Fracture behavior across interfaces in seal lithologies

Faults and fracture networks at depth are important fluid pathways, especially in fine-grained, low permeability seal lithologies. Discontinues in sealing lithologies can create seal bypass systems, leading to the failure of CO2 geosequestration sites or hydrocarbon traps. We characterize the occurrence of and changes in discontinuity patterns and the associated changes in elastic moduli across sedimentologic interfaces to document the importance of these discontinuities for fluid management in the subsurface and potential for re-activation in high-pressure injection scenarios. We evaluate well-exposed, fine-grained, low-permeability Mesozoic and Paleozoic units that are seals of potential CO2 repositories on the Colorado Plateau and show evidence for open fractures and fluid flow in the subsurface. Field observations document changes in fracture distributions across lithologic boundaries allowing us to identify mechano-stratigraphic units and focus on the effect of lithologic interfaces on fracture distribution. An interface marks the boundary between facies in a seal and in this study the fractures are shown to deflect or arrest at the interface. In outcrop fracture intensity varies in from 1 to 18 fractures per meter and fracture apertures range from mm to cm. The mineralized fractures often have associated alteration halos along their boundaries; their general orientation follows that of discontinuities within the underlying reservoir facies or adjacent faults. The recognition of these changes in fracture distribution is important for forward modeling of fluid flow and risk management. Studying the occurrence of and changes in fracture patterns from outcrops and scaling it up for use in modeling at a field scale is difficult due to the lack of direct correlation between outcrop observations and subsurface data. Due to the size and amount of data needed to model fluid flow at the field scale the meso-scale (cm to m) variability of rock properties is often neglected. We evaluate this meso-scale variability in elastic moduli, where possible. We combine mechano-stratigraphic outcrop observations with elastic moduli calculated from publically available wire line log data to evaluate the variability in rock strength within the heterolithic top seal. Relationships between changes in Young’s modulus to resulting fracture distribution can then be observed. The outcome of this analysis can be used for modeling the effectiveness of seal for storage of CO2 in the underlying reservoirs. Digitized publically available wire line well log data were used to calculate Poisson’s ratio and Young’s modulus over the Carmel Formation and upper most 3 m of the underlying Navajo Sandstone. Our calculations show that Young’s Modulus can range between 15 to 34 GPa across 60 cm of the intra-seal interfaces, and an average difference of 5 GPa across the reservoir seal interface. These variations will affect fracture distributions and fluid behavior in the subsurface. These data provide a means to closely tie outcrop observations to derived estimates of subsurface rock strength. The characterization of rock strength variability is especially important for modeling the response of seals to increased pressure, due to CO2 injection, and will allow for better site screening and fluid management once injection projects are underway

Use of wire line logs for estimation of strength variability in cap-­‐rock lithologies

The characterization of cap-rock, low permeability and high capillary entry pressure lithologies is important for modeling the response of cap-rocks to increased pressures due to CO2 injection. We evaluate the use of publically available wireline log data to provide empirical estimate of rock strength in order to determine the strength of top seal over a range of scales. This method is being used to characterize cap-rock lithologies in systems proposed for CO2 geosequestration, these data will be combined with outcrop fracture density observations, petrology, lithologic stacking patterns and mineralogy to predict the potential for bypass. Analysis to date includes wells with monopole and dipole sonic logs for comparison of the relationships established empirically by other workers and used in this study to estimate the dynamic values for Poisson’s Ratio and Young’s Modulus from publically available vintage well log data in Utah. This study focuses specifically on the Jurassic Carmel Formation, which is a cap-rock to the underlying proposed CO2 injection reservoir, the Navajo Sandstone. This study compliments the well data with outcrop characterization of the Carmel Formation, which we split into 3 mechanical units based on lithologic stacking patterns, fracture density, and relationships observed between the percent shale and fracture spacing ratio. Results obtained from the well log analysis fall within the published ranges for these rock types, however the data show a variability which is being evaluated further to understand if these observations are related to geology or artifacts associated with the wireline data. In future the use of these empirical estimates will provide a lower estimate for subsurface rock strength, as well as provide a means to closely tie outcrop observations to those made from subsurface data

Hydrologic Evaluation of the Coastal Belt Water Project Sarir and Tazerbo Well Fields, Libya

