18 research outputs found
EARLY STAGES OF LIGNITE FORMATION IN PTOLEMAIS BASIN: A COAL-PETROGRAPHIC APPROACH
With the present study it is intended to assess the depositional palaeoenvironment of the lower part of the Lignite-bearing Sequence in the Ptolemais Basin, and more specifically in the areas of Notio-Field and Tomeas-6 open pits. The sediments under study represent the seam between the Volcanic Tephra Layer and the Basal Marl, which constitute the roof and the floor, respectively. Coal-petrographic results showed that Huminite is the main macerai group (84-96%), while macérais from Liptinite and Inertinite groups display low values (<10%). In bulk lignite samples the main mineral phases are quartz, calcite, clay minerals and feldspars, while in the ashes the main phases are quartz, anhydrite and lime. The palaeoenvironment of the lignite formation was reconstructed using the lithological, coalpetrographic and mineralogical data, as well as coal-facies diagrammes. In Notio-Field Mine, at the early stages of lignite formation the conditions used to be limnotelmatic, while in Tomeas-6 Mine they were telmatic. Upwards the conditions turned to more telmatic in both mine areas. The vegetation was mainly herbaceous with some arboreal elements occurring mostly in Tomeas-6 area. The water influx was generally intense resulting in enhanced inorganic inpu
COMBUSTION AND LEACHING BEHAVIOR OF TRACE ELEMENTS IN LIGNITE AND COMBUSTION BY-PRODUCTS FROM THE MUĞLA BASIN, SW TURKEY
The Muğla Basin is one of the most well-documented coal basins of Anatolia, SW Turkey. Previous studies mainly focused on coal geology, as well as on the environmental impacts from trace elements emitted into the atmosphere during coal combustion. However, the environmental impacts from coal utilization also include groundwater contamination from hazardous trace elements leached from exposed lignite stockpiles or ash disposal dumps. In the present study a comparative assessment of the combustion, as well as the leaching behaviour of trace elements from sixteen lignite, fly ash and bottom ash samples under various pH conditions is attempted. The samples were picked up from three regions in the Muğla Basin, namely, these of Yeniköy, Kemerköy and Yatağan. Proximate and ultimate analyses were performed on all samples. Quantitative mineralogical analysis was carried out using a Rietveld-based full pattern fitting technique. The elements Ag, As, B, Ba, Be, Co, Cr, Cu, Fe, Ga, Hf, Li, Mn, Mo, Ni, Pb, Sr, U, V and Zn were grouped according to their volatility during combustion and their leachability in the various types of samples. The pH of the leaching agent little affected the leaching trends of most elements and the mode of occurrence proved to be the major factor controlling primarily combustion and to a lesser extent leaching. The elements were classified into 7 classes with increasing environmental significance with Mo, Sr and V being the most potentially hazardous trace elements in the Muğla region
Development of a petrographic classification of fly-ash components from coal combustion and co-combustion. (An ICCP Classification System, Fly-Ash Working Group – Commission III.)
A new system for the microscopic classification of fly-ash components has been developed by the Fly-Ash Working Group, Commission III of the ICCP and is presented herein. The studied fly-ashes were obtained from the combustion of single coals of varied rank, coal blends, and coals blended with other fuels (biomass, petroleum coke), in different operating conditions and by means of different technologies. Microscopic images of the fly-ash samples were used to test the optical criteria proposed for classifying the fly-ash components. The classification system developed is based on a small number of microscopic criteria, subdivided into six independent levels or categories, three of which are directed at whole particle identification on the basis of nature, origin and type of fly-ash particle, while the other three levels are directed at the smaller section identification on the basis of character, structure and optical texture of unburned carbons. To classify the inorganic components of the fly-ash, the criterion proposed is composition in terms of metallic/non-metallic character. To establish the classification criteria the petrographers involved in the work performed three successive round robins. Evaluation of the results by using firstly descriptive statistics and then the criteria and parameters employed by the ICCP in their accreditation programs indicated that the classification of the fly-ash components was accurate and that there was only a minor bias. The main conclusion of this study was that the proposed criteria are valuable for identifying, and classifying fly-ash components and for describing the optical properties of fly-ash particles
Late Cretaceous coal overlying karstic bauxite deposits in the Parnassus-Ghiona Unit, Central Greece: Coal characteristics and depositional environment
The Pera-Lakkos coal located on top of bauxite deposits in the Ghiona mining district (Central Greece), is the only known Mesozoic (Late Cretaceous) coal in the country. It was derived from herbaceous plants and algae growing in mildly brackish mires that formed behind a barrier system during a regression of the sea, on a karstified limestone partly filled in with bauxitic detritus. Petrological, mineralogical and geochemical data point to the predominance of reducing conditions and intense organic matter degradation in the palaeomires. O/C vs. H/C and OI vs. HI plots, based on elemental analysis and Rock-Eval data, characterize kerogen types I/II. This reflects the relatively high liptinite content of the coal. Besides kerogen composition, O/C vs. H/C plot for the Pera-Lakkos coals is in accordance with a catagenesis stage of maturation in contrast with vitrinite reflectance and Tmax from Rock-Eval pyrolysis, which indicate the onset of oil window maturation stage. Suppression of vitrinite reflectance should be considered and the high liptinite content corroborates this hypothesis. Despite some favourable aspects for petroleum generation presented by the Pera-Lakkos coal, its maximum thickness (up to 50cm) points to a restricted potential for petroleum generation. Coal oxidation took place either during the late stage of peat formation, due to wave action accompanying the subsequent marine transgression, or epigenetically after the emergence of the whole sequence due to percolation of drainage waters. Both options are also supported by the REE shale-normalized profiles, which demonstrate an upwards depletion in the coal layer. Oxidation also affected pyrite included in the coal; this led to the formation of acidic (sulfate-rich) solutions, which percolated downwards resulting in bleaching of the upper part of the underlying bauxite. © 2009 Elsevier B.V
Grape Maturity Estimation for Personalized Agrobot Harvest by Fuzzy Lattice Reasoning (FLR) on an Ontology of Constraints
Sustainable agricultural production, under the current world population explosion, calls for agricultural robot operations that are personalized, i.e., locally adjusted, rather than en masse. This work proposes implementing such operations based on logic in order to ensure that a reasonable operation is applied locally. In particular, the interest here is in grape harvesting, where a binary decision has to be taken regarding the maturity of a grape in order to harvest it or not. A Boolean lattice ontology of inequalities is considered regarding three grape maturity indices. Then, the established fuzzy lattice reasoning (FLR) is applied by the FLRule method. Comparative experimental results on real-world data demonstrate a good maturity prediction. Other advantages of the proposed method include being parametrically tunable, as well as exhibiting explainable decision-making with either crisp or ambiguous input measurements. New mathematical results are also presented