Intercalibration of the Hb3gr 40Ar/39Ar dating standard.

The 40Ar/39Ar dating technique is based on the knowledge of the age of neutron fluence monitors (standards). Recent investigations have improved the accuracy and precision of the ages of most of the Phanerozoic-aged standards (e.g. Fish Canyon Tuff sanidine (FCs), Alder Creek sanidine, GA1550 biotite and LP-6 biotite); however, no specific study has been undertaken on the older standards (i.e. Hb3gr hornblende and NL-25 hornblende) generally used to date Precambrian, high Ca/K, and/or meteoritic rocks.In this study, we show that Hb3gr hornblende is relatively homogenous in age, composition (Ca/K) and atmospheric contamination at the single grain level. The mean standard deviation of the 40Ar/39ArK (F-value) derived from this study is 0.49%, comparable to the most homogeneous standards. The intercalibration factor (which allows direct comparison between standards) between Hb3gr and FCs is RFCsHb3gr = 51.945 0.167. Using an age of 28.02 Ma for FCs, the age of Hb3gr derived from the R-value is 1073.6 5.3 Ma (1σ, internal error only) and 8.8 Ma (including all sources of error). This age is indistinguishable within uncertainty from the K/Ar age previously reported at 1072 11 Ma [Turner G., Huneke, J.C., Podosek, F.A., Wasserburg, G.J., 1971. 40Ar-39Ar ages and cosmic ray exposure ages of Apollo 14 samples. Earth Planet. Sci. Lett. 12, 19-35]. The R-value determined in this study can also be used to intercalibrate FCs if we consider the K/Ar date of 1072 Ma as a reference age for Hb3gr. We derive an age of 27.95 0.19 Ma (1σ, internal error only) for FCs which is in agreement with the previous determinations. Altogether, this shows that Hb3gr is a suitable standard for 40Ar/39Ar geochronology

Combined U–Th/He and 40Ar/39Ar geochronology of post-shield lavas from the Mauna Kea and Kohala volcanoes, Hawaii

Late Quaternary, post-shield lavas from the Mauna Kea and Kohala volcanoes on the Big Island of Hawaii have been dated using the 40Ar/39Ar and U–Th/He methods. The objective of the study is to compare the recently demonstrated U–Th/He age method, which uses basaltic olivine phenocrysts, with 40Ar/39Ar ages measured on groundmass from the same samples. As a corollary, the age data also increase the precision of the chronology of volcanism on the Big Island. For the U–Th/He ages, U, Th and He concentrations and isotopes were measured to account for U-series disequilibrium and initial He. Single analyses U–Th/He ages for Hamakua lavas from Mauna Kea are 87 ± 40 to 119 ± 23 ka (2σ uncertainties), which are in general equal to or younger than 40Ar/39Ar ages. Basalt from the Polulu sequence on Kohala gives a U–Th/He age of 354 ± 54 ka and a 40Ar/39Ar age of 450 ± 40 ka. All of the U–Th/He ages, and all but one spurious 40Ar/39Ar ages conform to the previously proposed stratigraphy and published 14C and K–Ar ages.The ages also compare favorably to U–Th whole rock–olivine ages calculated from 238U–230Th disequilibria. The U–Th/He and 40Ar/39Ar results agree best where there is a relatively large amount of radiogenic 40Ar (>10%), and where the 40Ar/36Ar intercept calculated from the Ar isochron diagram is close to the atmospheric value. In two cases, it is not clear why U–Th/He and 40Ar/39Ar ages do not agree within uncertainty. U–Th/He and 40Ar/39Ar results diverge the most on a low-K transitional tholeiitic basalt with abundant olivine. For the most alkalic basalts with negligible olivine phenocrysts, U–Th/He ages were unattainable while 40Ar/39Ar results provide good precision even on ages as low as 19 ± 4 ka. Hence, the strengths and weaknesses of the U–Th/He and 40Ar/39Ar methods are complimentary for basalts with ages of order 100–500 ka

40Ar/39Ar ages of seamount trachytes from the South China Sea and implications for the evolution of the northwestern sub-basin

A chronological study of seamount rocks in the South China Sea basin provides a great opportunity to understand the expansion and evolution history of the sea basin. In this paper, we analyzed the 40Ar/39Ar age of trachytic samples collected from the Shuangfeng seamounts in the northwestern sub-basin of the South China Sea. The two samples yielded plateau ages of 23.80 ± 0.18 and 23.29 ± 0.22 Ma, respectively, which indicate magmatic activity in late Oligocene which helpful constraints the expansion time of the northwest sub-basin. Previous studies suggested that the northwestern sub-basin and southwestern sub-basin have experienced a relatively consistent expansion in the NW–SE direction followed by a late expansion of the eastern sub-basin. We concluded that the expansion of the northwestern sub-basin began prior to ca. 24 Ma, which also implicated magmatic events of a late or stop expansion of the northwestern sub-basin combined with our results of 40Ar/39Ar age data and previous geophysical data

