Salting our Freshwater Lakes

The highest densities of lakes on Earth are in north temperate ecosystems, where increasing urbanization and associated chloride runoff can salinize freshwaters and threaten lake water quality and the many ecosystem services lakes provide. However, the extent to which lake salinity may be changing at broad spatial scales remains unknown, leading us to first identify spatial patterns and then investigate the drivers of these patterns. Significant decadal trends in lake salinization were identified using a dataset of long-term chloride concentrations from 371 North American lakes. Landscape and climate metrics calculated for each site demonstrated that impervious land cover was a strong predictor of chloride trends in Northeast and Midwest North American lakes. As little as 1% impervious land cover surrounding a lake increased the likelihood of long-term salinization. Considering that 27% of large lakes in the United States have \u3e1% impervious land cover around their perimeters, the potential for steady and long-term salinization of these aquatic systems is high. This study predicts that many lakes will exceed the aquatic life threshold criterion for chronic chloride exposure (230 mg L−1), stipulated by the US Environmental Protection Agency (EPA), in the next 50 y if current trends continue

LakeMetabolizer: An R package for estimating lake metabolism from free-water oxygen using diverse statistical models

Metabolism is a fundamental process in ecosystems that crosses multiple scales of organization from individual organisms to whole ecosystems. To improve sharing and reuse of published metabolism models, we developed LakeMetabolizer, an R package for estimating lake metabolism from in situ time series of dissolved oxygen, water temperature, and, optionally, additional environmental variables. LakeMetabolizer implements 5 different metabolism models with diverse statistical underpinnings: bookkeeping, ordinary least squares, maximum likelihood, Kalman filter, and Bayesian. Each of these 5 metabolism models can be combined with 1 of 7 models for computing the coefficient of gas exchange across the air–water interface (k). LakeMetabolizer also features a variety of supporting functions that compute conversions and implement calculations commonly applied to raw data prior to estimating metabolism (e.g., oxygen saturation and optical conversion models). These tools have been organized into an R package that contains example data, example use-cases, and function documentation. The release package version is available on the Comprehensive R Archive Network (CRAN), and the full open-source GPL-licensed code is freely available for examination and extension online. With this unified, open-source, and freely available package, we hope to improve access and facilitate the application of metabolism in studies and management of lentic ecosystems

Data Descriptor : Long-term chloride concentrations in North American and European freshwater lakes

Anthropogenic sources of chloride in a lake catchment, including road salt, fertilizer, and wastewater, can elevate the chloride concentration in freshwater lakes above background levels. Rising chloride concentrations can impact lake ecology and ecosystem services such as fisheries and the use of lakes as drinking water sources. To analyze the spatial extent and magnitude of increasing chloride concentrations in freshwater lakes, we amassed a database of 529 lakes in Europe and North America that had greater than or equal to ten years of chloride data. For each lake, we calculated climate statistics of mean annual total precipitation and mean monthly air temperatures from gridded global datasets. We also quantified land cover metrics, including road density and impervious surface, in buffer zones of 100 to 1,500m surrounding the perimeter of each lake. This database represents the largest global collection of lake chloride data. We hope that long-term water quality measurements in areas outside Europe and North America can be added to the database as they become available in the future.Peer reviewe

Geophysics, Water Balance, and History of Thick Perennial Ice Covers on Antarctic Lakes

Antarctic lakes are studied as sentinels of future change, for paleolimnological records contained in the sediments, and as habitats for the simple food webs that can exist in inhospitable environments. Understanding how lakes are formed and are sustained in response to landscape and climate conditions is critical in addressing the aforementioned research themes. This thesis is governed by the overarching hypothesis that an understanding of hydrologic and sediment transport processes associated with lake ice formation and preservation can be used to reveal past climatic changes, and further our awareness of current changes in climate and water balance in the McMurdo Dry Valleys of Antarctica. The first chapter focuses on water loss from closed basin lakes in Taylor Valley, Antarctica, and presents updated estimates of sublimation and ablation rates from long-term empirical measurements. The second and third chapters address the formation of Lake Vida, Antarctica. The former investigates the accretion of a 27 m ice cover, and considers the origin of thick sediment layers in the ice cover, and the latter uses two geophysical methods to quantify the extent and volume of the brine network in the subsurface beneath the lake. The results presented herein advance the study of hydrogeology in continuous permafrost, provide additional evidence for fluctuating climate states in the McMurdo Dry Valleys throughout the mid to late Holocene, and provide a case study for the preservation of water in a cold, desert environment analogous to neighboring planets

