130 research outputs found
Topological surface transport in epitaxial SnTe thin films grown on BiâTeâ
The topological crystalline insulator SnTe has been grown epitaxially on a BiâTeâ buffer layer by molecular beam epitaxy. In a 30-nm-thick SnTe film, p- and n-type carriers are found to coexist, and Shubnikovâde Haas oscillation data suggest that the n-type carriers are Dirac fermions residing on the SnTe (111) surface. This transport observation of the topological surface state in a p-type topological crystalline insulator became possible due to a downward band bending on the free SnTe surface, which appears to be of intrinsic origin
Ferromagnetism in Cr-doped topological insulator TlSbTe2
We have synthesized a new ferromagnetic topological insulator by doping Cr to the ternary topological-insulator material TlSbTe2. Single crystals of Tl1âx Cr x SbTe2 were grown by a melting method and it was found that Cr can be incorporated into the TlSbTe2 matrix only within the solubility limit of about 1%. The Curie temperature ΞC was found to increase with the Cr content but remained relatively low, with the maximum value of about 4 K. The easy axis was identified to be the c-axis and the saturation moment was 2.8 ÎŒB (Bohr magneton) at 1.8 K. The in-plane resistivity of all the samples studied showed metallic behavior with p-type carriers. Shubnikov-de Hass oscillations were observed in samples with the Cr-doping level of up to 0.76%. We also tried to induce ferromagnetism in TlBiTe2 by doping Cr, but no ferromagnetism was observed in Cr-doped TlBiTe2 crystals within the solubility limit of Cr which turned out to be also about 1%
Band structure engineering in (Bi1-xSbx)2Te3 ternary topological insulators
Three-dimensional (3D) topological insulators (TI) are novel quantum
materials with insulating bulk and topologically protected metallic surfaces
with Dirac-like band structure. The spin-helical Dirac surface states are
expected to host exotic topological quantum effects and find applications in
spintronics and quantum computation. The experimental realization of these
ideas requires fabrication of versatile devices based on bulk-insulating TIs
with tunable surface states. The main challenge facing the current TI materials
exemplified by Bi2Se3 and Bi2Te3 is the significant bulk conduction, which
remains unsolved despite extensive efforts involving nanostructuring, chemical
doping and electrical gating. Here we report a novel approach for engineering
the band structure of TIs by molecular beam epitaxy (MBE) growth of
(Bi1-xSbx)2Te3 ternary compounds. Angle-resolved photoemission spectroscopy
(ARPES) and transport measurements show that the topological surface states
exist over the entire composition range of (Bi1-xSbx)2Te3 (x = 0 to 1),
indicating the robustness of bulk Z2 topology. Most remarkably, the systematic
band engineering leads to ideal TIs with truly insulating bulk and tunable
surface state across the Dirac point that behave like one quarter of graphene.
This work demonstrates a new route to achieving intrinsic quantum transport of
the topological surface states and designing conceptually new TI devices with
well-established semiconductor technology.Comment: Minor changes in title, text and figures. Supplementary information
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Evidence for Layered Quantized Transport in Dirac Semimetal ZrTe5
ZrTe5 is an important semiconductor thermoelectric material and a candidate topological insulator. Here we report the observation of Shubnikov-de Hass (SdH) oscillations accompanied by quantized Hall resistance in bulk ZrTe5 crystal, with a mobility of 41,000 cm2V-1s-1. We have found that the quantum oscillations does not originate from the surface states, but from the bulk states. Each single layer ZrTe5 acted like an independent 2D electron system in the quantum Hall regime having the same carrier density and mobilities, while the bulk of the sample exhibits a multilayered quantum Hall effect
Ultra-low carrier concentration and surface dominant transport in Sb-doped Bi2Se3 topological insulator nanoribbons
A topological insulator is a new state of matter, possessing gapless
spin-locking surface states across the bulk band gap which has created new
opportunities from novel electronics to energy conversion. However, the large
concentration of bulk residual carriers has been a major challenge for
revealing the property of the topological surface state via electron transport
measurement. Here we report surface state dominated transport in Sb-doped
Bi2Se3 nanoribbons with very low bulk electron concentrations. In the
nanoribbons with sub-10nm thickness protected by a ZnO layer, we demonstrate
complete control of their top and bottom surfaces near the Dirac point,
achieving the lowest carrier concentration of 2x10^11/cm2 reported in
three-dimensional (3D) topological insulators. The Sb-doped Bi2Se3
nanostructures provide an attractive materials platform to study fundamental
physics in topological insulators, as well as future applications.Comment: 5 pages, 4 figures, 1 tabl
Aharonov-Bohm interference in topological insulator nanoribbons
Topological insulators represent novel phases of quantum matter with an
insulating bulk gap and gapless edges or surface states. The two-dimensional
topological insulator phase was predicted in HgTe quantum wells and confirmed
by transport measurements. Recently, Bi2Se3 and related materials have been
proposed as three-dimensional topological insulators with a single Dirac cone
on the surface and verified by angle-resolved photoemission spectroscopy
experiments. Here, we show unambiguous transport evidence of topological
surface states through periodic quantum interference effects in layered
single-crystalline Bi2Se3 nanoribbons. Pronounced Aharonov-Bohm oscillations in
the magnetoresistance clearly demonstrate the coverage of two-dimensional
electrons on the entire surface, as expected from the topological nature of the
surface states. The dominance of the primary h/e oscillation and its
temperature dependence demonstrate the robustness of these electronic states.
