27 research outputs found
Dimensionality, nematicity and Superconductivity in Fe-based systems
Study of Fe based compounds have drawn much attention due to the discovery of
superconductivity as well as many other exotic electronic properties. Here, we
review some of our works in these materials carried out employing density
functional theory and angle resolved photoemission spectroscopy. The results
presented here indicate that the dimensionality of the underlying electronic
structure plays important role in deriving their interesting electronic
properties. The nematicity found in most of these materials appears to be
related to the magnetic long range order. We argue that the exoticity in the
electronic properties are related to the subtlety in competing structural and
magnetic instabilities present in these materials.Comment: 7 figure
Anomalies of a topologically ordered surface
Bulk insulators with strong spin orbit coupling exhibit metallic surface states possessing topological order protected by the time reversal symmetry. However, experiments show vulnerability of topological states to aging and impurities. Different studies show contrasting behavior of the Dirac states along with plethora of anomalies, which has become an outstanding problem in material science. Here, we probe the electronic structure of Bi2Se3 employing high resolution photoemission spectroscopy and discover the dependence of the behavior of Dirac particles on surface terminations. The Dirac cone apex appears at different binding energies and exhibits contrasting shift on Bi and Se terminated surfaces with complex time dependence emerging from subtle adsorbed oxygen-surface atom interactions. These results uncover the surface states behavior of real systems and the dichotomy of topological and normal surface states important for device fabrication as well as realization of novel physics such as Majorana Fermions, magnetic monopole, etc
Observation of pseudogap in MgB2
Pseudogap phase in superconductors continues to be an outstanding puzzle that
differentiates unconventional superconductors from the conventional ones
(BCS-superconductors). Employing high resolution photoemission spectroscopy on
a highly dense conventional superconductor, MgB2, we discover an interesting
scenario. While the spectral evolution close to the Fermi energy is
commensurate to BCS descriptions as expected, the spectra in the wider energy
range reveal emergence of a pseudogap much above the superconducting transition
temperature indicating apparent departure from the BCS scenario. The energy
scale of the pseudogap is comparable to the energy of E2g phonon mode
responsible for superconductivity in MgB2 and the pseudogap can be attributed
to the effect of electron-phonon coupling on the electronic structure. These
results reveal a scenario of the emergence of the superconducting gap within an
electron-phonon coupling induced pseudogap.Comment: 4 figure
Anomalous spectral evolution with bulk sensitivity in BiPd
We investigate the electronic structure of a noncentrosymmetric
superconductor, BiPd using photoemission spectroscopy with multiple photon
energies ranging from ultraviolet to hard x-ray. Experimental data exhibit
interesting difference in the surface and bulk electronic structures of this
system. While the surface Bi core level peaks appear at lower binding energies,
the surface valence band features are found at the higher binding energy side
of the bulk valence band; valence band is primarily constituted by the Pd 4d
states. These changes in the electronic structure cannot be explained by the
change in ionicity of the constituent elements via charge transfer. Analysis of
the experimental data indicates that the Bi-Pd hybridization physics plays the
key role in deriving the anomalous spectral evolution and the electronic
properties of this system.Comment: Proceedings of DAE SSPS 201
Tuning the carrier injection barrier of hybrid metal–organic interfaces on rare earth-gold surface compounds
Magnetic hybrid metal-organic interfaces possess a great potential in areas such as organic spintronics and quantum information processing. However, tuning their carrier injection barriers on-demand is fundamental for the implementation in technological devices. We have prepared hybrid metal-organic interfaces by the adsorption of copper phthalocyanine CuPc on REAu2 surfaces (RE = Gd, Ho and Yb) and studied their growth, electrostatics and electronic structure. CuPc exhibits a long-range commensurability and a vacuum level pinning of the molecular energy levels. We observe a significant effect of the RE valence of the substrate on the carrier injection barrier of the hybrid metal-organic interface. CuPc adsorbed on trivalent RE-based surfaces (HoAu2 and GdAu2) exhibits molecular level energies that may allow injection carriers significantly closer to an ambipolar injection behavior than in the divalent case (YbAu2)
Effect of the valence state on the band magnetocrystalline anisotropy in two-dimensional rare-earth/noble-metal compounds
[EN] In intermetallic compounds with zero orbital momentum (L = 0) the magnetic anisotropy and the electronic band structure are interconnected. Here, we investigate this connection in divalent Eu and trivalent Gd intermetallic compounds. We find by x-ray magnetic circular dichroism an out-of-plane easy magnetization axis in two-dimensional atom-thick EuAu2. Angle-resolved photoemission spectroscopy and density-functional theory prove that this is due to strong f-d band hybridization and Eu2+ valence. In contrast, the easy in-plane magnetization of the structurally equivalent GdAu2 is ruled by spin-orbit-split d bands, notably Weyl nodal lines, occupied in the Gd3+ state. Regardless of the L value, we predict a similar itinerant electron contribution to the anisotropy of analogous compounds.Discussions with the late J. I. Cerda are warmly thanked. Financial support from Spanish Ministerio deCiencia e Innovacion (projects MAT-2017-88374-P, PID2020-116093RB-C44 and PID2019-103910GB-I00 funded by MCIN/AEI/10.13039/501100011033/) , the Basque Govern-ment (Grants No. IT-1255-19 and No. IT1260-19) , and the University of the Basque Country UPV/EHU (Grant No. GIU18/138) is acknowledged. L.F. acknowledges funding from the European Union's Horizon 2020 research and in-novation programme through the Marie Skodowska-Curie Grant Agreement MagicFACE No. 797109. We acknowl-edge SOLEIL for provision of synchrotron radiation facilities at CASSIOPEE beamline under proposal 20181362. The XMCD experiments were performed at BOREAS beamline at ALBA Synchrotron with the collaboration of ALBA staff. Computational resources were provided by DIPC