3,389 research outputs found
Crossover from a square to a hexagonal pattern in Faraday surface waves
We report on surface wave pattern formation in a Faraday experiment operated
at a very shallow filling level, where modes with a subharmonic and harmonic
time dependence interact. Associated with this distinct temporal behavior are
different pattern selection mechanisms, favoring squares or hexagons,
respectively. In a series of bifurcations running through a pair of
superlattices the surface wave pattern transforms between the two incompatible
symmetries. The close analogy to 2D and 3D crystallography is pointed out.Comment: 4 pages, 4 figure
Leading Indicator Analysis for High Speed Sled Test Programs
Leading Indicators (LI) were introduced to the Systems Engineering (SE) community in 2005. These measures are used to evaluate the effectiveness of how a specific work activity is applied on a project in a manner that provides information about impacts that are likely to affect the system performance. The LIs are designed to give a project manager/systems engineer insight into where their development project is heading and a chance to implement corrective actions early. This research strives to apply LIs to the testing community, specifically high speed sled testing, to improve the testing process and, in turn, improve the quality of the tests conducted. The thesis captures which SE processes are emphasized, valued and used in the high speed sled test community, then identifies LI trends that are most relevant to the high speed sled test community. Lastly, two of the top LIs - requirements maturity and requirements validation - were chosen for further trend analysis. Both of the LI trends were broken down into their suggested derived measures and current project trends were compared to historical trends
Self-Consistent Theory of the Gain Linewidth for Quantum Cascade Lasers
The linewidth in intersubband transitions can be significantly reduced below
the sum of the lifetime broadening for the involved states, if the scattering
environment is similar for both states. This is studied within a nonequilibrium
Green function approach here. We find that the effect is of particular
relevance for a recent, relatively low doped, THz quantum cascade laser.Comment: 3 pages, figures include
Phase relaxation of Faraday surface waves
Surface waves on a liquid air interface excited by a vertical vibration of a
fluid layer (Faraday waves) are employed to investigate the phase relaxation of
ideally ordered patterns. By means of a combined frequency-amplitude modulation
of the excitation signal a periodic expansion and dilatation of a square wave
pattern is generated, the dynamics of which is well described by a Debye
relaxator. By comparison with the results of a linear theory it is shown that
this practice allows a precise measurement of the phase diffusion constant.Comment: 5 figure
Efficient simulation of Bayesian logistic regression models
In this paper we highlight a data augmentation approach to inference in the Bayesian logistic regression model. We demonstrate that the resulting conditional likelihood of the regression coefficients is multivariate normal, equivalent to a standard Bayesian linear regression, which allows for efficient simulation using a block Gibbs sampler. We illustrate that the method is particularly suited to problems in covariate set uncertainty and random effects models
Melting and freezing of argon in a granular packing of linear mesopore arrays
Freezing and melting of Ar condensed in a granular packing of template-grown
arrays of linear mesopores (SBA-15, mean pore diameter 8 nanometer) has been
studied by specific heat measurements C as a function of fractional filling of
the pores. While interfacial melting leads to a single melting peak in C,
homogeneous and heterogeneous freezing along with a delayering transition for
partial fillings of the pores result in a complex freezing mechanism
explainable only by a consideration of regular adsorption sites (in the
cylindrical mesopores) and irregular adsorption sites (in niches of the rough
external surfaces of the grains, and at points of mutual contact of the powder
grains). The tensile pressure release upon reaching bulk liquid/vapor
coexistence quantitatively accounts for an upward shift of the
melting/freeezing temperature observed while overfilling the mesopores.Comment: 4 pages, 4 figures, to appear as a Letter in Physical Review Letter
Microsolvation and sp²-stereoinversion of monomeric α-(2, 6-di-tert-butylphenyl)vinyllithium as measured by NMR
The beta-unsubstituted title compound dissolves in THF as a uniformly trisolvated monomer, whereas it forms exclusively disolvated monomers in tert-butyl methyl ether, Et2O, TMEDA, or toluene with TMEDA (1.4 equiv). This was established at low temperatures through the observation of separated NMR signals for free and lithium-coordinated ligands and/or through the patterns and magnitudes of C-13, Li-6 NMR coupling constants. An aggregated form was observed only with Et2O (2 equiv) in toluene as the solvent. The olefinic geminal interproton coupling constants of the H2C= part can be used as a secondary criterion to differentiate between these differently solvated ground-states (3, 2, or <2 coordinated ligands per Li). Due to a kinetic trisolvation privilege of THF, the cis/trans sp(2)-stereoinversion rates could be measured through analyses of H-1 NMR line broadening and coalescence only in THF as the solvent: The pseudomonomolecular (because THF-catalyzed),ionic mechanism is initialized by a C-Li bond heterolysis with the transient immobilization of one additional THF ligand, followed by stereoinversion of the quasi-sp(2)-hybridized carbanionic center in cooperation with a "conducted tour" migration of Li+(THF)(4) along the alpha-aryl group within the solvent-separated ion pair
Low dimensional ordering and fluctuations in methanol--hydroquinone-clathrate studied by X-ray and neutron diffraction
Methanol--hydroquinone-clathrate has been established as a model
system for dielectric ordering and fluctuations and is conceptually close to
magnetic spin systems. In X-ray and neutron diffraction experiments, we
investigated the ordered structure, the one-dimensional (1D) and the
three-dimensional (3D) critical scattering in the paraelectric phase, and the
temperature dependence of the lattice constants. Our results can be explained
by microscopic models of the methanol pseudospin in the hydroquinone cage
network, in consistency with previous dielectric investigations
Enhanced thermal stability and spin-lattice relaxation rate of N@C60 inside carbon nanotubes
We studied the temperature stability of the endohedral fullerene molecule,
N@C60, inside single-wall carbon nanotubes using electron spin resonance
spectroscopy. We found that the nitrogen escapes at higher temperatures in the
encapsulated material as compared to its pristine, crystalline form. The
temperature dependent spin-lattice relaxation time, T_1, of the encapsulated
molecule is significantly shorter than that of the crystalline material, which
is explained by the interaction of the nitrogen spin with the conduction
electrons of the nanotubes.Comment: 5 pages, 4 figures, 1 tabl
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