76 research outputs found
Non-invasive Scanning Raman Spectroscopy and Tomography for Graphene Membrane Characterization
Graphene has extraordinary mechanical and electronic properties, making it a
promising material for membrane based nanoelectromechanical systems (NEMS).
Here, chemical-vapor-deposited graphene is transferred onto target substrates
to suspend it over cavities and trenches for pressure-sensor applications. The
development of such devices requires suitable metrology methods, i.e.,
large-scale characterization techniques, to confirm and analyze successful
graphene transfer with intact suspended graphene membranes. We propose fast and
noninvasive Raman spectroscopy mapping to distinguish between freestanding and
substrate-supported graphene, utilizing the different strain and doping levels.
The technique is expanded to combine two-dimensional area scans with
cross-sectional Raman spectroscopy, resulting in three-dimensional Raman
tomography of membrane-based graphene NEMS. The potential of Raman tomography
for in-line monitoring is further demonstrated with a methodology for automated
data analysis to spatially resolve the material composition in micrometer-scale
integrated devices, including free-standing and substrate-supported graphene.
Raman tomography may be applied to devices composed of other two-dimensional
materials as well as silicon micro- and nanoelectromechanical systems.Comment: 23 pages, 5 figure
Colorimetry technique for scalable characterization of suspended graphene
Previous statistical studies on the mechanical properties of
chemical-vapor-deposited (CVD) suspended graphene membranes have been performed
by means of measuring individual devices or with techniques that affect the
material. Here, we present a colorimetry technique as a parallel, non-invasive,
and affordable way of characterizing suspended graphene devices. We exploit
Newton rings interference patterns to study the deformation of a double-layer
graphene drum 13.2 micrometer in diameter when a pressure step is applied. By
studying the time evolution of the deformation, we find that filling the drum
cavity with air is 2-5 times slower than when it is purged
Controlling the threshold voltage of a semiconductor field-effect transistor by gating its graphene gate
The threshold voltage of a field-effect transistor (FED determines its switching and limits the scaling of the supply voltage in the logic gates. Here we demonstrate a GaAs FET with a monolayer graphene gate in which the threshold voltage was externally controlled by an additional control gate. The graphene gate forms a Schottky junction with the transistor channel, modulating the channel conductivity. The control gate sets the work function of the graphene gate, controlling the Schottky barrier height and therefore the threshold voltage, and reduces the subthreshold swing down to similar to 60 mV dec(-1). The change of the threshold voltage was large enough to turn the initially depletion mode FETs into the enhancement mode FETs. This allowed to realize logic gates with a positive switching threshold in which the threshold voltage of each transistor was independently set. The presented FETs can also be operated as dual-gate FETs, which was demonstrated by realizing frequency mixers
Ultra-low contact resistance in graphene devices at the Dirac point
Contact resistance is one of the main factors limiting performance of short-channel graphene field-effect transistors (GFETs), preventing their use in low-voltage applications. Here we investigated the contact resistance between graphene grown by chemical vapor deposition (CVD) and different metals, and found that etching holes in graphene below the contacts consistently reduced the contact resistance, down to 23 Omega . mu m with Au contacts. This low contact resistance was obtained at the Dirac point of graphene, in contrast to previous studies where the lowest contact resistance was obtained at the highest carrier density in graphene (here 200 Omega . mu m was obtained under such conditions). The 'holey' Au contacts were implemented in GFETs which exhibited an average transconductance of 940 S m(-1) at a drain bias of only 0.8 V and gate length of 500 nm, which out-perform GFETs with conventional Au contacts
Semiquantitative Classification of Two Oxidizing Gases with Graphene-Based Gas Sensors
