Ceramic Sensors for Wireless High-Temperature Sensing

A RF resonator for sensing a physical or environmental parameter includes a substrate having a substrate surface. A polymer-derived ceramic (PDC) element is positioned on or within the substrate surface. The RF resonator has a resonant frequency that changes as a function of the physical or environmental parameter. A system for wirelessely sensing at least one physical or environmental parameter includes at least one RF resonator and a wireless RF reader located remotely from the RF resonator first transmitting a wide-band RF interrogation signal that excites the RF resonator. The wireless RF reader detects a sensing signal retransmitted by the RF resonator and includes a processor for determining the physical or environmental parameter at the location of the RF resonator from the sensing signal

Buckling instability of lipid tubules with multibilayer walls under local radial indentation

The mechanical behavior of self-assembled lipid tubules is an important property which determines their suitability for technological applications. We study the instability of multibilayer lipid tubules (with wall thickness t and external radius R(ext)) beyond elastic response under local radial atomic force microscopy indentations. A discontinuity in force-distance curves associated with the buckling instability of lipid tubules is observed. The critical force at which lipid tubules undergo a buckling transition linearly scales as t/R(ext). In addition, a reduced critical buckling force is found to extend a distance of similar to 1 mu m from the end of lipid tubules

Method for Synthesizing Bulk Ceramics and Structures from Polymeric Ceramic Precursors

A method and product made by using a liquid polymeric ceramic precursor to synthesize dense, crack-free bulk ceramics in a technique using a sacrificial mold provides a ceramic structure for many technical, medical and industrial applications. The novel process uses an open cell material as a sacrificial mold to shape a liquid ceramic precursor during curing. The cured ceramic green body can be machined and shaped to form the desired ceramic structure prior to final pyrolysis. The open cell material forms gas release paths to release large amount of gases generated during the pyrolysis of the cured ceramic precursor. After pyrolysis, an intact, dense, crack-free ceramic structure with high purity, strength and durability is obtained. Uses of the present invention include, but are not limited to, bulk ceramic parts, ceramic crucibles, a replacement material in some applications involving glass, silicon carbides, silicon nitrides, hafnium carbide and the like

On Electric Conduction of Amorphous Silicon Carbonitride Derived from a Polymeric Precursor

A long-existing problem that the conductivity of amorphous silicon carbonitrides derived from polymeric precursor increases significantly with pyrolysis temperature is investigated. We show that the conductivity exhibited an Arrhenius dependence on pyrolysis temperature, with the activation energy of ∼3.41 eV. Structural analysis using Raman spectroscopy reveals that the free carbon within the material undergoes a sp3-to-sp2 transition as pyrolysis temperature increases, with the activation energy of ∼3.6 eV. We conclude that the pyrolysis-temperature induced increase in the conductivity is mainly due to the increase in the conductivity of the free carbon. A simple model is proposed to correlate the two

Ultraviolet photoluminescence from 3C-SiC nanorods

An intensive sharp photoluminescence at 3.3 eV is observed from single-crystal 3C-SiC nanorods. Structural characterization reveals that the nanorods contain a fairly large amount of threefold stacking faults. We tentatively attribute the emission to these stalking faults, which structurally resemble 6H-SiC nano-layers of 1.5 nm embedded in a 3C-SiC matrix. The emission mechanism is discussed in terms of spontaneous polarization at the stacking faults

Wireless passive polymer-derived SiCN ceramic sensor with integrated resonator/antenna

This paper presents a passive wireless polymer-derived silicon carbonitride (SiCN) ceramic sensor based on cavity radio frequency resonator together with integrated slot antenna. The effect of the cavity sensor dimensions on the Q-factor and resonant frequency is investigated by numerical simulation. A sensor with optimal dimensions is designed and fabricated. It is demonstrated that the sensor signal can be wirelessly detected at distances up to 20 mm. Given the high-temperature stability of the SiCN, the sensor is very promising for high-temperature wireless sensing applications

On electronic structure of polymer-derived amorphous silicon carbide ceramics

The electronic structure of polymer-derived amorphous silicon carbide ceramics was studied by combining measurements of temperature-dependent conductivity and optical absorption. By comparing the experimental results to theoretical models, electronic structure was constructed for a carbon-rich amorphous silicon carbide, which revealed several unique features, such as deep defect energy level, wide band-tail band, and overlap between the band-tail band and defect level. These unique features were discussed in terms of the microstructure of the material and used to explain the electric behavior

Inhibition the ubiquitination of ENaC and Na,K-ATPase with erythropoietin promotes alveolar fluid clearance in sepsis-induced acute respiratory distress syndrome

Sepsis-induced acute respiratory distress syndrome (ARDS) causes significant fatalities worldwide and lacks pharmacological intervention. Alveolar fluid clearance (AFC) plays a pivotal role in the remission of ARDS and is markedly impaired in the pathogenesis of ARDS. Here, we demonstrated that erythropoietin could effectively ameliorate lung injury manifestations and lethality, restore lung function and promote AFC in a rat model of lipopolysaccharide (LPS)-induced ARDS. Moreover, it was proven that EPO-induced restoration of AFC occurs through triggering the total protein expression of ENaC and Na,K-ATPase channels, enhancing their protein abundance in the membrane, and suppressing their ubiquitination for degeneration. Mechanistically, the data indicated the possible involvement of EPOR/JAK2/STAT3/SGK1/Nedd4–2 signaling in this process, and the pharmacological inhibition of the pathway markedly eliminated the stimulating effects of EPO on ENaC and Na,K-ATPase, and subsequently reversed the augmentation of AFC by EPO. Consistently, in vitro studies of alveolar epithelial cells paralleled with that EPO upregulated the expression of ENaC and Na,K-ATPase, and patch-clamp studies further demonstrated that EPO substantially strengthened sodium ion currents. Collectively, EPO could effectively promote AFC by improving ENaC and Na,K-ATPase protein expression and abundance in the membrane, dependent on inhibition of ENaC and Na,K-ATPase ubiquitination, and resulting in diminishing LPS-associated lung injuries

A Facile Route to Construct SiCO Nanospheres with Tunable Sizes

Natural Science Foundation of China [51175444, 51075344, 61274120]; Fundamental Research Funds for the Central Universities (Xiamen University) [2011121002]; Xiamen Municipal Bureau of Science and Technology [3502Z20126006]; Shenzhen City Science and Technology Innovation Committee [JCYJ20120618155425009]; National Science and Technology Major Project of the Ministry of Science and Technology of China [2011ZX02709-002]We report a facile route to synthesize SiCO nanospheres using Pluronic F127/ polyvinylsilazane (PVSZ) mixed micelles as a template, in which PVSZ selectively swells with the PEO core of the F127 micelles. The thermal degradation of the F127/ PVSZ mixed micelles leads to the formation of SiCO nanospheres. The size of the resultant SiCO nanospheres can be tuned in the range from 25 nm to 75 nm by controlling annealing time at 70 degrees C