Sexual minority women and parenthood: Perceptions of friendship among childfree and new parents

Many individuals experience shifts in their friendship networks after becoming parents. The current study investigated the narratives of how a sample of sixty-six sexual minority women, most of whom do not yet have children but who expect to be parents in the future, perceive the changes in friendship networks following becoming parents. A thematic analysis uncovered three themes: (1) general expectations surrounding future parenthood and friendships; (2) changes in lifestyle and priorities; and (3) LGBTQ + community attachment. Further, the theme of general expectations surrounding future parenthood and friendships was largely represented among lesbian and queer women, while the theme of changes in lifestyle and priorities was predominately represented among lesbian women, and finally, the theme of LGBTQ + community attachment was shared among all sexual minority women in our sample across different sexual identities. We discuss the diversity of shared and non-shared narratives among sexual minority women, the intentionality in how friendship during parenthood is perceived, as well as why some themes were particularly prevalent among women with specific sexual identities

Envisioning future parenthood among bisexual, lesbian, and heterosexual women

For many individuals, becoming a parent is an important milestone. The current study examined attitudes and beliefs about parenting among a sample of 196 self-identified bisexual, lesbian, and heterosexual women. Results showed no differences by sexual orientation for women’s desires and intentions to have children, their idealization of parenthood, and perceptions of their parental self-efficacy (i.e., their ability to care for a child). In contrast, differences did emerge by sexual orientation in aspects such as partner expectations as well as professional intentions (i.e., wanting a permanent position before becoming a parent). Bisexual women tended to anticipate lower partner support compared to heterosexual women. Lesbian women, however, had a greater preference to work full-time during parenthood and wanted a permanent position before becoming a parent compared to both bisexual and heterosexual women. Implications are discussed of how bisexual women’s perceptions of parenthood are both similar to and distinct from lesbian and heterosexual women

Studies on the mechanism of the peroxyoxalate chemiluminescence reaction Part 1. Confirmation of 1,2-dioxetanedione as an intermediate using 13C nuclear magnetic resonance spectroscopy

A simple model peroxyoxalate chemiluminescence system was monitored directly across a range of temperatures (from −80 to +20 °C) using 13C nuclear magnetic resonance spectroscopy. These experiments were made possible by the utilisation of 13C doubly labelled oxalyl chloride, which was reacted with anhydrous hydrogen peroxide in dry tetrahydrofuran. Ab initio quantum calculations were also performed to estimate the 13C nuclear magnetic resonance (NMR) shift of the most commonly postulated key intermediate 1,2-dioxetanedione and this data, in concert with the spectroscopic evidence, confirmed its presence during the reaction

Arithmetic Considerations for Isogeny Based Cryptography

In this paper we investigate various arithmetic techniques which can be used to potentially enhance the performance in the supersingular isogeny Diffie-Hellman (SIDH) key-exchange protocol which is one of the more recent contenders in the post-quantum public-key arena. Firstly, we give a systematic overview of techniques to compute efficient arithmetic modulo $2^xp^y\pm 1$. Our overview shows that in the SIDH setting, where arithmetic over a quadratic extension field is required, the approaches based on Montgomery reduction for such primes of a special shape are to be preferred. Moreover, the outcome of our investigation reveals that there exist moduli which allow even faster implementations. Secondly, we investigate if it is beneficial to use other curve models to speed-up the elliptic curve scalar multiplication. The use of twisted Edwards curves allows one to search for efficient addition-subtraction chains for fixed scalars while this is not possible with the differential addition law when using Montgomery curves. Our preliminary results show that despite the fact that we found such efficient chains, using twisted Edwards curves does not result in faster scalar multiplication arithmetic in the setting of SIDH

Faster Modular Arithmetic For Isogeny Based Crypto on Embedded Devices

We show how to implement the Montgomery reduction algorithm for isogeny based cryptography such that it can utilize the unsigned multiply accumulate accumulate long instruction present on modern ARM architectures. This results in a practical speed-up of a factor 1.34 compared to the approach used by SIKE: the supersingular isogeny based submission to the ongoing post-quantum standardization effort. Moreover, motivated by the recent work of Costello and Hisil (ASIACRYPT 2017), which shows that there is only a moderate degradation in performance when evaluating large odd degree isogenies, we search for more general supersingular isogeny friendly moduli. Using graphics processing units to accelerate this search we find many such moduli which allow for faster implementations on embedded devices. By combining these two approaches we manage to make the modular reduction 1.5 times as fast on a 32-bit ARM platform