Miniature and low-power gas sensing elements are urgently needed for a portable electronic nose, especially for outdoor pollution monitoring. Hereby we prepared chemiresistive sensors based on wide-area graphene (grown by chemical vapor deposition) placed on Si/Si3N4 substrates with interdigitated electrodes and built-in microheaters. Graphene of each sensor was individually functionalized with ultrathin oxide coating (CuO-MnO2, In2O3 or Sc2O3) by pulsed laser deposition. Over the course of 72 h, the heated sensors were exposed to randomly generated concentration cycles of 30 ppb NO2, 30 ppb O3, 60 ppb NO2, 60 ppb O3 and 30 ppb NO2 + 30 ppb O3 in synthetic air (21% O2, 50% relative humidity). While O3 completely dominated the response of sensors with CuO-MnO2 coating, the other sensors had comparable sensitivity to NO2 as well. Various response features (amplitude, response rate, and recovery rate) were considered as machine learning inputs. Using just the response amplitudes of two complementary sensors allowed us to distinguish these five gas environments with an accuracy of ~ 85%. Misclassification was mostly due to an overlap in the case of the 30 ppb O3, and 30 ppb O3 + 30 ppb NO2 responses, and was largely caused by the temporal drift of these responses. The addition of recovery rates to machine learning input variables enabled us to very clearly distinguish different gases and increase the overall accuracy to ~94%
Electrochemistry at the Edge of a van der Waals Heterostructure
: Artificial van der Waals heterostructures, obtained by stacking two-dimensional (2D) materials, represent a novel platform for investigating physicochemical phenomena and applications. Here, the electrochemistry at the one-dimensional (1D) edge of a graphene sheet, sandwiched between two hexagonal boron nitride (hBN) flakes, is reported. When such an hBN/graphene/hBN heterostructure is immersed in a solution, the basal plane of graphene is encapsulated by hBN, and the graphene edge is exclusively available in the solution. This forms an electrochemical nanoelectrode, enabling the investigation of electron transfer using several redox probes, e.g., ferrocene(di)methanol, hexaammineruthenium, methylene blue, dopamine and ferrocyanide. The low capacitance of the van der Waals edge electrode facilitates cyclic voltammetry at very high scan rates (up to 1000 V s-1 ), allowing voltammetric detection of redox species down to micromolar concentrations with sub-second time resolution. The nanoband nature of the edge electrode allows operation in water without added electrolyte. Finally, two adjacent edge electrodes are realized in a redox-cycling format. All the above-mentioned phenomena can be investigated at the edge, demonstrating that nanoscale electrochemistry is a new application avenue for van der Waals heterostructures. Such an edge electrode will be useful for studying electron transfer mechanisms and the detection of analyte species in ultralow sample volumes
Graphene Reflectarray Metasurface for Terahertz Beam Steering and Phase Modulation
We report a THz reflectarray metasurface which uses graphene as active
element to achieve beam steering, shaping and broadband phase modulation. This
is based on the creation of a voltage controlled reconfigurable phase hologram,
which can impart different reflection angles and phases to an incident beam,
replacing bulky and fragile rotating mirrors used for terahertz imaging. This
can also find applications in other regions of the electromagnetic spectrum,
paving the way to versatile optical devices including light radars, adaptive
optics, electro-optical modulators and screens
Graphene mechanical pixels for Interferometric MOdulator Displays (GIMOD)
Graphene, the carbon monolayer and 2D allotrope of graphite, has the
potential to impact technology with a wide range of applications such as
optical modulators for high-speed communications. In contrast to modulation
devices that rely on plasmonic or electronic effects, MEMS-based modulators can
have wider tuning ranges albeit at a lower operating frequency. These
properties make electro-optic mechanical modulators ideal for reflective-type
display technologies as has been demonstrated previously with SiN membranes in
Interferometric MOdulator Displays (IMODs). Despite their low-power consumption
and performance in bright environments, IMODs suffer from low frame rates and
limited color gamut. Double-layer graphene (DLG) membranes grown by chemical
vapor deposition (CVD) can also recreate the interference effect like in IMODs
as proven with drumheads displaying Newton's rings. Here, we report on the
electro-optical response of CVD DLG mechanical pixels by measuring the change
in wavelength-dependent reflectance of a suspended graphene drumhead as a
function of electrical gating. We use a spectrometer to measure the wavelength
spectrum at different voltages, and find a good agreement with a model based on
light interference. Moreover, to verify that gas compression effects do not
play an important role, we use a stroboscopic illumination technique to study
the electro-optic response of these graphene pixels at frequencies up to 400
Hz. Based on these findings, we demonstrate a continuous full-spectrum
reflective-type pixel technology with a Graphene Interferometric MOdulator
Display (GIMOD) prototype of 2500 pixels per inch (ppi) equivalent to more than
12K resolution.Comment: 13 pages, 4 figure
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