Stretching of a capillary bridge featuring a particle-laden interface: particle sedimentation in the interface

This paper was presented at the 4th Micro and Nano Flows Conference (MNF2014), which was held at University College, London, UK. The conference was organised by Brunel University and supported by the Italian Union of Thermofluiddynamics, IPEM, the Process Intensification Network, the Institution of Mechanical Engineers, the Heat Transfer Society, HEXAG - the Heat Exchange Action Group, and the Energy Institute, ASME Press, LCN London Centre for Nanotechnology, UCL University College London, UCL Engineering, the International NanoScience Community, www.nanopaprika.eu.Colloidal particles adsorbed at fluid interfaces can be subject to external forces, for instance of magnetic, electrical, or gravitational origin. To develop a tool that will enable to study the effect of these forces on interfacial particle transport, we derive a transport equation for the surface particle concentration using the method of volume averaging. This equation is specialised to the problem of particle sedimentation induced by external forces on an axisymmetric capillary bridge stretched with assigned constant velocity between two circular plates. The equation for the interfacial concentration is one-way coupled to the unsteady Stokes equation in the capillary bridge, and solved in the thin-thread approximation, in the limit of small capillary and Bond numbers and for moderate area fractions. We find that owing to the competition between particle settling in one direction, and fluid velocity in the opposite direction, a concentration peak develops between the neck region and the moving plate. Hydrodynamic interactions, modelled through a concentration-dependent hindrance function, have the effect of steepening the shock-like concentration gradients that develop in the interface

Buckling vs. particle desorption in a particle-covered drop subject to compressive surface stresses: a simulation study

We study via a new simulation method the transition between buckling and particle desorption when a particle-covered drop is compressed.</p

Accuracy Trends and Sources of Forecast Errors in WASDE Balance Sheet Categories for Corn and Soybeans

Marketing,

Affine actions on non-archimedean trees

We initiate the study of affine actions of groups on $\Lambda$-trees for a general ordered abelian group $\Lambda$; these are actions by dilations rather than isometries. This gives a common generalisation of isometric action on a $\Lambda$-tree, and affine action on an $\R$-tree as studied by I. Liousse. The duality between based length functions and actions on $\Lambda$-trees is generalised to this setting. We are led to consider a new class of groups: those that admit a free affine action on a $\Lambda$-tree for some $\Lambda$. Examples of such groups are presented, including soluble Baumslag-Solitar groups and the discrete Heisenberg group.Comment: 27 pages. Section 1.4 expanded, typos corrected from previous versio

X-ray Imaging of Transplanar Liquid Transport Mechanisms in Single Layer Textiles

Understanding the penetration of liquids within textile fibers is critical for the development of next-generation smart textiles. Despite substantial research on liquid penetration in the plane of the textile, little is known about how the liquid penetrates in the thickness direction. Here we report a time-resolved high-resolution X-ray measurement of the motion of the liquid–air interface within a single layer textile, as the liquid is transported across the textile thickness following the deposition of a droplet. The measurement of the time-dependent position of the liquid meniscus is made possible by the use of ultrahigh viscosity liquids (dynamic viscosity from 10⁵ to 2.5 × 10⁶ times larger than water). This approach enables imaging due to the slow penetration kinetics. Imaging results suggest a three-stage penetration process with each stage being associated with one of the three types of capillary channels existing in the textile geometry, providing insights into the effect of the textile structure on the path of the three-dimensional liquid meniscus. One dimensional kinetics studies show that our data for the transplanar penetration depth Δ<i>x</i>_L vs time do not conform to a power law, and that the measured rate of penetration for long times is smaller than that predicted by Lucas–Washburn kinetics, challenging commonly held assumptions regarding the validity of power laws when applied to relatively thin textiles

