Seasonal Variation in Heavy Metal Content of Lake and Underground Water in Some Selected Towns around the Bosomtwe Crater Lake

The levels of Arsenic, Iron, Lead, Zinc, Chromium, Cadmium and Nickel in water samples from Lake Bosomtwe and Bore Holes in some towns around the Lake have been determined using Atomic Absorption Spectrophotometer (Varian AAS 220). The levels of Arsenic, Cadmium and Nickel were generally small and were below the detection limit of the instrument. The results showed seasonal variations in the mean levels of Pb, Fe, Zn and Cr in water from the Bosomtwe Crater Lake. There were significant correlations between the mean levels of Fe and Pb in the underground water in the two seasons whilst Zn and Cr showed weak correlation in underground water for the wet and dry seasons. The levels of the metals in the bore holes were generally below the WHO standard values compared to the levels of the metals in the water samples from the lake. The mean pH values for water samples from the bore holes in the towns around the Bosomtwe Crater Lake were within the WHO standard of 6.50-8.50. Keywords: Lake Bosomtwe, Borehole, Crater, Heavy metals, Atomic Absorption Spectrophotometer

Chemical Analysis of Freshwater Bodies in the Kumasi Metropolis and Its Environs, Ghana

One of the main environmental problems facing the city of Kumasi the second largest city in Ghana over the years has been the pollution of water bodies arising from anthropogenic activities. This has become a potential health threat to the inhabitants of the city which was formerly referred to as the garden city of Ghana and its environs. The most affected are the surrounding rural areas that rely solely on the rivers for drinking, domestic and agricultural purposes. This study focused on the extent of chemical pollution of these water bodies through the determination physicochemical parameters such as pH, temperature, conductivity, total dissolved solids (TDS), Total suspended solids (TSS), alkalinity, Total hardness, nitrates, sulphates as well as heavy metals and biological contamination through the determination of total coliform and Escherichia coli. Eight samples were taken from three main rivers in the Kumasi metropolis namely Wiwi, Sisa and Subin. This data showed variations in the parameters in the samples as follows: pH, 6.67-7.50; temperature, 28-29°C; electrical conductivity (EC), 220-2120 mS/cm; TDS,10-1800 mg/l; alkalinity, 24-124 mg/l; total hardness, 25-365 mg/l; nitrates, b/d-0.47 mg/l; sulphate,0.352-40.30 ; phosphates, 5.2-30 mg/l; Pb, 6.620-6.797 mg/l; Fe. 14.81-45.65 mg/l; Mn, 0.726-4.7427 mg/l; Cd, 0.156-0.219 mg/l; Cr, 0.03-0.10 mg/l; Ni, 0.002-0.018 mg/l; Cu 0.113-2.258 mg/l and Zn 0.368-5.255 mg/l.  However, all the results obtained for the levels of the metals exceeded the EPA Maximum contaminant level (MCL) with the exception of the zinc where only one of the samples exceeded the MCL level. Keyword: environmental, chemical pollution, Maximum contaminant level, physicochemical parameters, Kumasi-Ghan

Water quality assessment of streams draining the Akwapim Ridge of Ghana

Surface water samples from seven streams on the Akwapim Ridge were analysed over a period of 1 year for various water quality parameters following standard methods prescribed in APHA, AWWA, WEF and AOAC. The study was carried out in order to assess the suitability of the streams for drinking and other domestic purposes. Additionally, the effect of land use activities was assessed. The study revealed that, generally, most of the physico-chemical parameters of the streams were below the World Health Organization (WHO) limits recommended for drinking water, with the exception of the levels of sulphate and conductivity in three of the streams (Opiafo: 224 mg/1, 908.5 ìS/cm; Kwati: 221.3 mg/1, 920 ìS/cm; and Ademi: 246 mg/1, 1292 ìS/cm), respectively, which were above the WHO requirements. Nevertheless, taking these factors into consideration (except the sulphate and conductivity), the waters may be regarded as excellent and good for drinking and other domestic uses

Defluorination of drinking water using surfactant modified zeolites

The prevalence of high concentrations of fluoride (i.e. > 1.5 mg/l) in groundwater in the Northernpart of Ghana especially around the Bongo communities has been an issue of concern.Owingto the arid nature of these localities, the inhabitants (who are mainly peasant farmers), relymore on groundwater sources for their drinking water. With the strenuous nature of their joband the warm weather conditions, the farmers generally consume more water, thus becomingmore vulnerable to dental and skeletal fluorosis. This study focused on the removal of fluoridefrom groundwater by employing surfactant modified zeolites (SMZ) synthesized using locallyavailable kaolin material as precursor. The zeolite synthesis involved calcination of kaolin, alkaline fusion and hydrothermal treatment. The final product was modified with 5g/L Hexadecyltrimethylammonium bromide (HDTMABr). The zeolite was characterised by Xray Diffraction(XRD), Energy Dispersive Xray (EDX) and Scanning Electron Microscopy (SEM) and the modified form employed in batch fluoride removal studies. The fluoride adsorption kinetics was studiedusing model water with varying initial fluoride concentration. From the EDX analysis, the synthesized zeolite NaLSX was found to comprise predominantly Oxygen (60%), Silicon (15%), and Aluminium (13%). The SEM showed the zeolite NaLSX crystals to be octahedrally shaped. The unmodified zeolite NaLSX was incapable of adsorbing fluoride ions but the surfactant modified zeolite adsorbed fluoride. The fluoride adsorption capacity of the modified zeolite was pH dependent and peaked at pH 6.0 – 7.0. Keywords: characterization, defluoridation, groundwater, surfactant, zeolite

