Local electromagnetic properties of magnetic pnictides: A comparative study probed by NMR measurement

75As and 31P NMR studies are performed in PrCoAsO and NdCoPO respectively. The Knight shift data in PrCoAsO indicate the presence of an antiferromagnetic interaction between the 4f moments along the c axis in the ferromagnetic state of Co 3d moments. We propose a possible spin structure in this system. The 75As quadrupolar coupling constant, $\nu_Q$ increases continuously with the decrease of temperature and is found to vary linearly with the intrinsic spin susceptibility, Kiso. This indicates a possibility of the presence of a coupling between charge density and spin density fluctuations. Further, 31P NMR Knight shift and spin lattice relaxation rate (1/T1) in the paramagnetic state of NdCoPO indicate that the differences between LaCoPO and NdCoPO with SmCoPO are due to the decrement of inter layer separation and not due to the moments of 4f electrons. Nuclear spin lattice relaxation time (T1) in NdCoPO shows weak anisotropy at 300 K. Using self consistent renormalization (SCR)theory of itinerant ferromagnet, it is shown that in the ab plane, the spin fluctuations are three dimensional ferromagnetic in nature. From SCR theory the important spin fluctuation parameters ($T_0$, $T_A$, $\bar{F}_1$) are evaluated. The similarities and dissimilarities of the NMR results in As and P based systems, with different rare earths have also been discussed.Comment: 18 pages,13 figures, accepted for publication in J. Phys. Condens. Matte

PRICE LINKAGES IN THE INTERNATIONAL WHEAT MARKET

This paper brings time series techniques to bear on the relationships between the prices of the principal types of wheat traded internationally. In all, the relationships between eleven wheat prices (categorised by wheat quality, harvest date and port of despatch) are scrutinised to uncover the structure of the wheat market implicit in the behaviour its prices reveal. The statistical evidence supports the notion of a highly integrated market that is segmented according to wheat strength-the principal determinant of end-use. Three segments are identified: a market for 'strong' (bread-making) wheat, another for 'weak' (confectionary products-making) wheat and a third for medium strength wheat suitable for unleavened breads and noodles. Whilst informative, market integration - detected by cointegration among prices - is not altogether surprising, yet the presence of cointegration implies a causal structure, which is of more cogent interest. Among a number of complementary techniques, linkages are uncovered using an innovative concept of irreducible cointegration vectors (Davidson 1998, Barassi et al 2001) which provides new evidence on price linkages. Statistical evidence is robust and not test-dependent. Specifically, we find a dominant price leader in each sub-market. In terms of its pricing, the EU is found to play a passive role in the world market, confirming a widely held view.Wheat market, price linkages, irreducible cointegration vectors, Crop Production/Industries, International Relations/Trade,

Study of electron spin dynamics in grain aligned LaCoPO: an itinerant ferromagnet

139La NMR study was performed in grain aligned (c|| H0) sample of LaCoPO and polycrystalline LaFePO. Knight shift is isotropic and temperature independent in LaFePO. It is strongly temperature dependent and anisotropic in LaCoPO. The spin-lattice relaxation rate in LaCoPO clearly reveals the existence of 3D spin fluctuations both in the paramagnetic and ferromagnetic state over and above the dominant 2D spin fluctuations in the paramagnetic state, observed earlier from 31P NMR measurements in the same oriented sample. The spin fluctuation parameters in LaCoPO determined from 139La NMR relaxation and magnetization data, using the self consistent renormalization (SCR) theory, are in close agreement and follow the universal Rhodes-Wohlfarth curve.Comment: Accepted in PR

On the long-run dynamics of income and wealth inequality

We analyse top income and wealth shares data, by conducting a robust estimation of trends, tests for structural breaks, and tests for determining persistence. We include Anglo-Saxon countries, continental Europe and Asian countries, grouped under different percentiles and deciles, spanning a period that is at least close to a century. We find that the top income shares for almost all countries are characterised by broken trends, or level shifts. The preponderance of trend breaks appears in the 1970s and 1980s where after a negative trend changes in magnitude or direction. Finally, shocks to the top income share data are not transitory, which have consequences for policy such as advocating redistributive measures

Crossover of the dimensionality of 3d spin fluctuations in LaCoPO

dc magnetization and 31^P spin lattice relaxation rate in the polycrystalline sample of LaCoPO suggest a spin fluctuation dominated ferromagnetically ordered state. Moreover, NMR data clearly indicate a crossover from 2D to 3D spin fluctuations across T_C. In contrast to isotropic hyperfine field, H_hf at the 31^P site in LaFePO, H_hf is anisotropic in LaCoPO. The data of spin lattice relaxation rate also exhibit anisotropic spin fluctuation. The anisotropy vanishes near T_C

Long-range and short-range magnetic correlations, and microscopic origin of net magnetization in the spin-1 trimer chain compound CaNi3P4O14

Spin-spin correlations and microscopic origin of net magnetization in the spin-1 trimer chain compound CaNi3P4O14 have been investigated by powder neutron diffraction. The present study reveals a 3D long-range magnetic ordering below 16 K where the magnetic structure consists of ferromagnetic trimers that are coupled ferromagnetically along the spin-chain. The moment components along the a and c axes arrange antiferromagnetically. Our study establishes that the uncompensated moment components along the b axis result in a net magnetization per unit cell. The magnetic structure, determined in the present study, is in agreement with the results of recent first principles calculation; however, it is in contrast to a fascinating experimental prediction of ferrimagnetic ordering based on the periodicity of the exchange interactions in CaNi3P4O14. Our study also confirms the presence of broad diffuse magnetic scattering, due to 1D short-range spin-spin correlations, over a wide temperature range below ~50 K down to a temperature well below the Tc. Total neutron scattering analysis by the RMC method reveals that the dominating spin-spin correlation above Tc is ferromagnetic and along the b axis. The nearest neighbour spin-spin correlations along the a and c axes are found to be weakly antiferromagnetic. The nature of the trimer spin structure of the short-range state is similar to that of the 3D long-range ordered state. The present investigation of microscopic nature of the magnetic ground state also explains the condition required for the 1/3 magnetization plateau to be observed in the trimer spin-chains. In spite of the S=1 trimer chain system, the present compound CaNi3P4O14 is found to be a good realization of 3D magnet below the Tc=16 K with full ordered moment values of ~2 mu_B/Ni2+ (1.98 and 1.96 mu_B/Ni2+ for two Ni sites, respectively) at 1.5 K.Comment: 10 pages, 8 figure