Nonlinear dynamic analysis of gas turbine combustor leaf seal

The leaf seals are one of the typical sealing systems in gas turbine and jet engines. In Baker Hughes LT family gas turbines, they are used to create sealing between the combustion chamber and the first stage nozzle. The leaf seals are thin metallic plates and subjected to dynamic loads and high temperatures. They have curved contacts, and depending on the inclination, they can experience partial contact. Furthermore, when excited by dynamic loads, the leaf seal can be subject to intermittent contact, possibly triggering wear out or vibratory phenomena. Due to its flexibility and its partial seating, it exhibits a complex nonlinear dynamic behaviour, strongly variable with the operating conditions. This study presents a numerical investigation using coupled static/dynamic harmonic balance method (HBM) frequency-based solution technique. The reported solutions include nonlinear forced response and contact studies for various operating and kinematic conditions along with brief insights

Towards biological control strategies for the bronze bug, Thaumastocoris peregrinus, on eucalyptus plantations in South America.

Edição dos abstracts do 24º IUFRO World Congress, 2014, Salt Lake City. Sustaining forests, sustaining people: the role of research

A Neutral and Stable Macrocyclic Mn(II) Complex for MRI Tumor Visualization

A stable and inert amphiphilic Mn(II) complex based on a bisamide derivative of 1,4-DO2A (DO2A=tetraazacyclododecane-1,4-diacetic acid) was synthesized and its H-1 NMR relaxometric behavior was investigated as a function of the magnetic field strength, pH and temperature. The interaction with human serum albumin (HSA) was also studied via relaxometry showing a good relaxivity enhancement at low field (at 1T and 298 K the relaxivity increases from 4.5 mM(-1) s(-1) of the Mn(II)-complex to 14.0 mM(-1) s(-1) of the complex-HSA supramolecular adduct). In vivo biodistribution and MRI studies highlighted a rapid and mixed renal/liver elimination without spleen accumulation from healthy mice and good contrast enhancing properties in a breast tumor murine model. A comparison with a clinically approved Gd(III) agent (GdBOPTA, Multihance (R)) underlined that the proposed Mn(II) contrast agent gave comparable tumor contrast enhancement up to 3 hours post-injection

Vibrational Spectroscopy of Selected Natural Uranyl Vanadates

Raman spectroscopy has been used to study a selection of uranyl vanadate minerals including carnotite, curienite, francevillite, tyuyamunite and metatyuyamunite. The minerals are characterised by an intense band in the 800 to 824 cm-1 region, assigned to the ν1 symmetric stretching vibrations of the (UO2)2+ units. A second intense band is observed in the 965 to 985 cm-1 range and is attributed to the ν1 (VO3) symmetric stretching vibrations in the (V2O8) units. This band is split with a second component observed at around 963 cm-1. A band of very low intensity is observed around 948 cm-1 and is assigned to the ν3 antisymmetric stretching vibrations of the (VO3) units. Bands in the range 608-655 cm-1 may be attributed to molecular water librational modes or the stretching modes ￮(V2O2) units. Bands in the range 573-583 cm-1 may be connected with the ￮ (U-Oequatorial) vibrations or ￮ (V2O2) units. Bands located in the range 467-539 cm-1 may be also attributed to the ￮ (U-Oequatorial) units vibrations. The bending modes of the (VO3) units are observed in the 463 to 480 cm-1 range – there may be some coincidence with ￮ (U-Oequatorial). The bending modes of the (V2O2) in the (V2O8) units are located in a series of bands around 407, 365 and 347 cm-1 (ν2). Two intense bands are observed in the 304 to 312 cm-1 range and 241 to 264 cm-1 range and are assigned to the doubly degenerate ν2 modes of the (UO2)2+ units. The study of the vibrational spectroscopy of uranyl vanadates is complicated by the overlap of bands from the (VO3) and (UO2)2+ units. Raman spectroscopy has proven most useful in assigning bands to these two units since Raman bands are sharp and well separated as compared with infrared bands. The uranyl vanadate minerals are often found as crystals on a host matrix and Raman spectroscopy enables their in-situ characterisation without sample preparation