Petrología y geoquímica de las tonalitas de Villarejo de Montalbán

[ES] Las tonalitas de Villarejo de Montalbán son rocas ricas en biotita en las que se observan segregados más félsicos con abundante titanita. Los datos geoquímicos e isotópicos de roca total ((87Sr/86Sr)300 = 0,7084-0,7089; εNd = -4,79, -4,80) sugieren que el magma tonalítico se formó por fusión de rocas metaígneas de composición básica/intermedia (anfibolitas o granulitas). A su vez, los segregados félsicos parecen haberse formado por acumulación del magma residual diferenciado a partir de una matriz formada sobre todo por plagioclasa y biotita. Las condiciones de cristalización estimadas por geotermobarometría del anfíbol indican temperaturas de 890- 920ºC, y presiones de 1,3-2,4 kbar, las cuales implican niveles aproximados de emplazamiento cercanos a los 5-10 km de profundidad. [EN] The tonalites of Villarejo de Montalbán are biotite-rich rocks showing felsic segregates with abundant titanite. Whole-rock geochemical and isotopic data ((87Sr/86Sr)300 = 0.7084-0.7089; εNd = -4.79, -4.80) suggest that the tonalitic magma was formed by melting of metaigneous rocks of basic/intermediate composition (amphibolites or granulites). At the same time, the felsic segregates seem to have formed through the accumulation of a differentiated residual magma after crystal fractionation of plagioclase and biotite. Crystallization conditions estimated according to amphibole geothermobarometry indicate temperatures between 890 and 920ºC, and pressures in the range 1.3-2.4 kbar, which is in accordance with an approximate emplacement level close to 5-10 km deep.Peer Reviewe

Eclogite facies relics in metabasites from the Sierra de Guadarrama (Spanish Central System): P-T estimations and implications for the Hercynian evolution

Relics of HP-MT eclogitic assemblages related to the first metamorphic stage of the Hercynian orogeny in the Sierra de Guadarrama (Spanish Central System, SCS) are preserved as boudins of pre-Ordovician metabasites enclosed by felsic gneisses. Textures indicate a multi-stage metamorphic history starting in the MT eclogite facies (as deduced from the presence of omphacite and rutile included in garnet) and continuing through medium to low pressure granulite and retrograde amphibolite-greenschist facies. Thermobarometric calculations in the eclogitic paragenesis yield pressures of ~14 kbar for temperatures in the range 725 7758C. Thermobarometry for the subsequent granulitic stage indicates a significant drop in pressure (P < 10 kbar) for similar temperatures of ~7508C. Metabasites vary from gabbro to leucotonalites showing the typical Fe enrichment of the tholeiitic series. Chemical characteristics indicate a derivation from low-pressure crystallization of tholeiitic melts more enriched than typical MORB compositions. Their original location far from continental margins as evidenced by the absence of ophiolitic material in the area and their association with platform sediments suggests that eclogitization was related to intracontinental crustal subduction and thickening. The P-T conditions estimated in the metabasites for the first metamorphic stage are similar to ones deduced for the surrounding metasediments and suggest that the Hercynian crust could have reached a thickness of ~70 80 km, which is more than the double the present thickness

Origin, ore forming fluid evolution and timing of the Logrosán Sn-(W) ore deposits (Central Iberian Zone, Spain)

The Logrosán Sn–(W) ore deposits in the metallogenic Sn–W province of the European Variscan Belt consist of endo- and exogranitic greisen-type and quartz–cassiterite veins associated with a S-type granite. Mineral characterization, fluid inclusion study, isotope geochemistry and Ar–Ar geochronology have been combined in order to reconstruct the conditions for Sn–(W) mineralization. The endo- and exogranitic mineralization must have been developed in a relatively long-lived system (~ 308–303 Ma), during or soon after the emplacement of the Logrosán related-granite (at ca. 308 Ma). The mineralizing fluids are characterized by complex aqueous and volatile (H2O–N2–CO2–CH4–NaCl) fluid inclusions. Microthermometry and Raman analyses indicate that fluid composition evolved from N2–CH4 to N2-rich, followed by CO2-rich fluids, with varying amounts of H2O. The presence of N2 and CH4 suggests the interaction with fluids derived from the nearby metasedimentary host rocks. A model of host-rock interaction, assimilation, and mixing of metamorphic and magmatic fluids, resulting in change of the redox conditions, is proposed for tin deposition. Later sulfide minerals were precipitated as a result of pressure and temperature release

Relaciones entre ortogneises y series volcano-sedimentarias en el macizo de El Caloco (Guadarrama Central)

