210 research outputs found
Synthesis of 3-(2-hydroxy–3,4-benzophenyl-5-methoxy)-5-(4-methoxy-phenyl)–1-substituted Pyrazolines
1-(2-hydroxy-3,4-benzophenyl-5-methoxy)-3aryl-prop-2-ene-1-one & semicarbazide / thiosemicarbazide / phenylhydrazine /isonicotinic acid hydrazide were added to DMF and the mixture was refluxed for about 2 hours . The reaction mixture was cooled and diluted with water. The semisolid so obtained was triturated with ethanol to get a solid which was recrystallised from ethanol–acetic acid mixture to obtain titled pyrazolines 
The Ecological and Ethical Consumption Development Prospects in Poland Compared with the Western European Countries
An overview of the Western European literature shows that one of the most distinct trends in consumption that has been noted in the recent years is globally increasing environmental and social awareness. The issue of consumers' behaviours and attitudes towards "socially responsible products" has been gaining importance in Polish economy as well. This article evaluates the development prospects of ethical and ecological consumption in Poland vis-à-vis Western European countries. The comparative analysis being part of the article utilizes primary sources of information, i.e. interviews with a representative sample of Polish adults, as well as secondary sources of information. A factor analysis or, more precisely, a principal component analysis, allowed dividing Polish consumers into groups that were typologically homogeneous in respect of their sensitivity to various aspects of business ethics and ecology.Przegląd literatury zachodnio-europejskiej pozwala stwierdzić, że jednym z najbardziej zauważalnych trendów w sferze konsumpcji w ostatnich latach jest coraz większa świadomość ekologiczna i społeczna w wymiarze globalnym. Problematyka zachowań i postaw konsumentów wobec produktów "społecznie odpowiedzialnych" nabiera coraz większego znaczenia także w polskiej gospodarce. Celem artykułu jest ocena perspektyw rozwoju etyczneji ekologicznej konsumpcji w Polsce na tle krajów zachodnio-europejskich. Analizę porównawczą prowadzono bazując na źródłach wtórych jak i badaniach pierwotnych realizowanych na reprezentatywnej próbie losowej dorosłych mieszkańców Polski. W oparciu o analizę czynnikową, a dokładniej metodę analizy głównych składowych, dokonano także podziału polskich konsumentów na jednorodne grupy typologiczne pod względem ich wrażliwości na różne aspekty związane z ekologią i etyką
Coffee pulp, a by-product of coffee production, modulates gut microbiota and improves metabolic syndrome in high-carbohydrate, high-fat diet-fed rats
Waste from food production can be re‐purposed as raw material for usable products to decrease industrial waste. Coffee pulp is 29% of the dry weight of coffee cherries and contains caf‐feine, chlorogenic acid, trigonelline, diterpenes and fibre. We investigated the attenuation of signs of metabolic syndrome induced by high‐carbohydrate, high‐fat diet in rats by dietary supplementation with 5% freeze‐dried coffee pulp for the final 8 weeks of a 16‐week protocol. Coffee pulp decreased body weight, feed efficiency and abdominal fat; normalised systolic blood pressure, left ventricular diastolic stiffness, and plasma concentrations of triglycerides and non‐esterified fatty acids; and improved glucose tolerance in rats fed high‐carbohydrate, high‐fat diet. Further, the gut microbiota was modulated with high‐carbohydrate, high‐fat diet and coffee pulp supplementation and 14 physiological parameters were correlated with the changes in bacterial community structures. This study suggested that coffee pulp, as a waste from the coffee industry, is useful as a functional food for improving obesity‐associated metabolic, cardiovascular and liver structure and function, and gut microbiota
Phase Field Model for Three-Dimensional Dendritic Growth with Fluid Flow
We study the effect of fluid flow on three-dimensional (3D) dendrite growth
using a phase-field model on an adaptive finite element grid. In order to
simulate 3D fluid flow, we use an averaging method for the flow problem coupled
to the phase-field method and the Semi-Implicit Approximated Projection Method
(SIAPM). We describe a parallel implementation for the algorithm, using Charm++
FEM framework, and demonstrate its efficiency. We introduce an improved method
for extracting dendrite tip position and tip radius, facilitating accurate
comparison to theory. We benchmark our results for two-dimensional (2D)
dendrite growth with solvability theory and previous results, finding them to