40Ar/39Ar impact ages and time-temperature argon diffusion history of the Bunburra Rockhole anomalous basaltic achondrite

The Bunburra Rockhole meteorite is a brecciated anomalous basaltic achondrite containing coarse-, medium- and fine-grained lithologies. Petrographic observations constrain the limited shock pressure to between ca. 10 GPa and 20 GPa. In this study, we carried out nine 40Ar/39Ar step-heating experiments on distinct single-grain fragments extracted from the coarse and fine lithologies. We obtained six plateau ages and three mini-plateau ages. These ages fall into two internally concordant populations with mean ages of 3640 ± 21 Ma (n=7; P=0.53) and 3544 ± 26 Ma (n=2; P=0.54), respectively. Based on these results, additional 40Ar/39Ar data of fusion crust fragments, argon diffusion modeling, and petrographic observations, we conclude that the principal components of the Bunburra Rockhole basaltic achondrite are from a melt rock formed at ~3.64 Ga by a medium to large impact event. The data imply this impact generated high enough energy to completely melt the basaltic target rock and reset the Ar systematics, but only partially reset the Pb-Pb age. We also conclude that a complete 40Ar* resetting of pyroxene and plagioclase at this time could not have been achieved at solid-state conditions. Comparison with a terrestrial analogue (Lonar crater) shows that the time-temperature conditions required to melt basaltic target rocks upon impact are relatively easy to achieve. Ar data also suggest that a second medium-size impact event occurred on a neighboring part of the same target rock at ~3.54 Ga. Concordant low-temperature step ages of the nine aliquots suggest that, at ~3.42 Ga, a third smaller impact excavated parts of the ~3.64 Ga and ~3.54 Ga melt rocks and brought the fragments together. The lack of significant impact activity after 3.5 Ga, as recorded by the Bunburra Rockhole suggest that (1) either the meteorite was ejected in a small secondary parent body where it resided untouched by large impacts, or (2) it was covered by a porous heat-absorbing regolith blanket which, when combined with the diminishing frequency of large impacts in the solar system, protected Bunburra from subsequent major heating events. Finally we note that the total (K/Ar) resetting impact event history recorded by some of the brecciated eucrites (peak at 3.8-3.5 Ga) is similar to the large impact history recorded by the Bunburra Rockhole parent body (ca. 3.64-3.54 Ga; this study) and could indicate a similar position in the asteroid belt at that time

Isotopic fractionation of Cu in tektites

Tektites are terrestrial natural glasses of up to a few centimeters in size that were produced during hypervelocity impacts on the Earth’s surface. It is well established that the chemical and isotopic composition of tektites is generally identical to that of the upper terrestrial continental crust. Tektites typically have very low water content, which has generally been explained by volatilization at high temperature; however, the exact mechanism is still debated. Because volatilization can fractionate isotopes, comparing the isotopic composition of volatile elements in tektites with those of their source rocks may help to understand the physical conditions during tektite formation.Interestingly, volatile chalcophile elements (e.g., Cd and Zn) seem to be the only elements for which isotopic fractionation is known so far in tektites. Here, we extend this study to Cu, another volatile chalcophile element. We have measured the Cu isotopic composition for 20 tektite samples from the four known different strewn fields. All of the tektites (except the Muong Nong-types) are enriched in the heavy isotopes of Cu (1.98 < δ65Cu < 6.99) in comparison to the terrestrial crust (δ65Cu ≈ 0) with no clear distinction between the different groups. The Muong Nong-type tektites and a Libyan Desert Glass sample are not fractionated (δ65Cu ≈ 0) in comparison to the terrestrial crust. To refine the Cu isotopic composition of the terrestrial crust, we also present data for three geological reference materials (δ65Cu ≈ 0).An increase of δ65Cu with decreasing Cu abundance probably reflects that the isotopic fractionation occurred by evaporation during heating. A simple Rayleigh distillation cannot explain the Cu isotopic data and we suggest that the isotopic fractionation is governed by a diffusion-limited regime. Copper is isotopically more fractionated than the more volatile element Zn (δ66/64Zn up to 2.49‰). This difference of behavior between Cu and Zn is predicted in a diffusion-limited regime, where the magnitude of the isotopic fractionation is regulated by the competition between the evaporative flux and the diffusive flux at the diffusion boundary layer. Due to the difference of ionic charge in silicates (Zn2+ vs. Cu+), Cu has a diffusion coefficient that is larger than that of Zn by at least two orders of magnitude. Therefore, the larger isotopic fractionation in Cu than in Zn in tektites is due to the significant difference in their respective chemical diffusivity

