Current induced light emission and light induced current in molecular tunneling junctions

The interaction of metal-molecule-metal junctions with light is considered within a simple generic model. We show, for the first time, that light induced current in unbiased junctions can take place when the bridging molecule is characterized by a strong charge-transfer transition. The same model shows current induced light emission under potential bias that exceeds the molecular excitation energy. Results based on realistic estimates of molecular-lead coupling and molecule-radiation field interaction suggest that both effects should be observable.Comment: 5 pages, 3 figures, RevTeX

Development of a magneforming process for the fabrication of thin-wall tungsten cylinders final report

Magneforming process - high energy rate metal forming technique for fabrication of thin wall tungsten cylinder

A Rigorous Derivation of Electromagnetic Self-force

During the past century, there has been considerable discussion and analysis of the motion of a point charge, taking into account "self-force" effects due to the particle's own electromagnetic field. We analyze the issue of "particle motion" in classical electromagnetism in a rigorous and systematic way by considering a one-parameter family of solutions to the coupled Maxwell and matter equations corresponding to having a body whose charge-current density $J^a(\lambda)$ and stress-energy tensor $T_{ab} (\lambda)$ scale to zero size in an asymptotically self-similar manner about a worldline $\gamma$ as $\lambda \to 0$. In this limit, the charge, $q$, and total mass, $m$, of the body go to zero, and $q/m$ goes to a well defined limit. The Maxwell field $F_{ab}(\lambda)$ is assumed to be the retarded solution associated with $J^a(\lambda)$ plus a homogeneous solution (the "external field") that varies smoothly with $\lambda$. We prove that the worldline $\gamma$ must be a solution to the Lorentz force equations of motion in the external field $F_{ab}(\lambda=0)$. We then obtain self-force, dipole forces, and spin force as first order perturbative corrections to the center of mass motion of the body. We believe that this is the first rigorous derivation of the complete first order correction to Lorentz force motion. We also address the issue of obtaining a self-consistent perturbative equation of motion associated with our perturbative result, and argue that the self-force equations of motion that have previously been written down in conjunction with the "reduction of order" procedure should provide accurate equations of motion for a sufficiently small charged body with negligible dipole moments and spin. There is no corresponding justification for the non-reduced-order equations.Comment: 52 pages, minor correction

Emergent Geometry and Quantum Gravity

We explain how quantum gravity can be defined by quantizing spacetime itself. A pinpoint is that the gravitational constant G = L_P^2 whose physical dimension is of (length)^2 in natural unit introduces a symplectic structure of spacetime which causes a noncommutative spacetime at the Planck scale L_P. The symplectic structure of spacetime M leads to an isomorphism between symplectic geometry (M, \omega) and Riemannian geometry (M, g) where the deformations of symplectic structure \omega in terms of electromagnetic fields F=dA are transformed into those of Riemannian metric g. This approach for quantum gravity allows a background independent formulation where spacetime as well as matter fields is equally emergent from a universal vacuum of quantum gravity which is thus dubbed as the quantum equivalence principle.Comment: Invited Review for Mod. Phys. Lett. A, 17 page

Descriptors for terpene esters from chromatographic and partition measurements: Estimation of human odor detection thresholds

We have used gas chromatographic retention data together with other data to obtain Abraham descriptors for 30 terpene esters. These include the air-water partition coefficient, as log Kw, for which no experimental values are available for any terpene ester. The other descriptors are the ester dipolarity, S, the hydrogen bond basicity, B, (the ester hydrogen bond acidity is zero for the esters studied), and L the logarithm of the air-hexadecane partition coefficient. Both S and B are larger than those for simple aliphatic esters, as expected from the terpene ester structures that include ring systems and ethylenic double bonds. These descriptors can then be used to obtain a large number of physicochemical and environmental properties of terpene esters. We have analyzed experimental results on human odor detection thresholds and have constructed another equation for the calculation of these thresholds, to go with a previous equation that we have reported. Then the descriptors for terpene esters can be used to estimate the important odor detection thresholds

Addenda and corrections to work done on the path-integral approach to classical mechanics

In this paper we continue the study of the path-integral formulation of classical mechanics and in particular we better clarify, with respect to previous papers, the geometrical meaning of the variables entering this formulation. With respect to the first paper with the same title, we {\it correct} here the set of transformations for the auxiliary variables $\lambda_{a}$. We prove that under this new set of transformations the Hamiltonian ${\widetilde{\cal H}}$, appearing in our path-integral, is an exact scalar and the same for the Lagrangian. Despite this different transformation, the variables $\lambda_{a}$ maintain the same operatorial meaning as before but on a different functional space. Cleared up this point we then show that the space spanned by the whole set of variables ($\phi, c, \lambda,\bar c$) of our path-integral is the cotangent bundle to the {\it reversed-parity} tangent bundle of the phase space ${\cal M}$ of our system and it is indicated as $T^{\star}(\Pi T{\cal M})$. In case the reader feel uneasy with this strange {\it Grassmannian} double bundle, we show in this paper that it is possible to build a different path-integral made only of {\it bosonic} variables. These turn out to be the coordinates of $T^{\star}(T^{\star}{\cal M})$ which is the double cotangent bundle of phase-space.Comment: Title changed, appendix expanded, few misprints fixe

Resonance Zones and Lobe Volumes for Volume-Preserving Maps

We study exact, volume-preserving diffeomorphisms that have heteroclinic connections between a pair of normally hyperbolic invariant manifolds. We develop a general theory of lobes, showing that the lobe volume is given by an integral of a generating form over the primary intersection, a subset of the heteroclinic orbits. Our definition reproduces the classical action formula in the planar, twist map case. For perturbations from a heteroclinic connection, the lobe volume is shown to reduce, to lowest order, to a suitable integral of a Melnikov function.Comment: ams laTeX, 8 figure

Casimir interactions in Ising strips with boundary fields: exact results

An exact statistical mechanical derivation is given of the critical Casimir forces for Ising strips with arbitrary surface fields applied to edges. Our results show that the strength as well as the sign of the force can be controled by varying the temperature or the fields. An interpretation of the results is given in terms of a linked cluster expansion. This suggests a systematic approach for deriving the critical Casimir force which can be used in more general models.Comment: 10 pages, 4 figure

Dutch Elm Disease in Iowa

Where does DED come from? How bad is it in Iowa? Here are some answers and some ways of beating this destructive disease

Plant Disease Outlook for 1969

Knowledge of carryover inoculum is by itself insufficient to predict this year\u27s disease attacks. Two botanists and plant pathologists analyze a number of environmental factors in recommending preventive control measures for 1969