El macizo de El Caloco está constituido por dos formaciones metamórficas de caracteres distintos. Una es fundamentalmente paradcrivada (metapelitas con niveles carbonatados asociados>, con tramos de origen voleano-sedimentarios o subvolcánico (gneises glandulares fémicos) y que se ha denominado «serie fémica heterogénea». Aparecen también metabasitas con clinopiroxeno, granate y plagioclasa, en parte anfibolitizadas. La otra formación es de naturaleza cuarzo-feldespática y está compuesta por ortogneises glandulares y leucogneises de origen mctagranítico. En función de los caracteres petrológicos y geoquimicos interpretamos los ortogneises cuarzo-feldespáticos como representantes de antiguos granitos de dos micas con silicatos de aluminio (granitos tipo 8). El estudio geoquimico pone de manifiesto en las facies más diferenciadas (leucogneises con nidos de turmalina y/o granate> un trend evolutivo de carácter sílico-potásico. Existe un contacto neto y discordante entre ambos conjuntos, encontrándose localmente facies mosqueadas en los esquistos metapelíticos próximos al mismo.Peer reviewe

Evolución metamórfica del sector centro-septentrional de la Sierra de Guadarrama

Tesis Univ. Complutense de Madrid.Depto. de Mineralogía y PetrologíaFac. de Ciencias GeológicasTRUEProQuestpu

Mineralogical and isotopic characterization of graphite deposits from the Anatectic Complex of Toledo, central Spain

Graphite is found dispersed in high-grade metapelitic rocks of the Anatectic Complex of Toledo (ACT) and was mined during the mid twentieth century in places where it has been concentrated (Guadamur and la Puebla de Montalbán mines). Some samples from these mines show variable but significant alteration intensity, reaching very low-T hydrothermal (supergene) conditions for some samples from the waste heap of the Guadamur site (<100 °C and 1 kbar). Micro-Raman and XRD data indicate that all the studied ACT graphite is of high crystallinity irrespective of the degree of hydrothermal alteration. Chemical differences were obtained for graphite δ13C composition. ACT granulitic graphite shows δ13CPDB values in the range of −20.5 to −27.8 ‰, indicating a biogenic origin. Interaction of graphite with hydrothermal fluids does not modify isotopic compositions even in the most transformed samples from mining sites. The different isotopic signatures of graphite from the mining sites reflect its contrasted primary carbon source. The high crystallinity of studied graphite makes this area of central Spain suitable for graphitic exploration and its potential exploitation, due to the low carbon content required for its viability and its strategic applications in advanced technologies, such as graphene synthesis.This work is included in the objectives of, and supported by, the CGL2012-32822 project of the Ministerio de Economía y Competitividad of Spain and the 910492-UCM group.Peer reviewe

Geochemistry and geochronology of mafic rocks from the Spanish Central System: Constraints on the mantle evolution beneath central Spain

The Spanish Central System (SCS) contains several suites of Palaeozoic mafic igneous intrusions with contrasting geochemical affinity: Ordovician tholeiitic metabasites, Variscan calc-alkaline gabbros (Gb1) and microdiorites (Gb2), shoshonitic monzogabbros (Gb3) and alkaline diabases and lamprophyres (Gb4). Not all of these rocks are accurately dated, and several aspects of their genesis are still poorly understood. We present new whole-rock geochemical data (major and trace elements, and Sr–Nd isotopes), U–Pb and Lu–Hf isotopic ratios on magmatic zircons and 40Ar/39Ar amphibole geochronology results in order to establish a precise chronology for the successive events of magmatism in the SCS, and discuss the nature of their mantle sources. Accurate ages have been determined for the Variscan gabbros (305–294 ​Ma), the microdiorites (299 ​Ma) and the accompanying felsic porphyries (292 ​Ma), the shoshonitic monzogabbros (285 ​Ma), and the alkaline diabases (274 ​Ma) and monzosyenites (271–264 ​Ma). According to this information, the Variscan mafic magmatism would be mainly concentrated in the range of 305–294 ​Ma, with a final manifestation represented by the minor shoshonitic dykes. The alkaline magmatism proved to be slightly older than previously thought and yielded at least two distinct pulses: diabases and lamprophyres–monzosyenites. Zircon Hf isotopes evidence the involvement of depleted and slightly enriched mantle sources. The bulk of the εHf values are in the broad range of −8 to +11, indicative of melting both depleted and enriched mantle regions. The high within-sample Hf isotope variation (up to ~11 epsilon units) shown by samples from the Variscan series (gabbros, microdiorites and monzogabbros) could be explained mainly by hybridisation of magmas derived from heterogeneous lithospheric mantle sources. Pressure estimates indicate that the Variscan mafic magmas were extracted from the lithosphere. The Nd–Hf isotopic composition of these suites of rocks suggests the recycling of pelitic sediments during the Cadomian orogeny. Deeper (asthenospheric) mantle levels were involved in the generation of the alkaline suite, whose anomalous negative εHf values (moderately decoupled with respect to radiogenic Nd) could be associated with subducted oceanic components raised by mantle upwelling associated with lithosphere thinning and extension during the Permian