The metamorphic sole of New Caledonia ophiolite: 40Ar/39Ar, U-Pb, and geochemical evidence for subduction inception at a spreading ridge

Amphibolite lenses that locally crop out below the serpentinite sole at the base of the ophiolite of New Caledonia (termed Peridotite Nappe) recrystallized in the high-temperature amphibolite facies and thus sharply contrast with blueschists and eclogites of the Eocene metamorphic complex. Amphibolites mostly display the geochemical features of MORB with a slight Nb depletion and thus are similar to theyoungest (Late Paleocene–Eocene) BABB components of the allochthonous Poya Terrane. Thermochronological data from hornblende (40Ar/39Ar), zircon, and sphene (U-Pb) suggest that these mafic rocks recrystallized at ~56 Ma. Using various geothermobarometers provides a rough estimate of peak recrystallization conditions of ~0.5 GPa at ~80–95°C. The thermal gradient inferred from the metamorphic assemblage (~60°C km-1), geometrical relationships, and geochemical similarity suggest that these mafic rocks belong to the oceanic crust of the lower plate of the subduction/obduction system and recrystallized when they subducted below young and hot oceanic lithosphere. They were detached from the down-going plate and finally thrust onto unmetamorphosed Poya Terrane basalts. This and the occurrence of slab melts at ~53 Ma suggest that subduction inception occurred at or near to the spreading ridge of the South Loyalty Basin at ~56 Ma

Neoproterozoic 40Ar/39Ar mica ages mark the termination of a billion years of intraplate reworking in the Capricorn Orogen, Western Australia

The tectonic history of the Proterozoic Capricorn Orogen, Western Australia, records complex intraplate reworking lasting nearly one billion years. Although the Paleo-Mesoproterozoic reworking history is well defined in the crystalline basement of the Gascoyne Province, at the western end of the orogen, the younger reactivation history remains unclear. Four reworking events affected the orogen at 1820–1770 Ma, 1680–1620 Ma, 1320–1170 Ma, and 1030–900 Ma. These events were succeeded by a breakout in predominantly dextral strike-slip reactivation of major shear zones across the Gascoyne Province. Currently, the age of this reactivation is constrained by only one date of c. 570 Ma from a single shear zone, but field relationships imply that some of the shear zones must be older than a suite of c. 755 Ma dolerite dykes. In order to constrain the age of fault and shear zone reactivation we obtained new 40 Ar/ 39 Ar dates for mica and in situ SHRIMP U-Pb dates for xenotime within shear zones. Our results when combined with previously published data, show that reactivation occurred between 920 and 830 Ma. These dates overlap with the youngest reworking event, the 1030–900 Ma Edmundian Orogeny. Furthermore, Neoproterozoic U-Pb phosphate ages are known from the bounding cratons and faulting within the adjacent Mesoproterozoic sedimentary basins suggest this event is of regional significance. In contrast to previous suggestions that this Neoproterozoic reactivation was the result of a collision from the west, we propose that it reflects north–south compression that caused dextral strike-slip fault reactivation in the north and exhumation of the southern part of the orogen

Lithospheric mantle evolution monitored by overlapping large igneous provinces: case study in southern Africa

Most of the studies on the large igneous provinces (LIPs) focus on Phanerozoic times, and in particular, thoserelated to the disruption of Pangea (e.g. CAMP, Karoo, Parana–Etendeka) while Precambrian LIPs (e.g.Ventersdorpf, Fortescue) remain less studied. Although the investigation of Precambrian LIPs is difficultbecause they are relatively poorly preserved, assessment of their geochemical characteristics in parallel withyounger overlapping LIP is fundamental for monitoring the evolution of the mantle composition through time.Recent 40Ar/39Ar dating of the Okavango giant dyke swarm (and related sills) in southern Africa showed that~90% of the dykes were emplaced at 179±1Ma and belong to the Karoo large igneous province whereas ~10% ofdykes yielded Proterozoic ages (~1–1.1 Ga). Here,weprovide newmajor, trace and rare earth elements analysesof the low-Ti Proterozoic Okavango dyke swarm (PODS) that suggest, combined with age data, a cognate originwith the 1.1 Ga Umkondo large igneous province (UIP), southern Africa.The geochemical characteristics of the PODS and UIP basalts are comparable to those of overlapping low-TiKaroo basalts, and suggest that both LIPs were derived from similar enriched mantle sources. A mantle plumeorigin for these LIPs is not easily reconciled with the geochemical dataset and the coincidence of twocompositionally similar mantle plumes acting 900 Myr apart is unlikely. Instead,we propose that the Umkondoand Karoo large igneous provinces monitored the slight evolution of a shallow enriched lithospheric mantlefrom Proterozoic to Jurassic

Basement control on dyke distribution in Large Igneous Provinces: Case study of the Karoo triple junction.