Executive Summary: The basic purpose of this study was to conduct a finite-element computer model and give an dindependent appraisal of the reliability of the groundwater supply for the proposed Coastal Belt Water Project (CBWP_ Well Fields at Sarir and Tazerbo. There is no doubt that ample quantities of groundwater of acceptable quality occur at the sites selected for these well fields for the estimated 50-year life of the project and longer. Of major concern is the predicted drawdown of wells and total pumping lifts throughout the 50-year period. Excessive drawdowns could cause operating costs to become prohibitibely expensive. Average drawdown in wells not including well-field interference and hydraulic friction losses at the CBWP Well Field at Sarir is expected to be only about 30 m at the end of 50 years, but the static water level is relatively deep (56 m) which makes the total pumping lift fairly high when well-field interference and other losses are added. This optimistic estimate of drawdown is based upon computer analysis for almost 7 years of pumping history of the existing Sarir South agricultural well field nearby, where the subsurface geology is believed to be quite similar to that at the propsed CBWP Well Field at Sarir. The average dpumping lift, which includes many other factors besides aquifer drawdown, is estimated to be about 142 m. at the end of the 50-year pumping period at Sarir and should average about 136 m during the 50 years. Interference from pumpage at the existing agricultural well fields at Sarir may be responsible for about 10 m of this predicted pumping lift. Drawdown at Tazerbo is predicted to be about 90 m. at the end of 50 years, but the static water level is only about 9 m. there. Consequently its average pumping lift should be about 133 m at the end of the 50-year pumping period and should average about 118 m during the 50 years. no appreciable interference from nearby well fields is expected in the Tazerbo area based upon presently known conditions. Significatn reductions in pumping lifts at Tazerbo and in water-collection network costs at Sarir are possible by improved well field layout and well design. Suggested inprovements and estimated cost savings are presented in detail in Appendix A (especially see well-field design comparisons of Tables A-1 and A-4)

Correlation Effects and Electronic Structure of Gd@C60

We have investigated the electronic structure of Gd@C60 using ab initio calculations, photoemission and resonant photoemission (constant initial state spectroscopy). In comparing our calculations based on the local spin density approximation and the Hubbard model description with the observed photoemission spectra, we conclude that Gd 4f states exhibit enhanced correlation energies. These correlation energies have values larger than those normally observed in metallic gadolinium and gadolinium compounds. We attributed the enhanced correlation to the diminished screening of the encapsulated Gd. Both calculation and experiment confi rm a strong hybridization between the valence states of Gd and the C 2p states of the fullerene cage

The genus <i>Elaphomyces </i>(<i>Ascomycota</i>, <i>Eurotiales</i>):a ribosomal DNA-based phylogeny and revised systematics of European 'deer truffles'

Elaphomyces (‘deer truffles’) is one of the most important ectomycorrhizal fungal genera in temperate and subarctic forest ecosystems, but also one of the least documented in public databases. The current systematics are mainly based on macromorphology, and is not significantly different from that proposed by Vittadini (1831). Within the 49 species recognised worldwide, 23 were originally described from Europe and 17 of these were described before the 20th century. Moreover, very recent phylogenetic treatments of the genus are mainly based on a few extra-European species and most common European species are still poorly documented. Based on an extensive taxonomic sampling mainly made in the biogeographically rich Cantabrian area (Spain), complemented with collections from France, Greece, Italy, Norway, Portugal and Sweden, all currently recognized species in Europe have been sequenced at the ITS and 28S of the rDNA. Combined phylogenetic analyses yielded molecular support to sections Elaphomyces and Ceratogaster (here emended), while a third, basal lineage encompasses the sections Malacodermei and Ascoscleroderma as well as the tropical genus Pseudotulostoma. Species limits are discussed and some taxa formerly proposed as genuine species based on morphology and biogeography are re-evaluated as varieties or forms. Spore size and ornamentation, features of the peridial surface, structure of the peridium, and the presence of mycelium patches attached to the peridial surface emerge as the most significant systematic characters. Four new species: E. barrioi, E. quercicola, E. roseolus and E. violaceoniger, one new variety: E. papillatus var. sulphureopallidus, and two new forms: E. granulatus forma pallidosporus and E. anthracinus forma talosporus are introduced, as well as four new combinations in the genus: E. muricatus var. reticulatus, E. muricatus var. variegatus, E. papillatus var. striatosporus and E. morettii var. cantabricus. Lectotypes and epitypes are designated for most recognised species. For systematic purposes, new infrageneric taxa are introduced: E. sect. Ascoscleroderma stat. nov., E. subsect. Sclerodermei stat. nov., E. subsect. Maculati subsect. nov., E. subsect. Muricati subsect. nov., and E. subsect. Papillati subsect. nov. Lastly, E. laevigatus, E. sapidus, E. sulphureopallidus and E. trappei are excluded from the genus and referred to Rhizopogon roseolus, Astraeus sapidus comb. nov., Astraeus hygrometricus and Terfezia trappei comb. nov. (syn.: Terfezia cistophila), respectively