The slow and steady salinization of Sparkling Lake, Wisconsin

The concentrations of conservative solutes in seepage lakes are determined by the relative inputs of precipitation vs. groundwater. In areas of road salt application, seepage lakes may be at high risk of salinization depending on groundwater flow. Here, we revisit a 1992 analysis on the salinization of Sparkling Lake, a deep seepage lake in Northern Wisconsin. The original analysis predicted a rapid increase in chloride concentrations before reaching a steady steady of 8 mg L−1 by 2020. Forty years of monitoring Sparkling Lake show that rather than reaching a dynamic equilibrium, chloride concentrations have steadily increased. We update the original box model approach by adding a soil reservoir component that shows the slow steady rise in chloride is the result of terrestrial retention. For freshwater rivers and lakes, chloride retention on the landscape will both delay chloride impairment and prolong recovery and must be considered when modeling future chloride contamination risk

High-Resolution Ground-Penetrating Radar Profiles of Perennial Lake Ice in the McMurdo Dry Valleys, Antarctica: Horizon Attributes, Unconformities, and Subbottom

Ground-penetrating radar (GPR) is not commonly used to study lake ice, and in general, the ground-based use of radar frequencies greater than 500 MHz in cryosphere geophysics is rare, due to a general interest in deeper stratigraphy and the difficulty of extensive profiling over rough snow surfaces. Our goal was to find further information on the origin of the deposition and formation of intra-ice layers, bottom topography, and subbottom deposits using GPR with pulses centered near 850 MHz on two permanently ice-covered lakes in the Mc- Murdo Dry Valleys, Antarctica. The profiles were obtained using a one-person sled operation over Lake Bonney, which is typical of lakes in the region, having an ice thickness that ranges between 3 and 5 m, and Lake Vida, where the maximum ice depth is at least 27 m. Lake Bonney exhibits a semicontinuous sediment horizon at approximately a 2-m depth and several minor horizons. In contrast, Lake Vida contains unconformably eroded and folded continuous reflection horizons, packages of minor horizons between major horizons, evidence of incised fluvial deposition along the bottom, and subbottom penetration of at least 4.5 m in some areas. Where the ice thickness is less than 20 m, the lake is frozen to the bottom. Most horizon waveform phase attributes indicate relatively lower permittivity than in the surrounding matrix. Consequently, we interpreted these strata to be caused by layers of pure ice embedded within a salty and dirty ice matrix, which were formed during minor flooding. These findings supported previous conclusions that Lake Vida ice formed from surface runoff in combination with periods of ablation

Impact of salinization on lake stratification and spring mixing

Abstract Anthropogenic freshwater salinization affects thousands of lakes worldwide, and yet little is known about how salt loading may shift timing of lake stratification and spring mixing in dimictic lakes. Here, we investigate the impact of salinization on mixing in Lakes Mendota and Monona, Wisconsin, by deploying under‐ice buoys to record salinity gradients, using an analytical approach to quantify salinity thresholds that prevent spring mixing, and running an ensemble of vertical one‐dimensional hydrodynamic lake models (GLM, GOTM, and Simstrat) to investigate the long‐term impact of winter salt loading on mixing and stratification. We found that spring salinity gradients between surface and bottom waters persist up to a month after ice‐off, and that theory predicts a salinity gradient of 1.3–1.4 g kg−1 would prevent spring mixing. Numerical models project that salt loading delays spring mixing and increases water column stability, with ramifications for oxygenation of bottom waters, biogeochemistry, and lake habitability

Ice Formation and the Risk of Chloride Toxicity in Shallow Wetlands and Lakes

The process of ice formation in shallow waterbodies can increase chloride to toxic levels in waterbodies already impacted by chloride loading from road salt (NaCl deicer) application. Chloride concentrations were measured bi-weekly in a shallow, urban wetland in Madison, Wisconsin. We found that in this shallow waterbody, ice thickening doubled chloride concentrations from ion exclusion as the water froze. To understand the role of ice formation and ion exclusion, we constructed a numerical model to predict chloride concentrations beneath the ice resulting from ion exclusion. Where chloride levels already are elevated above background and flushing rates are low, ice thickening can push concentrations well above toxicity thresholds for much of the winter. The compounding effects of road salt runoff and ice formation should be considered in the management of water quality and ecosystem health in shallow urban water bodies or waterbodies receiving road salt runoff from nearby roadways

Ice Formation and the Risk of Chloride Toxicity in Shallow Wetlands and Lakes

The process of ice formation in shallow waterbodies can increase chloride to toxic levels in waterbodies already impacted by chloride loading from road salt (NaCl deicer) application. Chloride concentrations were measured bi-weekly in a shallow, urban wetland in Madison, Wisconsin. We found that in this shallow waterbody, ice thickening doubled chloride concentrations from ion exclusion as the water froze. To understand the role of ice formation and ion exclusion, we constructed a numerical model to predict chloride concentrations beneath the ice resulting from ion exclusion. Where chloride levels already are elevated above background and flushing rates are low, ice thickening can push concentrations well above toxicity thresholds for much of the winter. The compounding effects of road salt runoff and ice formation should be considered in the management of water quality and ecosystem health in shallow urban water bodies or waterbodies receiving road salt runoff from nearby roadways