Our results suggest that topological insulator nanoribbons afford novel
promising materials for future spintronic devices at room temperature.Comment: 5 pages, 4 figures, RevTex forma
Topological crystalline insulator states in Pb(1-x)Sn(x)Se
Topological insulators are a novel class of quantum materials in which
time-reversal symmetry, relativistic (spin-orbit) effects and an inverted band
structure result in electronic metallic states on the surfaces of bulk
crystals. These helical states exhibit a Dirac-like energy dispersion across
the bulk bandgap, and they are topologically protected. Recent theoretical
proposals have suggested the existence of topological crystalline insulators, a
novel class of topological insulators in which crystalline symmetry replaces
the role of time-reversal symmetry in topological protection [1,2]. In this
study, we show that the narrow-gap semiconductor Pb(1-x)Sn(x)Se is a
topological crystalline insulator for x=0.23. Temperature-dependent
magnetotransport measurements and angle-resolved photoelectron spectroscopy
demonstrate that the material undergoes a temperature-driven topological phase
transition from a trivial insulator to a topological crystalline insulator.
These experimental findings add a new class to the family of topological
insulators. We expect these results to be the beginning of both a considerable
body of additional research on topological crystalline insulators as well as
detailed studies of topological phase transitions.Comment: v2: published revised manuscript (6 pages, 3 figures) and
supplementary information (5 pages, 8 figures
Josephson supercurrent through a topological insulator surface state
Topological insulators are characterized by an insulating bulk with a finite
band gap and conducting edge or surface states, where charge carriers are
protected against backscattering. These states give rise to the quantum spin
Hall effect without an external magnetic field, where electrons with opposite
spins have opposite momentum at a given edge. The surface energy spectrum of a
threedimensional topological insulator is made up by an odd number of Dirac
cones with the spin locked to the momentum. The long-sought yet elusive
Majorana fermion is predicted to arise from a combination of a superconductor
and a topological insulator. An essential step in the hunt for this emergent
particle is the unequivocal observation of supercurrent in a topological phase.
Here, we present the first measurement of a Josephson supercurrent through a
topological insulator. Direct evidence for Josephson supercurrents in
superconductor (Nb) - topological insulator (Bi2Te3) - superconductor e-beam
fabricated junctions is provided by the observation of clear Shapiro steps
under microwave irradiation, and a Fraunhofer-type dependence of the critical
current on magnetic field. The dependence of the critical current on
temperature and length shows that the junctions are in the ballistic limit.
Shubnikov-de Haas oscillations in magnetic fields up to 30 T reveal a
topologically non-trivial two-dimensional surface state. We argue that the
ballistic Josephson current is hosted by this surface state despite the fact
that the normal state transport is dominated by diffusive bulk conductivity.
The lateral Nb-Bi2Te3-Nb junctions hence provide prospects for the realization
of devices supporting Majorana fermions
Planar Hall effect from the surface of topological insulators
A prominent feature of topological insulators (TIs) is the surface states comprising of spin-nondegenerate massless Dirac fermions. Recent technical advances have made it possible to address the surface transport properties of TI thin films by tuning the Fermi levels of both top and bottom surfaces. Here we report our discovery of a novel planar Hall effect (PHE) from the TI surface, which results from a hitherto-unknown resistivity anisotropy induced by an in-plane magnetic field. This effect is observed in dual-gated devices of bulk-insulating Bi2âx Sb x Te3 thin films, where the field-induced anisotropy presents a strong dependence on the gate voltage with a characteristic two-peak structure near the Dirac point. The origin of PHE is the peculiar time-reversal-breaking effect of an in-plane magnetic field, which anisotropically lifts the protection of surface Dirac fermions from backscattering. The observed PHE provides a useful tool to analyze and manipulate the topological protection of the TI surface
Highly efficient and robust cathode materials for low-temperature solid oxide fuel cells: PrBa0.5Sr0.5Co2-xFexO5+delta
Solid oxide fuel cells (SOFC) are the cleanest, most efficient, and cost-effective option for direct conversion to electricity of a wide variety of fuels. While significant progress has been made in anode materials with enhanced tolerance to coking and contaminant poisoning, cathodic polarization still contributes considerably to energy loss, more so at lower operating temperatures. Here we report a synergistic effect of co-doping in a cation-ordered double-perovskite material, PrBa 0.5 Sr 0.5 Co 2-x Fe x O 5+??, which has created pore channels that dramatically enhance oxygen ion diffusion and surface oxygen exchange while maintaining excellent compatibility and stability under operating conditions. Test cells based on these cathode materials demonstrate peak power densities ???2.2â�...W cm -2 at 600 C, representing an important step toward commercially viable SOFC technologies.open16
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