be in good agreement. The physics of dendritic growth with fluid flow in three
dimensions is very different from that in two dimensions, and we discuss the
origin of this behavior
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Optimization of azimuthal uniformity of thermal conductance between AI TMP and Si cooling arms
Tunable intervalence charge transfer in ruthenium Prussian blue analogue enables stable and efficient biocompatible artificial synapses
Emerging concepts for neuromorphic computing, bioelectronics, and
brain-computer interfacing inspire new research avenues aimed at understanding
the relationship between oxidation state and conductivity in unexplored
materials. Here, we present ruthenium Prussian blue analogue (RuPBA), a mixed
valence coordination compound with an open framework structure and ability to
conduct both ionic and electronic charge, for flexible artificial synapses that
reversibly switch conductance by more than four orders of magnitude based on
electrochemically tunable oxidation state. Retention of programmed states is
improved by nearly two orders of magnitude compared to the extensively studied
organic polymers, thus reducing the frequency, complexity and energy costs
associated with error correction schemes. We demonstrate dopamine detection
using RuPBA synapses and biocompatibility with neuronal cells, evoking
prospective application for brain-computer interfacing. By application of
electron transfer theory to in-situ spectroscopic probing of intervalence
charge transfer, we elucidate a switching mechanism whereby the degree of mixed
valency between N-coordinated Ru sites controls the carrier concentration and
mobility, as supported by DFT
Linking the dust and chemical evolution: Taurus and Perseus -- New collisional rates for HCN, HNC, and their C, N, and H isotopologues
HCN, HNC, and their isotopologues are ubiquitous molecules that can serve as
chemical thermometers and evolutionary tracers to characterize star-forming
regions. Despite their importance in carrying information that is vital to
studies of the chemistry and evolution of star-forming regions, the collision
rates of some of these molecules have not been available for rigorous studies
in the past. We perform an up-to-date gas and dust chemical characterization of
two different star-forming regions, TMC 1-C and NGC 1333-C7, using new
collisional rates of HCN, HNC, and their isotopologues. We investigated the
possible effects of the environment and stellar feedback in their chemistry and
their evolution. With millimeter observations, we derived their column
densities, the C and N isotopic fractions, the isomeric ratios, and the
deuterium fractionation. The continuum data at 3 mm and 850 m allowed us
to compute the emissivity spectral index and look for grain growth as an
evolutionary tracer. The HCN/HNC ratio is anticorrelated with the
deuterium fraction of HCN, thus it can readily serve as a proxy for the
temperature. The spectral index shows a tentative
anticorrelation with the HCN/HNC ratio, suggesting grain growth
in the evolved, hotter, and less deuterated sources. Unlike TMC 1-C, the
south-to-north gradient in dust temperature and spectral index observed in NGC
1333-C7 suggests feedback from the main NGC 1333 cloud. With this up-to-date
characterization of two star-forming regions, we found that the chemistry and
the physical properties are tightly related. The dust temperature, deuterium
fraction, and the spectral index are complementary evolutionary tracers. The
large-scale environmental factors may dominate the chemistry and evolution in
clustered star-forming regions.Comment: 25 pages, 20 figure
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Lessons from Two Years of Building Fusion Ignition Targets with the Precision Robotic Assembly Machine
The Precision Robotic Assembly Machine was developed to manufacture the small and intricate laser-driven fusion ignition targets that are being used in the world's largest and most energetic laser, the National Ignition Facility (NIF). The National Ignition Campaign (NIC) goal of using the NIF to produce a self-sustaining nuclear fusion burn with energy gain - for the first time ever in a laboratory setting - requires targets that are demanding in materials fabrication, machining, and assembly. We provide an overview of the design and function of the machine, with emphasis on the aspects that revolutionized how NIC targets are manufactured
Computer modelling of the plasma chemistry and plasma-based growth mechanisms for nanostructured materials
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