A chemical survey of standing waters in south-east England, with reference to acidification and eutrophication

This study looks at the distribution and magnitude of acidification and eutrophication in south-east England where there are no natural lakes but a large number of shallow artificial ponds. The study area is defined as the region lying within a 100 km radius of central London but excluding the area within the M25 motorway. Water samples were taken from 120 sites between mid-January and the end of February 1990, with a subsequent monthly survey of a subset of 31 of these waters. Twelve chemical variables were measured in the laboratory using standard techniques. PH values for the full dataset ranged from 3.2 to 8.4, although the majority of sites had pH values in the range 7.0 to 8.5; only five sites had a pH of less than 6.0. The five low pH sites expectedly had low alkalinities and are the only sites with values below 0.1 meq per litre. Concentrations of calcium, sodium, potassium, magnesium, chloride, sulphate and nitrate had normal distributions. The majority of sites had total phosphorus concentrations in the range 25 to 200 mu g per litre, although 10 sites had concentrations above 400 mu g per litre. The low number of acid sites suggests that surface water acidity is not a widespread regional problem in south-east England. However the survey shows that a large number of standing waters in the region have high total phosphorus and nitrate concentrations, and 89% may be considered moderately to considerably eutrophic

Practitioner perspectives on the application of palaeoecology in nature conservation

It is widely recognised that palaeoecology holds great potential to inform and support nature conservation, but that there are difficulties in knowledge exchange between academia and practitioners that inhibit the operationalisation of research. To facilitate the integration of palaeoecology into the conservation toolkit, it is essential to understand perspectives of the practitioners themselves and the contexts in which they work. This paper reports the results of a survey of 153 UK-based conservation practitioners, concerning their perceptions of palaeoecology, the barriers to its use and potential solutions for making palaeoecological insights more accessible in conservation practice. The survey was conducted online over a period of 3 months; closed question responses were analysed for statistical trends and thematic analysis was done on open question responses. The majority of respondents were strongly positive about the role palaeoecological research could play, though they also exhibited a limited understanding of how and why one might implement it. They identified time constraints as the biggest barrier to using palaeoecology within their work, and also flagged concerns around financial resources and the accessibility of the research. Access to applied case studies and a centralised database were the most favoured solutions among respondents. Respondents with prior experience of working with palaeoecology were generally more optimistic about its incorporation. This paper makes several key recommendations to progress the integration of palaeoecology into conservation, including improving data accessibility, aligning research design with conservation and policy drivers, and increasing both respective groups’ understanding of the other

Lake eutrophication and its implications for organic carbon sequestration in Europe

The eutrophication of lowland lakes in Europe by excess nitrogen (N) and phosphorus (P) is severe because of the long history of land-cover change and agricultural intensification. The ecological and socio-economic effects of eutrophication are well understood but its effect on organic carbon (OC) sequestration by lakes and its change overtime has not been determined. Here, we compile data from ~90 culturally impacted European lakes [~60% are eutrophic, Total P (TP) >30 μg P l-1] and determine the extent to which OC burial rates have increased over the past 100-150 years. The average focussing corrected, OC accumulation rate (C ARFC) for the period 1950-1990 was ~60 g C m-2 yr-1, and for lakes with >100 μg TP l-1 the average was ~100 g C m-2 yr-1. The ratio of post-1950 to 1900-1950 C AR is low (~1.5) indicating that C accumulation rates have been high throughout the 20th century. Compared to background estimates of OC burial (~5-10 g C m-2 yr-1), contemporary rates have increased by at least four to fivefold. The statistical relationship between C ARFC and TP derived from this study (r2 = 0.5) can be used to estimate OC burial at sites lacking estimates of sediment C-burial. The implications of eutrophication, diagenesis, lake morphometry and sediment focussing as controls of OC burial rates are considered. A conservative interpretation of the results of the this study suggests that lowland European meso- to eutrophic lakes with >30 μg TP l-1 had OC burial rates in excess of 50 g C m-2 yr-1 over the past century, indicating that previous estimates of regional lake OC burial have seriously underestimated their contribution to European carbon sequestration. Enhanced OC burial by lakes is one positive side-effect of the otherwise negative impact of the anthropogenic disruption of nutrient cycles

A chemical survey of standing waters in South East England, with reference to acidification and eutrophication

The worldwide occurrence of nutrient enrichment and surface wateracidification and their consequences for aquatic systems have been welldocumented, including many examples from the UK (e.g. Battarbee et al.1988; Tailing & Heaney 1988; Sutcliffe & Jones 1992; Carvalho & Moss1995). However, most limnological and palaeolimnological studies have beenundertaken on natural lakes in the UK. Very little is known about thedistribution and magnitude of lake acidification and eutrophication in southeastEngland where there are no natural lakes but a large number (ca. 2000) ofshallow, artificial ponds

