1,982 research outputs found
Ion and polymer dynamics in polymer electrolytes PPO-LiClO4: II. 2H and 7Li NMR stimulated-echo experiment
We use 2H NMR stimulated-echo spectroscopy to measure two-time correlation
functions characterizing the polymer segmental motion in polymer electrolytes
PPO-LiClO4 near the glass transition temperature Tg. To investigate effects of
the salt on the polymer dynamics, we compare results for different ether oxygen
to lithium ratios, namely, 6:1, 15:1, 30:1 and infinity. For all compositions,
we find nonexponential correlation functions, which can be described by a
Kohlrausch function. The mean correlation times show quantitatively that an
increase of the salt concentration results in a strong slowing down of the
segmental motion. Consistently, for the high 6:1 salt concentration, a high
apparent activation energy E_a=4.1eV characterizes the temperature dependence
of the mean correlation times at Tg < T< 1.1T_g, while smaller values E_a=2.5eV
are observed for moderate salt contents. The correlation functions are most
nonexponential for 15:1 PPO-LiClO4, whereas the stretching is reduced for
higher and lower salt concentrations. A similar dependence of the correlation
functions on the evolution time in the presence and in the absence of ions
indicates that addition of salt hardly affects the reorientational mechanism.
For all compositions, mean jump angles of about 15 degree characterize the
segmental reorientation. In addition, comparison of results from 2H and 7Li NMR
stimulated-echo experiments suggests a coupling of ion and polymer dynamics in
15:1 PPO-LiClO4.Comment: 14 pages, 12 figure
Space Shuttle Crawler Transporter Truck Shoe Qualification Tests and Analyses for Return-to-Flight
A vital element to Launch Complex 39 (LC39) and NASA's Kennedy Space Center (KSC) mobile launch transfer operation is a 3 million kilogram behemoth known as the Crawler Transporter (CT). Built in the 1960's, two CT's have accumulated over 1700+ miles each and have been used for the Apollo and the Space Shuttle programs. Recent observation of fatigue cracks on the CT shoes led to a comprehensive engineering, structural and metallurgical evaluation to assess the root cause that necessitated procurement of over 1000 new shoes. This paper documents the completed dynamic and compression tests on the old and new shoes respectively, so as to certify them for Space Shuttle's return-to-flight (RTF). Measured strain data from the rollout tests was used to develop stress/loading spectra and static equivalent load for qualification testing of the new shoes. Additionally, finite element analysis (FEA) was used to conduct sensitivity analyses of various contact parameters and structural characteristics for acceptance of new shoes
Massive Increase, Spread, and Exchange of Extended Spectrum {beta}-Lactamase-Encoding Genes Among Intestinal Enterobacteriaceae in Hospitalized Children With Severe Acute Malnutrition in Niger.
Background. From the time of CTX-M emergence, extended-spectrum β-lactamase-producing enterobacteria (ESBL-E) have spread worldwide in community settings as well as in hospitals, particularly in developing countries. Although their dissemination appears linked to Escherichia coli intestinal carriage, precise paths of this dynamic are largely unknown. Methods. Children from a pediatric renutrition center were prospectively enrolled in a fecal carriage study. Antibiotic exposure was recorded. ESBL-E strains were isolated using selective media from fecal samples obtained at admission and, when negative, also at discharge. ESBL-encoding genes were identified, their environments and plasmids were characterized, and clonality was assessed with polymerase chain reaction-based methods and pulsed-field gel electrophoresis for E. coli and Klebsiella pneumoniae. E. coli strains were subjected to multilocus sequence typing. Results. The ESBL-E carriage rate was 31% at admission in the 55 children enrolled. All children enrolled received antibiotics during hospitalization. Among the ESBL-E-negative children, 16 were resampled at discharge, and the acquisition rate was 94%. The bla(CTX-M-15) gene was found in >90% of the carriers. Genetic environments and plasmid characterization evidenced the roles of a worldwide, previously described, multidrug-resistant region and of IncF plasmids in CTX-M-15 E. coli dissemination. Diversity of CTX-M-15-carrying genetic structures and clonality of acquired ESBL E. coli suggested horizontal genetic transfer and underlined the potential of some ST types for nosocomial cross-transmission. Conclusions. Cross-transmission and high selective pressure lead to very high acquisition of ESBL-E carriage, contributing to dissemination in the community. Strict hygiene measures as well as careful balancing of benefit-risk ratio of current antibiotic policies need to be reevaluated
