The Anomalous Behavior of Solid 4^{4}He in Porous Vycor Glass

The low temperature properties of solid $^4$He contained in porous Vycor glass have been investigated utilizing a two-mode compound torsional oscillator. At low temperatures, we find period shift signals for the solid similar to those reported by Kim and Chan \cite{ref1}, which were taken at the time as evidence for a supersolid helium phase. The supersolid is expected to have properties analogous to those of a conventional superfluid, where the superfluid behavior is independent of frequency and the ratio of the superfluid signals observed at two different mode periods will depend only on the ratio of the sensitivities of the mode periods to mass-loading. In the case of helium studies in Vycor, one can compare the period shift signals seen for a conventional superfluid film with signals obtained for a supersolid within the same Vycor sample. We find, contrary to our own expectations, that the signals observed for the solid display a marked period dependence not seen in the case of the superfluid film. This surprising result suggests that the low temperature response of solid $^4$He in a Vycor is more complex than previously assumed and cannot be thought of as a simple superfluid.Comment: 4 pages, 5 figure

Probing Coherent Vibrations of Organic Phosphonate Radical Cations with Femtosecond Time-Resolved Mass Spectrometry

Organic phosphates and phosphonates are present in a number of cellular components that can be damaged by exposure to ionizing radiation. This work reports femtosecond time-resolved mass spectrometry (FTRMS) studies of three organic phosphonate radical cations that model the DNA sugar-phosphate backbone: dimethyl methylphosphonate (DMMP), diethyl methylphosphonate (DEMP), and diisopropyl methylphosphonate (DIMP). Upon ionization, each molecular radical cation exhibits unique oscillatory dynamics in its ion yields resulting from coherent vibrational excitation. DMMP has particularly well-resolved 45 fs (732 ± 28 cm−1) oscillations with a weak feature at 610–650 cm−1, while DIMP exhibits bimodal oscillations with a period of ∼55 fs and two frequency features at 554 ± 28 and 670–720 cm−1. In contrast, the oscillations in DEMP decay too rapidly for effective resolution. The low- and high-frequency oscillations in DMMP and DIMP are assigned to coherent excitation of the symmetric O–P–O bend and P–C stretch, respectively. The observation of the same ionization-induced coherently excited vibrations in related molecules suggests a possible common excitation pathway in ionized organophosphorus compounds of biological relevance, while the distinct oscillatory dynamics in each molecule points to the potential use of FTRMS to distinguish among fragment ions produced by related molecules

Probing Coherent Vibrations of Organic Phosphonate Radical Cations with Femtosecond Time-Resolved Mass Spectrometry

Organic phosphates and phosphonates are present in a number of cellular components that can be damaged by exposure to ionizing radiation. This work reports femtosecond time-resolved mass spectrometry (FTRMS) studies of three organic phosphonate radical cations that model the DNA sugar-phosphate backbone: dimethyl methylphosphonate (DMMP), diethyl methylphosphonate (DEMP), and diisopropyl methylphosphonate (DIMP). Upon ionization, each molecular radical cation exhibits unique oscillatory dynamics in its ion yields resulting from coherent vibrational excitation. DMMP has particularly well-resolved 45 fs (732 ± 28 cm−1) oscillations with a weak feature at 610–650 cm−1, while DIMP exhibits bimodal oscillations with a period of ∼55 fs and two frequency features at 554 ± 28 and 670–720 cm−1. In contrast, the oscillations in DEMP decay too rapidly for effective resolution. The low- and high-frequency oscillations in DMMP and DIMP are assigned to coherent excitation of the symmetric O–P–O bend and P–C stretch, respectively. The observation of the same ionization-induced coherently excited vibrations in related molecules suggests a possible common excitation pathway in ionized organophosphorus compounds of biological relevance, while the distinct oscillatory dynamics in each molecule points to the potential use of FTRMS to distinguish among fragment ions produced by related molecules

X-shaped and Y-shaped Andreev resonance profiles in a superconducting quantum dot

The quasi-bound states of a superconducting quantum dot that is weakly coupled to a normal metal appear as resonances in the Andreev reflection probability, measured via the differential conductance. We study the evolution of these Andreev resonances when an external parameter (such as magnetic field or gate voltage) is varied, using a random-matrix model for the $N\times N$ scattering matrix. We contrast the two ensembles with broken time-reversal symmetry, in the presence or absence of spin-rotation symmetry (class C or D). The poles of the scattering matrix in the complex plane, encoding the center and width of the resonance, are repelled from the imaginary axis in class C. In class D, in contrast, a number $\propto\sqrt{N}$ of the poles has zero real part. The corresponding Andreev resonances are pinned to the middle of the gap and produce a zero-bias conductance peak that does not split over a range of parameter values (Y-shaped profile), unlike the usual conductance peaks that merge and then immediately split (X-shaped profile).Comment: Contribution for the JETP special issue in honor of A.F. Andreev's 75th birthday. 9 pages, 8 figure

Flexible conformable hydrophobized surfaces for turbulent flow drag reduction

In recent years extensive work has been focused onto using superhydrophobic surfaces for drag reduction applications. Superhydrophobic surfaces retain a gas layer, called a plastron, when submerged underwater in the Cassie-Baxter state with water in contact with the tops of surface roughness features. In this state the plastron allows slip to occur across the surface which results in a drag reduction. In this work we report flexible and relatively large area superhydrophobic surfaces produced using two different methods: Large roughness features were created by electrodeposition on copper meshes; Small roughness features were created by embedding carbon nanoparticles (soot) into Polydimethylsiloxane (PDMS). Both samples were made into cylinders with a diameter under 12 mm. To characterize the samples, scanning electron microscope (SEM) images and confocal microscope images were taken. The confocal microscope images were taken with each sample submerged in water to show the extent of the plastron. The hydrophobized electrodeposited copper mesh cylinders showed drag reductions of up to 32% when comparing the superhydrophobic state with a wetted out state. The soot covered cylinders achieved a 30% drag reduction when comparing the superhydrophobic state to a plain cylinder. These results were obtained for turbulent flows with Reynolds numbers 10,000 to 32,500