294 research outputs found

    High-resolution antenna near-field imaging and sub-THz measurements with a small atomic vapor-cell sensing element

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    Atomic sensing and measurement of millimeter-wave (mmW) and THz electric fields using quantum-optical EIT spectroscopy of Rydberg states in atomic vapors has garnered significant interest in recent years towards the development of atomic electric-field standards and sensor technologies. Here we describe recent work employing small atomic vapor cell sensing elements for near-field imaging of the radiation pattern of a Ku_u-band horn antenna at 13.49 GHz. We image fields at a spatial resolution of λ/10\lambda/10 and measure over a 72 to 240 V/m field range using off-resonance AC-Stark shifts of a Rydberg resonance. The same atomic sensing element is used to measure sub-THz electric fields at 255 GHz, an increase in mmW-frequency by more than one order of magnitude. The sub-THz field is measured over a continuous ±\pm100 MHz frequency band using a near-resonant mmW atomic transition

    Numerical methods for entrainment and detrainment in the multi-fluid Euler equations for convection

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    Convection schemes are a large source of error in global weather and climate models, and modern resolutions are often too fine to parameterise convection but are still too coarse to fully resolve it. Recently, numerical solutions of multi-fluid equations have been proposed for a more flexible and consistent treatment of sub-grid scale convection, including net mass transport by convection and non-equilibrium dynamics. The technique involves splitting the atmosphere into multiple fluids. For example, the atmosphere could be divided into buoyant updrafts and stable regions. The fluids interact through a common pressure, drag and mass transfers (entrainment and detrainment). Little is known about the numerical properties of mass transfer terms between the fluids. We derive mass transfer terms which relabel the fluids and derive numerical properties of the transfer schemes, including boundedness, momentum conservation and energy conservation on a co-located grid. Numerical simulations of the multi-fluid Euler equations using a C-grid are presented using stable and unstable treatments of the transfers on a well-resolved two-fluid dry convection test case. We find two schemes which are conservative, stable and bounded for large timesteps, and maintain their numerical properties on staggered grids

    The Power of Action Plots: Unveiling Reaction Selectivity of Light‐Stabilized Dynamic Covalent Chemistry

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    Exploiting the optimum wavelength of reactivity for efficient photochemical reactions has been well-established based on the development of photochemical action plots. We herein demonstrate the power of such action plots by a remarkable example of the wavelength-resolved photochemistry of two triazolinedione (TAD) substrates, i.e., aliphatic and aromatic substituted, that exhibit near identical absorption spectra yet possess vastly disparate photoreactivity. We present our findings in carefully recorded action plots, from which reaction selectivity is identified. The profound difference in photoreactivity is exploited by designing a ‘hybrid’ bisfunctional TAD molecule, enabling the formation of a dual-gated reaction manifold that demonstrates the exceptional and site-selective (photo)chemical behavior of both TAD substrates within a single small molecule
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