Correlation effects and electronic structure of Gd@C\u3csub\u3e60\u3c/sub\u3e

We have investigated the electronic structure of Gd@C60 using ab initio calculations, photoemission and resonant photoemission (constant initial state spectroscopy). In comparing our calculations based on the local spin density approximation and the Hubbard model description with the observed photoemission spectra, we conclude that Gd 4f states exhibit enhanced correlation energies. These correlation energies have values larger than those normally observed in metallic gadolinium and gadolinium compounds. We attributed the enhanced correlation to the diminished screening of the encapsulated Gd. Both calculation and experiment confirm a strong hybridization between the valence states of Gd and the C 2p states of the fullerene cage

Pressure-dependent EPANET extension

In water distribution systems (WDSs), the available flow at a demand node is dependent on the pressure at that node. When a network is lacking in pressure, not all consumer demands will be met in full. In this context, the assumption that all demands are fully satisfied regardless of the pressure in the system becomes unreasonable and represents the main limitation of the conventional demand driven analysis (DDA) approach to WDS modelling. A realistic depiction of the network performance can only be attained by considering demands to be pressure dependent. This paper presents an extension of the renowned DDA based hydraulic simulator EPANET 2 to incorporate pressure-dependent demands. This extension is termed “EPANET-PDX” (pressure-dependent extension) herein. The utilization of a continuous nodal pressure-flow function coupled with a line search and backtracking procedure greatly enhance the algorithm’s convergence rate and robustness. Simulations of real life networks consisting of multiple sources, pipes, valves and pumps were successfully executed and results are presented herein. Excellent modelling performance was achieved for analysing both normal and pressure deficient conditions of the WDSs. Detailed computational efficiency results of EPANET-PDX with reference to EPANET 2 are included as well

1997 evaluation of tritium removal and mitigation technologies for Hanford Site wastewaters

This report contains results of a biennial assessment of tritium separation technology and tritium nitration techniques for control of tritium bearing wastewaters at the Hanford Site. Tritium in wastewaters at Hanford have resulted from plutonium production, fuel reprocessing, and waste handling operations since 1944. this assessment was conducted in response to the Hanford Federal Facility Agreement and Consent Order

Expression of a barley cystatin gene in maize enhances resistance against phytophagous mites by altering their cysteine-proteases

Phytocystatins are inhibitors of cysteine-proteases from plants putatively involved in plant defence based on their capability of inhibit heterologous enzymes. We have previously characterised the whole cystatin gene family members from barley (HvCPI-1 to HvCPI-13). The aim of this study was to assess the effects of barley cystatins on two phytophagous spider mites, Tetranychus urticae and Brevipalpus chilensis. The determination of proteolytic activity profile in both mite species showed the presence of the cysteine-proteases, putative targets of cystatins, among other enzymatic activities. All barley cystatins, except HvCPI-1 and HvCPI-7, inhibited in vitro mite cathepsin L- and/or cathepsin B-like activities, HvCPI-6 being the strongest inhibitor for both mite species. Transgenic maize plants expressing HvCPI-6 protein were generated and the functional integrity of the cystatin transgene was confirmed by in vitro inhibitory effect observed against T. urticae and B. chilensis protein extracts. Feeding experiments impaired on transgenic lines performed with T. urticae impaired mite development and reproductive performance. Besides, a significant reduction of cathepsin L-like and/or cathepsin B-like activities was observed when the spider mite fed on maize plants expressing HvCPI-6 cystatin. These findings reveal the potential of barley cystatins as acaricide proteins to protect plants against two important mite pests