Identifying sediment discontinuities and solving dating puzzles using monitoring and palaeolimnological records

Palaeolimnological studies should ideally be based upon continuous, undisturbed sediment sequences with reliable chronologies. However for some lake cores, these conditions are not met and palaeolimnologists are often faced with dating puzzles caused by sediment disturbances in the past. This study chooses Esthwaite Water from England to illustrate how to identify sedimentation discontinuities in lake cores and how chronologies can be established for imperfect cores by correlation of key sediment signatures in parallel core records and with long-term monitoring data (1945‒2003). Replicated short cores (ESTH1, ESTH7, and ESTH8) were collected and subjected to loss-on-ignition, radiometric dating (210Pb, 137Cs, and 14C), particle size, trace metal, and fossil diatom analysis. Both a slumping and a hiatus event were detected in ESTH7 based on comparisons made between the cores and the long-term diatom data. Ordination analysis suggested that the slumped material in ESTH7 originated from sediment deposited around 1805‒1880 AD. Further, it was inferred that the hiatus resulted in a loss of sediment deposited from 1870 to 1970 AD. Given the existence of three superior 14C dates in ESTH7, ESTH1 and ESTH7 were temporally correlated by multiple palaeolimnological proxies for age-depth model development. High variability in sedimentation rates was evident, but good agreement across the various palaeolimnological proxies indicated coherence in sediment processes within the coring area. Differences in sedimentation rates most likely resulted from the natural morphology of the lake basin. Our study suggests that caution is required in selecting suitable coring sites for palaeolimnological studies of small, relatively deep lakes and that proximity to steep slopes should be avoided wherever possible. Nevertheless, in some cases, comparisons between a range of contemporary and palaeolimnological records can be employed to diagnose sediment disturbances and establish a chronology

The spectral sensitivity of long period gratings fabricated in elliptical core D-shaped optical fiber

Long period gratings (LPGs) were written into a D-shaped optical fibre, which has an elliptical core with a W-shaped refractive index profile. The LPG's attenuation bands were found to be sensitive to the polarisation of the interrogating light with a spectral separation of about 15nm between the two orthogonal polarisation states. In addition, two spectrally overlapping attenuation bands corresponding to orthogonal polarisation states were observed; modelling successfully reproduced this spectral feature. The spectral sensitivity of both orthogonal states was experimentally measured with respect to temperature, surrounding refractive index, and directional bending. These LPG devices produced blue and red wavelength shifts of the stop-bands due to bending in different directions. The measured spectral sensitivities to curvatures, d?/dR , ranged from -3.56nm m to +6.51nm m. The results obtained with these LPGs suggest that this type of fibre may be useful as a shape/bend sensor. It was also demonstrated that the neighbouring bands could be used to discriminate between temperature and bending and that overlapping orthogonal polarisation attenuation bands can be used to minimise error associated with polarisation

Multi-proxy palaeoecological responses to water-level fluctuations in three shallow Turkish lakes

Natural or human-induced water-level fluctuations influence the structure and function of shallow lakes, especially in semi-arid to arid climate regions. In order to reliably interpret the effect of water-level changes from sedimentary remains in the absence of historical data, it is crucial to understand the variation in sedimentary proxies in relation to water level measurements. Here, we took advantage of existing water surface elevation data on three large shallow lakes in Turkey to elucidate the impact of lake-level changes on benthic-pelagic primary production over the last 50-100 years. Sub-fossil cladocerans, diatoms, plant remains and pigments were investigated as biological variables; X-ray fluorescence (XRF) and loss on ignition (LOI) analyses were conducted as geochemical-physical variables on a set of Pb-210 and Cs-137 dated cores. Dating of the cores were robust, with the exception of uncertainties in Lake Marmara littoral core due to low unsupported 210Pb activities and high counting errors. Results indicated that Lake Marmara was dominated by benthic species throughout the sediment record, while Lakes Beysehir and Uluabat shifted from a littoral-dominated system to one with increased pelagic species abundance. In all cores there was a stronger response to longer-term (decadal) and pronounced water-level changes than to short-term (annual-biennial) and subtle changes. It was also noted that degree of alteration in proxies differed between lakes, through time and among pelagic-littoral areas, likely emphasising differences in depositional environments and/or resolution of sampling and effects of other stressors such as eutrophication. Our results highlight lake-specific changes associated with water-level fluctuations, difficulties of conducting studies at required resolution in lakes with rather mixed sediment records and complexity of palaeolimnological studies covering recent periods where multiple drivers are in force. They further emphasise the need to include instrumental records when interpreting effects of recent water-level changes from sediment core data in large shallow lakes