Redetermination of para-aminopyridine (fampridine, EL-970) at 150 K

The structure of fampridine (EL-970) or 4-aminopyridine, C₅H₆N₂, has been redetermined at 150 K. The room-temperature structure has been reported previously [Chao & Schempp (1977). Acta Cryst. B33, 1557-1564]. Pyramidalization at the amine N atom occurs in fampridine, with the N atom 0.133 (11) Å from the plane of the three C/H/H atoms to which it is bonded; the interplanar angle between the pyridyl ring and NH2 group is 21 (2)°. Aggregation in the solid state occurs by N-H...N and N-H...[pi](pyridine) interactions with N...N and N...[pi](centroid) distances of 2.9829 (18) and 3.3954 (15) Å, respectively; a C-H...[pi](pyridine) contact completes the intermolecular interactions [C...[pi](centroid) = 3.6360 (16) Å]

Electric field effect on superconductivity at complex oxide interfaces

We examine the enhancement of the interfacial superconductivity between LaAlO$_{3}$ and SrTiO$_{3}$ by an effective electric field. Through the breaking of inversion symmetry at the interface, we show that a term coupling the superfluid density and an electric field can augment the superconductivity transition temperature. Microscopically, we show that an electric field can also produce changes in the carrier density by relating the measured capacitance to the density of states. Through the electron-phonon induced interaction in bulk SrTiO$_{3}$, we estimate the transition temperature.Comment: 7 Pages, Submitted to Physical Revie

Nearly free electrons in the layered oxide superconductor Ag5Pb2O6

We present first measurements of quantum oscillations in the layered oxide superconductor Ag5Pb2O6. From a detailed angular and temperature dependent study of the dHvA effect we determine the electronic structure and demonstrate that the electron masses are very light, m^* is approximately equalt to 1.2 m_e. The Fermi surface we observe is essentially that expected of nearly-free electrons - establishing Ag5Pb2O6 as the first known example of a monovalent, nearly-free electron superconductor at ambient pressure.Comment: 4 pages, 3 figure

Energy-resolved inelastic electron scattering off a magnetic impurity

We study inelastic scattering of energetic electrons off a Kondo impurity. If the energy E of the incoming electron (measured from the Fermi level) exceeds significantly the Kondo temperature T_K, then the differential inelastic cross-section \sigma (E,w), i.e., the cross-section characterizing scattering of an electron with a given energy transfer w, is well-defined. We show that \sigma (E,w) factorizes into two parts. The E-dependence of \sigma (E,w) is logarithmically weak and is due to the Kondo renormalization of the effective coupling. We are able to relate the w-dependence to the spin-spin correlation function of the magnetic impurity. Using this relation, we demonstrate that in the absence of magnetic field the dynamics of the impurity spin causes the electron scattering to be inelastic at any temperature. Quenching of the spin dynamics by an applied magnetic field results in a finite elastic component of the electron scattering cross-section. The differential scattering cross-section may be extracted from the measurements of relaxation of hot electrons injected in conductors containing localized spins.Comment: 15 pages, 9 figures; final version as published, minor changes, reference adde

Omnigenity as generalized quasisymmetry

Any viable stellarator reactor will need to be nearly omnigenous, meaning the radial guiding-center drift velocity averages to zero over time for all particles. While omnigenity is easier to achieve than quasisymmetry, we show here that several properties of quasisymmetric plasmas also apply directly or with only minor modification to the larger class of omnigenous plasmas. For example, concise expressions exist for the flow and current, closely resembling those for a tokamak, and these expressions are explicit in that no magnetic differential equations remain. A helicity (M,N) can be defined for any omnigenous field, based on the topology by which |B| contours close on a flux surface, generalizing the helicity associated with quasisymmetric fields. For generalized quasi-poloidal symmetry (M=0), the bootstrap current vanishes, which may yield desirable equilibrium and stability properties. A concise expression is derived for the radial electric field in any omnigenous plasma that is not quasisymmetric. The fact that tokamak-like analytical calculations are possible in omnigenous plasmas despite their fully-3D magnetic spectrum makes these configurations useful for gaining insight and benchmarking codes. A construction is given to produce omnigenous B(theta, zeta) patterns with stellarator symmetry.Comment: 37 pages, 8 figure

Spin-Orbital Entanglement and Violation of the Goodenough-Kanamori Rules

We point out that large composite spin-orbital fluctuations in Mott insulators with $t_{2g}$ orbital degeneracy are a manifestation of quantum entanglement of spin and orbital variables. This results in a dynamical nature of the spin superexchange interactions, which fluctuate over positive and negative values, and leads to an apparent violation of the Goodenough-Kanamori rules. [{\it Published in Phys. Rev. Lett. {\bf 96}, 147205 (2006).}]Comment: 4 pages, 2 figure

Modeling software design diversity

Design diversity has been used for many years now as a means of achieving a degree of fault tolerance in software-based systems. Whilst there is clear evidence that the approach can be expected to deliver some increase in reliability compared with a single version, there is not agreement about the extent of this. More importantly, it remains difficult to evaluate exactly how reliable a particular diverse fault-tolerant system is. This difficulty arises because assumptions of independence of failures between different versions have been shown not to be tenable: assessment of the actual level of dependence present is therefore needed, and this is hard. In this tutorial we survey the modelling issues here, with an emphasis upon the impact these have upon the problem of assessing the reliability of fault tolerant systems. The intended audience is one of designers, assessors and project managers with only a basic knowledge of probabilities, as well as reliability experts without detailed knowledge of software, who seek an introduction to the probabilistic issues in decisions about design diversity

Fluid/solid transition in a hard-core system

We prove that a system of particles in the plane, interacting only with a certain hard-core constraint, undergoes a fluid/solid phase transition

Natural orbital functional theory and pairing correlation effects in electron momentum density

Occupation numbers of natural orbitals capture the physics of strong electron correlations in momentum space. A Natural Orbital Density Functional Theory based on the antisymmetrized geminal product provides these occupation numbers and the corresponding electron momentum density. A practical implementation of this theory approximates the natural orbitals by the Kohn-Sham orbitals and uses a mean-field approach to estimate pairing amplitudes leading to corrections for the independent particle model. The method is applied to weakly doped \mbox{La_2$CuO$_4}.Comment: 9 pages, 3 figures. Review paper contribution for the special issue (V.40, No.3 2014) of Fizika Nizkikh Temperatur on New Trends of Fermiology (shorter version

Correlated Persistent Tunneling Currents in Glasses

Low temperature properties of glasses are derived within a generalized tunneling model, considering the motion of charged particles on a closed path in a double-well potential. The presence of a magnetic induction field B violates the time reversal invariance due to the Aharonov-Bohm phase, and leads to flux periodic energy levels. At low temperature, this effect is shown to be strongly enhanced by dipole-dipole and elastic interactions between tunneling systems and becomes measurable. Thus, the recently observed strong sensitivity of the electric permittivity to weak magnetic fields can be explained. In addition, superimposed oscillations as a function of the magnetic field are predicted.Comment: 4 page