24 research outputs found

    Post-mortem volatiles of vertebrate tissue

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    Volatile emission during vertebrate decay is a complex process that is understood incompletely. It depends on many factors. The main factor is the metabolism of the microbial species present inside and on the vertebrate. In this review, we combine the results from studies on volatile organic compounds (VOCs) detected during this decay process and those on the biochemical formation of VOCs in order to improve our understanding of the decay process. Micro-organisms are the main producers of VOCs, which are by- or end-products of microbial metabolism. Many microbes are already present inside and on a vertebrate, and these can initiate microbial decay. In addition, micro-organisms from the environment colonize the cadaver. The composition of microbial communities is complex, and communities of different species interact with each other in succession. In comparison to the complexity of the decay process, the resulting volatile pattern does show some consistency. Therefore, the possibility of an existence of a time-dependent core volatile pattern, which could be used for applications in areas such as forensics or food science, is discussed. Possible microbial interactions that might alter the process of decay are highlighted

    Short-Lived Trace Gases in the Surface Ocean and the Atmosphere

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    The two-way exchange of trace gases between the ocean and the atmosphere is important for both the chemistry and physics of the atmosphere and the biogeochemistry of the oceans, including the global cycling of elements. Here we review these exchanges and their importance for a range of gases whose lifetimes are generally short compared to the main greenhouse gases and which are, in most cases, more reactive than them. Gases considered include sulphur and related compounds, organohalogens, non-methane hydrocarbons, ozone, ammonia and related compounds, hydrogen and carbon monoxide. Finally, we stress the interactivity of the system, the importance of process understanding for modeling, the need for more extensive field measurements and their better seasonal coverage, the importance of inter-calibration exercises and finally the need to show the importance of air-sea exchanges for global cycling and how the field fits into the broader context of Earth System Science

    A novel data-driven algorithm for the automated detection of unexpectedly high traffic flow in uncongested traffic states

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    We present an algorithm to identify days that exhibit the seemingly paradoxical behaviour of high traffic flow and, simultaneously, a striking absence of traffic jams. We introduce the notion of high-performance days to refer to these days. The developed algorithm consists of three steps: step 1, based on the fundamental diagram (i.e. an empirical relation between the traffic flow and traffic density), we estimate the critical speed by using robust regression as a tool for labelling congested and uncongested data points; step 2, based on this labelling of the data, the breakdown probability can be estimated (i.e. the probability that the average speed drops below the critical speed); step 3, we identify unperturbed moments (i.e. moments when a breakdown is expected, but does not occur) and subsequently identify the high-performance days based on the number of unperturbed moments. Identifying high-performance days could be a building block in the quest for traffic jam reduction; using more detailed data one might be able to identify specific characteristics of high-performance days. The algorithm is applied to a case study featuring the highly congested A15 motorway in the Netherlands
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