64,291 research outputs found
Thermodynamics and phase behavior of the lamellar Zwanzig model
Binary mixtures of lamellar colloids represented by hard platelets are
studied within a generalization of the Zwanzig model for rods, whereby the
square cuboids can take only three orientations along the , or axes.
The free energy is calculated within Rosenfeld's ''Fundamental Measure Theory''
(FMT) adapted to the present model. In the one-component limit, the model
exhibits the expected isotropic to nematic phase transition, which narrows as
the aspect ratio ( is the width and the thickness of the
platelets) increases. In the binary case the competition between nematic
ordering and depletion-induced segregation leads to rich phase behaviour.Comment: 9 pages, 6 figure
On the nonlocal viscosity kernel of mixtures
In this report we investigate the multiscale hydrodynamical response of a
liquid as a function of mixture composition. This is done via a series of
molecular dynamics simulations where the wave vector dependent viscosity kernel
is computed for three mixtures each with 7-15 different compositions. We
observe that the nonlocal viscosity kernel is dependent on composition for
simple atomic mixtures for all the wave vectors studied here, however, for a
model polymer melt mixture the kernel is independent of composition for large
wave vectors. The deviation from ideal mixing is also studied. Here it is shown
that a Lennard-Jones mixture follows the ideal mixing rule surprisingly well
for a large range of wave vectors, whereas for both the Kob-Andersen mixture
and the polymer melt large deviations are found. Furthermore, for the polymer
melt the deviation is wave vector dependent such that there exists a critical
length scale at which the ideal mixing goes from under-estimating to
over-estimating the viscosity
Ka-band (32 GHz) benefits to planned missions
The benefits of using 32 GHz downlinks for a set of deep space missions, as well as the implications to radio science and the Deep Space Network (DSN) are documented. The basic comparison is between the use of the current X-band (8.4 GHz) and a 32 GHZ (Ka-band) downlink. There was shown to be approximately an 8 dB (about 600%) link advantage for 32 GHz. This 8 dB advantage would be able to either reduce mission cost or improve mission science return. Included here are studies on how the 8 dB advantage would be used for the Cassini and Mars Sample Return missions. While the work is preliminary, it shows that the 8 dB advantage can be exploited to provide large benefits to future deep space missions. There can be significant mass and/or power savings to the spacecraft, which can translate into cost savings. Alternatively, the increased downlink telecommunications performance can provide a greater science return
Feasibility study of an Integrated Program for Aerospace vehicle Design (IPAD) Volume 7: IPAD benefits and impact
The potential benefits, impact and spinoff of IPAD technology are described. The benefits are projected from a flowtime and labor cost analysis of the design process and a study of the flowtime and labor cost savings being experienced with existing integrated systems. Benefits in terms of designer productivity, company effectiveness, and IPAD as a national resource are developed. A description is given of the potential impact of information handling as an IPAD technology, upon task and organization structure and people who use IPAD. Spinoff of IPAD technology to nonaerospace industries is discussed. The results of a personal survey made of aerospace, nonaerospace, government and university sources are given
Civil markets for buoyant heavy-lift vehicles
Worldwide civil markets for heavy lift airships were investigated. Substantial potential market demand was identified for payloads of from 13 to 800 tons. The largest markets appear to be in applications to relieve port congestion, construction of power generating plants, and, most notably, logging. Because of significant uncertainties both in vehicle and market characteristics, further analysis will be necessary to verify the identified market potential of heavy lift airship concepts
Three dimensional global modeling of atmospheric CO2
A model was developed to study the prospects of extracting information on carbon dioxide sources and sinks from observed CO2 variations. The approach uses a three dimensional global transport model, based on winds from a 3-D general circulation model (GCM), to advect CO2 noninteractively, i.e., as a tracer, with specified sources and sinks of CO2 at the surface. The 3-D model employed is identified and biosphere, ocean and fossil fuel sources and sinks are discussed. Some preliminary model results are presented
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Primal-dual variable neighborhood search for the simple plant-location problem
Copyright @ 2007 INFORMSThe variable neighborhood search metaheuristic is applied to the primal simple plant-location problem and to a reduced dual obtained by exploiting the complementary slackness conditions. This leads to (i) heuristic resolution of (metric) instances with uniform fixed costs, up to n = 15,000 users, and m = n potential locations for facilities with an error not exceeding 0.04%; (ii) exact solution of such instances with up to m = n = 7,000; and (iii) exact solutions of instances with variable fixed costs and up to m = n = 15, 000.This work is supported by NSERC Grant 105574-02; NSERC Grant OGP205041; and partly by the Serbian Ministry of Science, Project 1583
Screened electrostatic interactions between clay platelets
An effective pair potential for systems of uniformly charged lamellar
colloids in the presence of an electrolytic solution of microscopic co- and
counterions is derived. The charge distribution on the discs is expressed as a
collection of multipole moments, and the tensors which determine the
interactions between these multipoles are derived from a screened Coulomb
potential. Unlike previous studies of such systems, the interaction energy may
now be expressed for discs at arbitrary mutual orientation. The potential is
shown to be exactly equivalent to the use of linearized Poisson-Boltzmann
theory.Comment: 23 pages, 10 figures, created with Revtex. To appear in Molecular
Physic
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