Close-circuit domain quadruplets in BaTiO3_3 nanorods embedded in SrTiO3_3 film

Cylindrical BaTiO3 nanorods embedded in (100)-oriented SrTiO3 epitaxial film in a brush-like configuration are investigated in the framework of the Ginzburg-Landau-Devonshire model. It is shown that strain compatibility at BaTiO3/SrTiO3 interfaces keeps BaTiO3 nanorods in the rhombohedral phase even at room temperature. Depolarization field at the BaTiO3/SrTiO3 interfaces is reduced by an emission of the 109-degree or 71-degree domain boundaries. In case of nanorods of about 10-80 nm diameter, the ferroelectric domains are found to form a quadruplet with a robust flux-closure arrangement of the in-plane components of the spontaneous polarization. The out-of-plane components of the polarization are either balanced or oriented up or down along the nanorod axis. Switching of the out-of-plane polarization with coercive field of about $5.10^6$ V/m occurs as a collapse of a 71-degree cylindrical domain boundary formed at the curved circumference surface of the nanorod. The remnant domain quadruplet configuration is chiral, with the $C_4$ macroscopic symmetry. More complex stable domain configurations with coexisting clockwise and anticlockwise quadruplets contain interesting arrangement of strongly curved 71-degree boundaries.Comment: Erratta - corrected error in Fig.

Central mode and soft mode behavior in PbMg1/Nb2/3O3 relaxor ferroelectric

The relaxor ferroelectric PbMg1/Nb2/3O3 was investigated by means of broad-band dielectric and Fourier Transform Infrared (FTIR) transmission spectroscopy in the frequency range from 1 MHz to 15 THz at temperatures between 20 and 900 K using PMN films on infrared transparent sapphire substrates. While thin film relaxors display reduced dielectric permittivity at low frequencies, their high frequency intrinsic or lattice response is shown to be the same as single crystal/ceramic specemins. It was observed that in contrast to the results of inelastic neutron scattering, the optic soft mode was underdamped at all temperatures. On heating, the TO1 soft phonon followed the Cochran law with an extrapolated critical temperature equal to the Burns temperature of 670 K and softened down to 50 cm-1. Above 450 K the soft mode frequency leveled off and slightly increased above the Burns temperature. A central mode, describing the dynamics of polar nanoclusters appeared below the Burns temperature at frequencies near the optic soft mode and dramatically slowed down below 1 MHz on cooling below room temperature. It broadened on cooling, giving rise to frequency independent losses in microwave and lower frequency range below the freezing temperature of 200 K. In addition, a new heavily damped mode appeared in the FTIR spectra below the soft mode frequency at room temperature and below. The origin of this mode as well as the discrepancy between the soft mode damping in neutron and infrared spectra is discussed.Comment: 7 pages with 7 figures, submitted to Phys. Rev.

Issues and solutions for researching weed eradication target species

Species biology drives the frequency, duration and extent of survey and control activities in weed eradication programs. Researching the key biological characters can be difficult when plants occur at limited locations and are controlled immediately by field crews who are dedicated to preventing reproduction. Within the National Four Tropical Weeds Eradication Program and the former National Siam Weed Eradication Program, key information needed by the eradication teams has been obtained through a combination of field, glasshouse and laboratory studies without jeopardising the eradication objective. Information gained on seed longevity, age to reproductive maturity, dispersal and control options has been used to direct survey and control activities. Planned and opportunistic data collections will continue to provide biological information to refine eradication activities

Rotator and extender ferroelectrics: Importance of the shear coefficient to the piezoelectric properties of domain-engineered crystals and ceramics

The importance of a high shear coefficient d15 (or d24) to the piezoelectric properties of domain-engineered and polycrystalline ferroelectrics is discussed. The extent of polarization rotation, as a mechanism of piezoelectric response, is directly correlated to the shear coefficient. The terms "rotator" and "extender" are introduced to distinguish the contrasting behaviors of crystals such as 4mm BaTiO3 and PbTiO3. In "rotator" ferroelectrics, where d15 is high relative to the longitudinal coefficient d33, polarization rotation is the dominant mechanism of piezoelectric response; the maximum longitudinal piezoelectric response is found away from the polar axis. In "extender" ferroelectrics, d15 is low and the collinear effect dominates; the maximum piezoelectric response is found along the polar axis. A variety of 3m, mm2 and 4mm ferroelectrics, with various crystal structures based on oxygen octahedra, are classified in this way. It is shown that the largest piezoelectric anisotropies d15/d33 are always found in 3m crystals; this is a result of the intrinsic electrostrictive anisotropy of the constituent oxygen octahedra. Finally, for a given symmetry, the piezoelectric anisotropy increases close to ferroelectric-ferroelectric phase transitions; this includes morphotropic phase boundaries and temperature induced polymorphic transitions.Comment: accepted in J. Appl. Phy

Increased options for controlling mikania vine (Mikania micrantha) with foliar herbicides

Mikania micrantha Kunth (mikania vine) is a highly invasive tropical weed that was first discovered in Australia in 1997, and has been the target of a nationally cost-shared weed eradication program since 2003. Field crews have been effectively treating the weed with herbicide solutions containing 1 g a.i. L−1 of fluroxypyr. During the eradication program there have been limited opportunities to test alternative foliar herbicides or rates. A newly discovered infestation provided sufficient immature vines to compare the effectiveness of eight herbicide treatments

The Structural Complexity of (Bi0.5Na0.5)TiO3-BaTiO3 as Revealed by Raman Spectroscopy

The structural phase diagram of the Pb-free ferroelectric (Na1/2Bi1/2)1-xBaxTiO3 (NBT-BT), x<0.1, has been explored by Raman spectroscopy at temperatures from 10 to 470 K. The data provide clear evidence for a proposed temperature-independent morphotropic phase boundary at x \approx 0.055. However, there is no evidence for a structural phase transition across T \approx 370 K for x > 0.055, where bulk-property anomalies appear to signal a transition to a nonpolar or antiferroelectric phase. The results identify that the phase above 370 K shows short-range ionic displacements that are identical to those in the long-range-ordered phase below 370 K. These conclusions provide a natural interpretation of the weak piezoelectric response in this system and have important implications for the search for Pb-free piezoelectrics.Comment: 21 pages, 5 figure

Human-robot swarm interaction with limited situational awareness

This paper studies how an operator with limited situational awareness can collaborate with a swarm of simulated robots. The robots are distributed in an environment with wall obstructions. They aggregate autonomously but are unable to form a single cluster due to the obstructions. The operator lacks the bird’s-eye perspective, but can interact with one robot at a time, and influence the behavior of other nearby robots. We conducted a series of experiments. They show that untrained participants had marginal influence on the performance of the swarm. Expert participants succeeded in aggregating 85% of the robots while untrained participants, with bird’s-eye view, succeeded in aggregating 90%. This demonstrates that the controls are sufficient for operators to aid the autonomous robots in the completion of the task and that lack of situational awareness is the main difficulty. An analysis of behavioral differences reveals that trained operators learned to gain superior situational awareness

Anharmonicity of BaTiO_3 single crystals

By analyzing the dielectric non-linearity with the Landau thermodynamic expansion, we find a simple and direct way to assess the importance of the eighth order term. Following this approach, it is demonstrated that the eighth order term is essential for the adequate description of the para/ferroelectric phase transition of BaTiO_3. The temperature dependence of the quartic coefficient \beta is accordingly reconsidered and is strongly evidenced by the change of its sign above 165 C. All these findings attest to the strong polarization anharmonicity of this material, which is unexpected for classical displacive ferroelectrics.Comment: 4 figures, to be published in Phys. Rev.