Space Shuttle Crawler Transporter Vibration Analysis in Support of Rollout Fatigue Load Spectra Verification Program
The Crawler Transporter (CT), designed and built for the Apollo Program in the 1960's and surpassing its initial operational life, has become an integral part of the Space Shuttle Program (SSP). The CT transports the Space Shuttle Vehicle (SSV) stack, atop the Mobile Launch Platform (MLP), from the Vehicle Assembly Building (VAB) to the launch pad. This support structure provides hydraulic jacking, leveling and load equalization for the 12 million pound stack on its 3.5-5.0 mile rollout to the launch pad. Major elements of the SSV, consisting of the orbiter, solid rocket boosters (SRB) and external tank (ET) have required fatigue analyses as part of the mission life certification. Compared to rollout vibration, the SSV sees relatively high vibration loads during launch, ascent, descent and landing phases of the mission. Although preliminary measured SRB vibration levels during rollout were of low amplitude and frequency, the duration of the rollout phase is typically high, from 5-6 hours. As part of an expanded mission life assessment, additional certification effort was initiated to define fatigue load spectra for rollout. This study addresses the CT vibration analyses in support of the rollout fatigue study. Structural models developed for modal and vibration analyses were used to identify unique CT, CT/MLP and CT/MLP/SRB vibration characteristics for comparison to instrumented rollout tests. Whereas the main structural and vibration characteristics of the SSV are well defined, minimum analytical and vibration test data on the Crawler Transporter were available. Unique vibration characteristics of the CT are attributable to the drive mechanism, hydraulic jacking system, structural framing and the CT-to-MLP support pad restraints. Initial tests performed on the CT/MLP/SRB configuration showed reasonable correlation with predicted mode shapes and frequencies
Efficient Certified Resolution Proof Checking
We present a novel propositional proof tracing format that eliminates complex
processing, thus enabling efficient (formal) proof checking. The benefits of
this format are demonstrated by implementing a proof checker in C, which
outperforms a state-of-the-art checker by two orders of magnitude. We then
formalize the theory underlying propositional proof checking in Coq, and
extract a correct-by-construction proof checker for our format from the
formalization. An empirical evaluation using 280 unsatisfiable instances from
the 2015 and 2016 SAT competitions shows that this certified checker usually
performs comparably to a state-of-the-art non-certified proof checker. Using
this format, we formally verify the recent 200 TB proof of the Boolean
Pythagorean Triples conjecture
The First Detections of the Extragalactic Background Light at 3000, 5500, and 8000A (III): Cosmological Implications
(Abridged) We have used HST WFPC2 and ground-based spectroscopy to measure
the integrated extragalactic background light (EBL) at optical wavelengths. We
have also computed the integrated light from individual galaxy counts in the
images used to measure the EBL and in the Hubble Deep Field. We find that the
flux in galaxies as measured by standard galaxy photometry methods has
generally been underestimated by about 50%. Further, we find that the total
flux in individually detected galaxies is a factor of 2 to 3 less than the EBL
at 3000--8000A. We show that a significant fraction of the EBL may come from
normal galaxies at z<4, which are simply undetectable as a result of
K-corrections and cosmological surface brightness dimming. This is consistent
with recent redshift surveys at z<4. In the context of some simple models, we
discuss the constraints placed by the EBL on the evolution of the luminosity
density at z>1. Based on our optical EBL and published UV and IR EBL
measurements, we estimate that the total EBL from 0.1--1000 microns is 100+/-20
nW/m^2/sr. If the total EBL were produced entirely by stellar nucleosynthesis,
then we estimate that the total baryonic mass processed through stars is
Omega_* = 0.0062 (+/- 0.0022) h^{-2}, which corresponds to 0.33+/-0.12 Omega_B
for currently favored values of the baryon density. This estimate is smaller by
roughly 7% if 7 h_{0.7} nW/m^2/sr of the total EBL comes from accretion onto
central black holes. This estimate of Omega_* suggests that the universe has
been enriched to a total metal mass of 0.21(+/-0.13) Z_sun Omega_B. Our