Continental flood basalts consist of vast quantities of lava, sills and giant dyke swarms that are associated with continental break-up. The commonly radiating geometry of dyke swarms in these provinces is generally interpreted as the result of the stress regime that affected the lithosphere during the initial stage of continental break-up or as the result of plume impact. On the other hand, structures in the basement may also control dyke orientations, though such control has not previously been documented. In order to test the role of pre-dyke structures, we investigated four major putative Karoo-aged dyke swarms that taken together represent a giant radiating dyke swarm (the so-called "triple-junction") ascribed to the Jurassic Karoo continental flood basalt (> 3x10 6 km2; southern Africa). One of the best tests to discriminate between neoformed and inherited dyke orientation is to detect Precambrian dykes in the Jurassic swarms. Accordingly, we efficiently distinguished between Jurassic and Precambrian dykes using abbreviated low resolution, 40Ar/39Ar incremental heating schedules. Save-Limpopo dyke swarm samples (n = 19) yield either apparent Proterozoic (728-1683 Ma) or Mesozoic (131-179 Ma) integrated ages; the Olifants River swarm (n = 20) includes only Proterozoic (851-1731 Ma) and Archaean (2470-2872 Ma) dykes. The single age obtained on one N-S striking dyke (1464 Ma) suggests that the Lebombo dyke swarm includes Proterozoic dykes in the basement as well. These dates demonstrate the existence of pre-Karoo dykes in these swarms as previously hypothesized without supporting age data.In addition, aeromagnetic and air-photo interpretations indicate that: (1) dyke emplacement was largely controlled by major discontinuities such as the Zimbabwe and Kaapvaal craton boundaries, the orientation of the Limpopo mobile belt, and other pre-dyke structures including shear zones and (2) considering its polygenetic, pre-Mesozoic origin, the Olif ants River dyke swarm cannot be considered part of the Karoo magmatic event.This study, along with previous results obtained on the Okavango dyke swarm, shows that the apparent "triple junction" formed by radiating dyke swarms is not a Jurassic structure; rather, it reflects weakened lithospheric pathways that have controlled dyke orientations over hundreds of millions of years. One consequence is that the "triple-junction" geometry can no longer be unambiguously used as a mantle plume marker as previously proposed, although it does not preclude the possible existence of a mantle plume. More generally, we suggest that most Phanerozoic dyke swarms (including triple junctions) related to continental flood basalts were probably controlled in part by pre-existing lithospheric discontinuities

Continental Arc and Back-Arc Migration in Eastern NE China: New Constraints on Cretaceous Paleo-Pacific Subduction and Rollback

Tectonic evolution models for the Cretaceous Russia Sikhote-Alin and eastern NE China continental margin and interior remain controversial. To understand the magmatic evolution over time and assess regional geodynamic processes, we sampled a diverse array of igneous rocks and employed zircon U-Pb dating, hornblende and plagioclase 40Ar-39Ar dating, whole-rock major and trace element analysis, and 87Sr/86Sr and 143Nd/144Nd isotopic analysis. The west Sikhote-Alin Pikeshan Formation volcanics and associated granites occurred at a peak of ~118 Ma and are hosted by the Triassic-Jurassic accretionary complex. Their whole rock geochemistry shows that SiO2 increased in a linear trend, Eu/Eu* values decreased from 0.91 to 0.38, and eNd(t) values decreased from +0.6 to -2.9, indicating magma mixing of a juvenile mantle wedge source and continental crust, consistent with a continental arc. The arc thickened over time with a felsic dike hosted in the Pikeshan granites showing depletion in heavy rare earth elements. The termination of the arc front is documented by the ~107-Ma intermediate lamprophyre and felsic dikes with eNd(t) values of +4.5 to +1.1, indicating an increased mantle contribution over time. Lithospheric extension of the Jiamusi Block to the west occurred at ~100 Ma, characterized by bimodal volcanism and composite dike emplacement, suggestive of asthenosphere upwelling. Based on the spatial and temporal distribution of these igneous rocks, the continental arc and intraplate magmatism migrated eastward contemporaneously. We favor a model invoking rollback of the subducting Paleo-Pacific slab affecting a long-lived continental arc