Properties of model E-glass fiber composites with varying matrix monomer ratios

ObjectiveTo evaluate properties of fiber-reinforced-composites (FRC) containing Bis-EMA/UDMA monomers but identical dispersed phase (60% wt BaSi glass power +10% wt E-glass fibre).MethodsA control (Group A), monomer mixture comprising 60% Bis-GMA, 30% TEGDMA, and 10% PMMA (typical FRC monomers) was used. The following monomer mass fractions were mixed: 50% bis-GMA plus 50% of different ratios of Bis-EMA+UDMA to produce consistent formulations (Groups B-E) of workable viscosities was also studied. Flexural strength (FS), fracture toughness (KIC), water sorption (SP), solubility (SL) and hygroscopic expansion (HE) were measured. FS and KIC specimens were stored for 1, 7 d, and 30 d in water at 37 °C. SP/SL specimens were water-immersed for 168d, weighed at intervals, then dried for 84 d at 37 °C. To analyze differences in FS, and KIC, a two-way ANOVA and Tukey post-hoc tests (α = 0.05) were conducted. For SP/SL, and HE, one-way ANOVA with subsequent Tukey post-hoc tests (α = 0.05) were utilized.ResultsFS and KIC for groups A, D, E decreased progressively after 1 d. Groups B and C (highest amounts of Bis-EMA) did not decrease significantly. The modified matrix composites performed significantly better than the control group for SP and HE. The control group outperformed the experimental composites only for SL with up to 250% higher SL for group E (6.9 μg/mm) but still below the maximum permissible threshold of 7.5 μg/mm. Significance:Experimentalcomposites with highest amounts of Bis-EMA showed improved hydrolytic stability and overall enhancement in several clinically-relevant properties. This makes them potential candidates for alternative matrices to a semi-interpenetrating network in fiber-reinforced composites

NN^k networks for Content-Based Image Retrieval

This paper describes a novel interaction technique to support content-based image search in large image collections. The idea is to represent each image as a vertex in a directed graph. Given a set of image features, an arc is established between two images if there exists at least one combination of features for which one image is retrieved as the nearest neighbour of the other. Each arc is weighted by the proportion of feature combinations for which the nearest neighbour relationship holds. By thus integrating the retrieval results over all possible feature combinations, the resulting network helps expose the semantic richness of images and thus provides an elegant solution to the problem of feature weighting in content-based image retrieval.We give details of the method used for network generation and describe the ways a user can interact with the structure. We also provide an analysis of the network’s topology and provide quantitative evidence for the usefulness of the technique

Shrinkage strain – Rates study of dental composites based on (BisGMA/TEGDMA) monomers

AbstractThe viscosity of the initial monomer mixture and the chemical structure of the monomers are both important variables in the kinetic behavior of resin composites. This paper aims to determine the effect of opaque mineral fillers and monomer ratios on the shrinkage strain-rate and time at maximum shrinkage strain (Smax) rate, of experimental composites based on (BisGMA/TEGDMA) monomers. Polymerization shrinkage and the degree of conversion (DC) of resin composites are closely related manifestations of the same process. The proportionality of these two properties was also investigated by studying the variation of the ratio: (total shrinkage strain/degree of conversion): (Smax/DC), as a function of mineral filler contents and monomer ratios.Resin composites were prepared by mixing different monomer ratios of (BisGMA/TEGDMA) with camphoroquinone and dimethyl aminoethyl methacrylate (DMAEMA) as photo-initiator system. Five different radiopacifying filler agents: La2O3, BaO, BaSO4,·SrO and ZrO2 at various volume fractions ranging from 0 to 80wt.% were added. The samples were cured at ca. 550mW/cm2. The shrinkage strain-rate, was calculated from the derivative of shrinkage strain using numerical differentiation. The shrinkage strain was measured by the bonded-disk technique at room temperature. Degree of conversion was calculated using FTIR/ATR spectroscopy.The results revealed that the fraction of opaque filler had no significant effect on the shrinkage strain-rate and on the time at maximum shrinkage strain-rate but these two parameters are closely related to the monomer ratios and viscosity of the organic matrix. The results have confirmed the proportionality of the shrinkage strain and DC and showed that the filler contents and monomer ratios would not affect this proportionality