estimate is consistent with other measurements of the cumulative metal mass
fraction of stars, stellar remnants, and the intracluster medium of galaxy
clusters in the local universe.Comment: Accepted for publication in ApJ, 20 pages using emulateapj.sty,
version with higher resolution figures available at
http://www.astro.lsa.umich.edu/~rab/publications.html or at
http://nedwww.ipac.caltech.edu/level5/Sept01/Bernstein3/frames.htm
Scientific, institutional and personal rivalries among Soviet geographers in the late Stalin era
Scientific, institutional and personal rivalries between three key centres of geographical research and scholarship (the Academy of Sciences Institute of Geography and the Faculties of Geography at Moscow and Leningrad State Universities) are surveyed for the period from 1945 to the early 1950s. It is argued that the debates and rivalries between members of the three institutions appear to have been motivated by a variety of scientific, ideological, institutional and personal factors, but that genuine scientific disagreements were at least as important as political and ideological factors in influencing the course of the debates and in determining their final outcome
Reversed anisotropies and thermal contraction of FCC (110) surfaces
The observed anisotropies of surface vibrations for unreconstructed FCC metal
(110) surfaces are often reversed from the "common sense" expectation. The
source of these reversals is investigated by performing ab initio density
functional theory calculations to obtain the surface force constant tensors for
Ag(110), Cu(110) and Al(110). The most striking result is a large enhancement
in the coupling between the first and third layers of the relaxed surface,
which strongly reduces the amplitude of out-of-plane vibrations of atoms in the
first layer. This also provides a simple explanation for the thermal
contraction of interlayer distances. Both the anisotropies and the thermal
contraction arise primarily as a result of the bond topology, with all three
(110) surfaces showing similar behavior.Comment: 13 pages, in revtex format, plus 1 postscript figur
Monitoring and Evaluation of Development Programs in Five Ministries: a Study on the System and Implementation
The system of planning and budgeting in Indonesia is undergoing a change, from an input-based system to one based on output and outcome. information accountability in monitoring and evaluation is a must to support the implementation of a performance-based system as mandated by law no. 17/2003 on state finance, and government regulation no. 21/2004 on formulating ministerial/institutional work plans and budgets. an evaluation needs to be conducted on government regulation no. 39/2006 on procedure of monitoring and evaluation of development plan implementation to accommodate the output – and outcome –based planning and budgeting system.
this study presents snapshots of the monitoring and evaluation system of government programs which have been implemented in five selected ministries. the methods used include conducting in-depth interviews with staff members and collecting secondary ministerial-level data at both the planning bureau (bpkln) and directorate general/program executing directorate; distributing questionnaires on budget absorption and achievement of targeted output/outcome indicators of selected programs; and conducting a field study on monitoring and evaluation systems and processes of data validation at the local level.
this study recommends that the monitoring and evaluation process should be placed parallel with the planning, budgeting, and implementation processes of the programs/activities. therefore a regulation regarding monitoring and evaluation management in national and local level government agencies is needed. it should provide clear definitions of monitoring and evaluation and address the need for an independent monitoring and evaluation unit; reward and punishment mechanisms; a feedback mechanism; and simplification of forms, number of reports, and indicators of programs/activities.
keywords: monitoring, evaluation, programs, ministr
Suppression of Phase Separation in LiFePO4 Nanoparticles During Battery Discharge
Using a novel electrochemical phase-field model, we question the common
belief that LixFePO4 nanoparticles separate into Li-rich and Li-poor phases
during battery discharge. For small currents, spinodal decomposition or
nucleation leads to moving phase boundaries. Above a critical current density
(in the Tafel regime), the spinodal disappears, and particles fill
homogeneously, which may explain the superior rate capability and long cycle
life of nano-LiFePO4 cathodes.Comment: 27 pages, 8 figure
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