Holistic lipidomics of the human gut phenotype using validated ultra-high-performance liquid chromatography coupled to hybrid orbitrap mass spectrometry

As lipids are assigned a plethora of biological functions, it is evident that dysregulated lipid metabolism signifies a key element in many pathological conditions. With this rationale, this study presents a validated lipidomics platform to map the fecal lipidome, which integrates unique information' about host-gut microbiome interactions, gastrointestinal functionality, and dietary patterns. This particular method accomplished coverage across all eight lipid categories: fatty acyls, glycerolipids, phosphoglycerolipids, polyketides, prenols, saccharolipids, sphingolipids, and sterols. Generic extraction of freeze-dried feces was achieved by solid-liquid extraction using methanol and methyl tert-butyl ether. Extracted components were separated by liquid chromatography, whereby the selected ethylene-bridged hybrid phenyl ultra-high-performance liquid chromatography stationary phase allowed fast separation of both individual lipid species and categories. Detection was achieved by high-resolution full-scan Q-Exactive Orbitrap mass spectrometry and covered a broad m/z scan range (67-2300 Da). Method validation was performed in a targeted fashion to evaluate the analytical performance across all lipid categories, revealing excellent linearity (R-2 >= 0.9921), acceptable repeatability (coefficients of variance = 0.90) for 75.3% and acceptable repeatability (coefficients of variance <= 30%) for 84.5% of about 9000 endogenous fecal compounds. Eventually, the potential of fecal lipidomics was exemplified within a clinical context of type 2 diabetes, thereby revealing significant perturbations [orthogonal partial least-squares discriminant analysis Q(2)(Y) of 0.728] in the fecal lipidome between participants with normal blood glucose levels (n = 26) and those with type 2 diabetes (n = 17)

Spatial Variations of Stochastic Noise Properties in GPS Time Series

The noise in position time series of 568 GPS (Global Position System) stations across North America with an observation span of ten years has been investigated using solutions from two processing centers, namely, the Pacific Northwest Geodetic Array (PANGA) and New Mexico Tech (NMT). It is well known that in the frequency domain, the noise exhibits a power-law behavior with a spectral index of around −1. By fitting various noise models to the observations and selecting the most likely one, we demonstrate that the spectral index in some regions flattens to zero at long periods while in other regions it is closer to −2. This has a significant impact on the estimated linear rate since flattening of the power spectral density roughly halves the uncertainty of the estimated tectonic rate while random walk doubles it. Our noise model selection is based on the highest log-likelihood value, and the Akaike and Bayesian Information Criteria to reduce the probability of over selecting noise models with many parameters. Finally, the noise in position time series also depends on the stability of the monument on which the GPS antenna is installed. We corroborate previous results that deep-drilled brace monuments produce smaller uncertainties than concrete piers. However, if at each site the optimal noise model is used, the differences become smaller due to the fact that many concrete piers are located in tectonic/seismic quiet areas. Thus, for the predicted performance of a new GPS network, not only the type of monument but also the noise properties of the region need to be taken into account

The OSIRIS-REx Visible and InfraRed Spectrometer (OVIRS): Spectral Maps of the Asteroid Bennu

The OSIRIS-REx Visible and Infrared Spectrometer (OVIRS) is a point spectrometer covering the spectral range of 0.4 to 4.3 microns (25,000-2300 cm-1). Its primary purpose is to map the surface composition of the asteroid Bennu, the target asteroid of the OSIRIS-REx asteroid sample return mission. The information it returns will help guide the selection of the sample site. It will also provide global context for the sample and high spatial resolution spectra that can be related to spatially unresolved terrestrial observations of asteroids. It is a compact, low-mass (17.8 kg), power efficient (8.8 W average), and robust instrument with the sensitivity needed to detect a 5% spectral absorption feature on a very dark surface (3% reflectance) in the inner solar system (0.89-1.35 AU). It, in combination with the other instruments on the OSIRIS-REx Mission, will provide an unprecedented view of an asteroid's surface.Comment: 14 figures, 3 tables, Space Science Reviews, submitte