Immediate performance of self-etching versus system adhesives with multiple light-activated restoratives

Objectives: The purpose of this study was to evaluate the performance of both single and double applications of (Adper Prompt L-Pop) self-etching dental adhesive, when used with three classes of light-activated restorative materials, in comparison to the performance of each restorative system adhesive. Evaluation parameters to be considered for the adhesive systems were (a) immediate marginal adaptation (or gap formation) in tooth cavities, (b) free setting shrinkage-strain determined by the immediate marginal gap-width in a non-bonding Teflon cavity, and (c) their immediate shear bond-strengths to enamel and to dentin. Methods: The maximum marginal gap-width and the opposing-width (if any) in the tooth cavities and in the Teflon cavities were measured immediately (3 min) after light-activation. The shear bond-strengths to enamel and to dentin were also measured at 3 min. Results: For light-activated restorative materials during early setting (&#60;3 min), application of Adper Prompt L-Pop exhibited generally superior marginal adaptation to most system adhesives. But there was no additional benefit from double application. The marginal-gaps in tooth cavities and the marginal-gaps in Teflon cavities were highly correlated (r=0.86–0.89, p&#60;0.02–0.01). For enamel and dentin shear bond-strengths, there were no significant differences between single and double applications, for all materials tested except Toughwell and Z 250 with enamel. Significance: Single application of a self-etch adhesive was a feasible and beneficial alternative to system adhesives for several classes of restorative. Marginal gap-widths in tooth cavities correlated more strongly with free shrinkage-strain magnitudes than with bond-strengths to tooth structure.</p

Dietary iron intakes based on food composition data may underestimate the contribution of potentially exchangeable contaminant iron from soil

Iron intakes calculated from one-day weighed records were compared with those from same day analyzed duplicate diet composites collected from 120 Malawian women living in two rural districts with contrasting soil mineralogy and where threshing may contaminate cereals with soil iron. Soils and diet composites from the two districts were then subjected to a simulated gastrointestinal digestion and iron availability in the digests measured using a Caco-2 cell model. Median analyzed iron intakes (mg/d) were higher (p < 0.001) than calculated intakes in both Zombwe (16.6 vs. 10.1 mg/d) and Mikalango (29.6 vs. 19.1 mg/d), attributed to some soil contaminant iron based on high Al and Ti concentrations in diet composites. A small portion of iron in acidic soil from Zombwe, but not Mikalango calcareous soil, was bioavailable, as it induced ferritin expression in the cells, and may have contributed to higher plasma ferritin and total body iron for the Zombwe women reported earlier, despite lower iron intakes. In conclusion, iron intakes calculated from food composition data were underestimated, highlighting the importance of analyzing duplicate diet composites where extraneous contaminant iron from soil is likely. Acidic contaminant soil may make a small but useful contribution to iron nutrition

Statistical mechanics of topological phase transitions in networks

We provide a phenomenological theory for topological transitions in restructuring networks. In this statistical mechanical approach energy is assigned to the different network topologies and temperature is used as a quantity referring to the level of noise during the rewiring of the edges. The associated microscopic dynamics satisfies the detailed balance condition and is equivalent to a lattice gas model on the edge-dual graph of a fully connected network. In our studies -- based on an exact enumeration method, Monte-Carlo simulations, and theoretical considerations -- we find a rich variety of topological phase transitions when the temperature is varied. These transitions signal singular changes in the essential features of the global structure of the network. Depending on the energy function chosen, the observed transitions can be best monitored using the order parameters Phi_s=s_{max}/M, i.e., the size of the largest connected component divided by the number of edges, or Phi_k=k_{max}/M, the largest degree in the network divided by the number of edges. If, for example the energy is chosen to be E=-s_{max}, the observed transition is analogous to the percolation phase transition of random graphs. For this choice of the energy, the phase-diagram in the [,T] plane is constructed. Single vertex energies of the form E=sum_i f(k_i), where k_i is the degree of vertex i, are also studied. Depending on the form of f(k_i), first order and continuous phase transitions can be observed. In case of f(k_i)=-(k_i+c)ln(k_i), the transition is continuous, and at the critical temperature scale-free graphs can be recovered.Comment: 12 pages, 12 figures, minor changes, added a new refernce, to appear in PR