
into outburst in late 2003. The spectrum of this object reveals an extremely
red continuum, CO bands at 2.3-2.5 microns in emission, a deep 3.0 micron ice
absorption feature, and a solid state CO absorption feature at 4.7 microns. In
addition, emission lines of H, Ca II, Mg I, and Na I are present. The Paschen
lines exhibit P Cygni profiles, as do two lines of He I, although the emission
features are very weak in the latter. The Brackett lines, however, are seen to
be purely in emission. The P Cygni profiles clearly indicate that mass outflow
is occurring in a wind with a velocity of ~400 km/s. The H line ratios do not
yield consistent estimates of the reddening, nor do they agree with the
extinction estimated from the ice feature (A_V ~ 11). We propose that these
lines are optically thick and are produced in a dense, ionized wind. The
near-infrared spectrum does not appear similar to any known FUor or EXor
object. However, all evidence suggests that McNeil's Nebula Object is a
heavily-embedded low-mass Class I protostar, surrounded by a disk, whose
brightening is due to a recent accretion event.Comment: 11 pages, 2 ps figures, accepted for publication in ApJ Letter
Isolated effective coherence (iCoh): causal information flow excluding indirect paths
A problem of great interest in real world systems, where multiple time series
measurements are available, is the estimation of the intra-system causal
relations. For instance, electric cortical signals are used for studying
functional connectivity between brain areas, their directionality, the direct
or indirect nature of the connections, and the spectral characteristics (e.g.
which oscillations are preferentially transmitted). The earliest spectral
measure of causality was Akaike's (1968) seminal work on the noise contribution
ratio, reflecting direct and indirect connections. Later, a major breakthrough
was the partial directed coherence of Baccala and Sameshima (2001) for direct
connections. The simple aim of this study consists of two parts: (1) To expose
a major problem with the partial directed coherence, where it is shown that it
is affected by irrelevant connections to such an extent that it can
misrepresent the frequency response, thus defeating the main purpose for which
the measure was developed, and (2) To provide a solution to this problem,
namely the "isolated effective coherence", which consists of estimating the
partial coherence under a multivariate auto-regressive model, followed by
setting all irrelevant associations to zero, other than the particular
directional association of interest. Simple, realistic, toy examples illustrate
the severity of the problem with the partial directed coherence, and the
solution achieved by the isolated effective coherence. For the sake of
reproducible research, the software code implementing the methods discussed
here (using lazarus free-pascal "www.lazarus.freepascal.org"), including the
test data as text files, are freely available at:
https://sites.google.com/site/pascualmarqui/home/icoh-isolated-effective-coherenceComment: 2014-02-21 pre-print, technical report, KEY Institute for Brain-Mind
Research, University of Zurich, et a
Proton Lifetime and Baryon Number Violating Signatures at the LHC in Gauge Extended Models
There exist a number of models in the literature in which the weak
interactions are derived from a chiral gauge theory based on a larger group
than SU(2)_L x U(1)_Y. Such theories can be constructed so as to be
anomaly-free and consistent with precision electroweak measurements, and may be
interpreted as a deconstruction of an extra dimension. They also provide
interesting insights into the issues of flavor and dynamical electroweak
symmetry breaking, and can help to raise the mass of the Higgs boson in
supersymmetric theories. In this work we show that these theories can also give
rise to baryon and lepton number violating processes, such as nucleon decay and
spectacular multijet events at colliders, via the instanton transitions
associated with the extended gauge group. For a particular model based on
SU(2)_1 x SU(2)_2, we find that the violating scattering cross sections
are too small to be observed at the LHC, but that the lower limit on the
lifetime of the proton implies an upper bound on the gauge couplings.Comment: 36 page
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