Xenolitos peridotíticos del volcán Morrón de Villamayor (Campo Volcánico de Calatrava)

The El Morrón de Villamayor (MVM) peridote xenoliths vary from orthopyroxene-poor lherzolite to wehrlite in modal composition. This compositional feature contrasts with other Calatrava (CVF) xenolith suites. The studied xenoliths equilibrated at lower temperatures (618-942 o C) and slightly shallower (8.8-13.6 kbar) conditions than other CVF peridotites. MVM peridotites show local intense interaction with the host leucitite displaying spongy rims around primary clinopyroxene and also reaction zones with K-rich minerals (e.g., sanidine, leucite and richterite) and widespread clinopyroxene, olivine and spinel neoblasts. Nevertheless, the orthopyroxene-poor character of MVM peridotites might be caused by some previous metasomatic eventLos xenolitos peridotíticos del volcán El Morrón de Villamayor (MVM) son lherzolitas pobres en ortopiroxeno y wehrlitas, en contraste con los datos previos de xenolitos de otros volcanes de Calatrava. Las peridotitas estudiadas están equilibradas a temperaturas más bajas (618-942 o C) y menor profundidad (8,8-13,6 kbar) que las estimadas en otras peridotitas del Campo Volcánico de Calatrava. Localmente hay una intensa interacción del fundido leucitítico con los minerales primarios de la peridotita, ya que se originan zonas de reacción con minerales ricos en K (p.ej., sanidina, leucita y richterita) y frecuentes neoblastos de clinopiroxeno, olivino y espinela. El carácter pobre en ortopiroxeno de las peridotitas MVM debe estar causado por algún evento metasomático previ

Geothermobarometric applications of trace-element contents in granulite minerals: Zr-in rutile and HREE-in garnet from lower crustal felsic xenoliths of the Spanish Central System

Geothermobarometric estimations based on the trace element concentration of minerals from lower crustal peraluminous felsic granulite xenoliths from the Spanish Central System (SCS) have been performed. Zr in rutile thermometry (Zack et al., 2004) gives a main range of 970 to 1100 ºC whereas HREE in garnet barometry (Bea et al., 1997) yields a pressure range of 7.2 to 9.3 kbar. These new thermobarometric data overlap previous P-T estimates based on conventional metamorphic phase equilibria. Nevertheless, the slightly higher temperature range obtained with rutile thermometry force to future revision of granulite mineral equilibria of the SCS lower crustal xenolith

Pyroxenites and Megacrysts From Alkaline Melts of the Calatrava Volcanic Field (Central Spain): Inferences From Trace Element Geochemistry and Sr-Nd Isotope Composition

Alkaline volcanic rocks from explosive monogenetic centers often carry an unusual cargo of crystals and rock fragments, which may provide valuable constraints on magma source, ascent and eruption. One of such examples is the Cenozoic Calatrava Volcanic Field in central Spain, a still poorly explored area to address these issues. Clinopyroxene, amphibole and phlogopite appear either as megacryst/phenocrysts or forming fine-grained cumulates (pyroxenite enclaves s.l.) in some eruptive centers of this volcanic field. They have previously been interpreted as cogenetic high-P minerals formed within the upper lithospheric mantle. The presence of Fe-Na-rich green and Mg-Cr-rich colorless clinopyroxene types as phenocryst cores or as oscillatory zoned crystals in pyroxenite enclaves points to a complex evolution of mineral fractionates from petrogenetically related magmas. In trace element chemistry all studied clinopyroxene types show parallel rare earth element patterns irrespective of whether they are megacrysts, colorless or green core phenocrysts, or zoned crystals within pyroxenite cumulates. This similarity indicates a genetic relationship between all the fractionated minerals. This is in agreement with the overlapping of initial 143Nd/144Nd and 87Sr/86Sr ratios of pyroxenite enclaves (0.512793–0.512885 and 0.703268–0.703778) that is within the chemical field of the host magmas and the Calatrava volcanics. The initial 143Nd/144Nd and 87Sr/86Sr ratios of megacrystic clinopyroxene, amphibole and phlogopite show a more restricted range (0.512832–0.512890 and 0.703217–0.703466), also falling within the isotopic composition of the Calatrava volcanic rocks. Deep magmatic systems beneath monogenetic volcanic fields involve several stages of melt accumulation, fractionation and contamination at variable depths. Trace element and isotope mineral chemistry are powerful tools to understand the history of ascent and stagnation of alkaline basaltic magmas and discriminate between magma mixing, wall-rock contamination and closed magmatic system evolution. In our study, we establish a cogenetic origin for green and colorless clinopyroxene as high-pressure precipitates from liquids of different fractionation degrees (up to 80%, for the highly evolved melts equilibrated with the green clinopyroxene), originated from a highly solidified front of silica-undersaturated alkaline magmas at mantle reservoirs