Pesticide residues in fish from the Densu River Basin in Ghana

The Densu River is a typical river flowing through agricultural areas in Southern Ghana. Six fish species from different locations in the river were sampled and analyzed for residues of pesticides and metabolites using GC with ECD/FID. The results of the study indicate that all the detected residues and metabolites in fish samples from the Densu River Basin were organochlorines (OCs). Among the pesticides residues analyzed, DDE, α-endosulfan, γ- HCH, δ- HCH, heptachlor and endosulfan sulphate, were predominant in all the samples. About 50% of the samples recorded positive detection of DDE while α-endosulfan was detected in 60% of the samples. γ- HCH, δ- HCH were detected in 75% and 65% of the samples respectively with heptachlor occurring in 80% of the samples. In almost all the fish species analyzed, DDE was the predominant compound having a mean value of 7.99 μgKg-1. Higher concentrations of pesticide residues were detected in fish samples from the Densu River at Nsawam than the other locations. The total concentration of residues in the fish samples ranged between 0.49 μgKg-1 and 8.90 μgKg-1 with the highest level detected in Hepsetue odoe (HO-N). The sequence of pesticide residues detected in fish samples were HO-N > HN-N > CO-N > CG-N > TZ-N > CN-W > TZ-W > CG-W. The high ratio of DDE/DDT in fish samples (0.1 – 6.9 with a mean of 2.51) indicated probably old input of DDT and significant degradation. The γ -HCH isomer (lindane) was the dominant HCH in fish samples suggesting a preferential usage of lindane (purified γ-HCH) in these areas. The δ-HCH/γ-HCH ratios in most fish samples were low indicating the present input of the pesticide lindane from non-point sources.Keywords: Pesticide residues, Fish, Densu River Basin, Ghana, exposur

Barriers and facilitators to implementation of cancer treatment and palliative care strategies in low- and middle-income countries: systematic review

© 2018, Swiss School of Public Health (SSPH+). Objectives: To appraise improvement strategies adopted by low- and middle-income countries to increase access to cancer treatments and palliative care; and identify the facilitators and barriers to implementation. Methods: A systematic review was conducted and reported in accordance with PRISMA statement. MEDLINE, CINAHL, and the Cochrane Library databases were searched. Bias was assessed using the Standards for Quality Improvement Reporting Excellence, and evidence graded using the Australian National Health and Medical Research Council system. Results: Of 3069 articles identified, 18 studied were included. These studies involved less than a tenth (n = 12, 8.6%) of all low- and middle-income countries. Most were case reports (58%), and the majority focused on palliative care (n = 11, 61%). Facilitators included: stakeholder engagement, financial support, supportive learning environment, and community networks. Barriers included: lack of human resources, financial constraints, and limited infrastructure. Conclusions: There is limited evidence on sustainable strategies for increasing access to cancer treatments and palliative care in low- and middle-income countries. Future strategies should be externally evaluated and be tailored to address service delivery; workforce; information; medical products, vaccines, and technologies; financing; and leadership and governance

Impurity and quaternions in nonrelativistic scattering from a quantum memory

Models of quantum computing rely on transformations of the states of a quantum memory. We study mathematical aspects of a model proposed by Wu in which the memory state is changed via the scattering of incoming particles. This operation causes the memory content to deviate from a pure state, i.e. induces impurity. For nonrelativistic particles scattered from a two-state memory and sufficiently general interaction potentials in 1+1 dimensions, we express impurity in terms of quaternionic commutators. In this context, pure memory states correspond to null hyperbolic quaternions. In the case with point interactions, the scattering process amounts to appropriate rotations of quaternions in the frequency domain. Our work complements a previous analysis by Margetis and Myers (2006 J. Phys. A 39 11567--11581).Comment: 16 pages, no figure

Development of the ‘REadiness SElf-assessment (RESEA) guide’ to assist low and middle-income countries with establishing safe and sustainable radiotherapy services: a pragmatic sequential mixed qualitative methods project

Background: Improving access to radiotherapy services in low and middle-income countries (LMICs) is challenging. Many LMICs’ radiotherapy initiatives fail because of multi-faceted barriers leading to significant wastage of scarce resources. Supporting LMICs to self-assess their readiness for establishing radiotherapy services will help to improve cancer outcomes by ensuring safe, effective and sustainable evidenced-based cancer care. The aim of the study was to develop practical guidance for LMICs on self-assessing their readiness to establish safe and sustainable radiotherapy services. Methods: The Access to Radiotherapy for Cancer treatment (ARC) Project was a pragmatic sequential mixed qualitative methods design underpinned by the World Health Organisation’s ‘Innovative Care for Chronic Conditions Framework’ and ‘Health System Building Blocks Framework for Action’ conceptual frameworks. This paper reports on the process of overall data integration and meta-inference from previously published components comprising a systematic review and two-part qualitative study (semi-structured interviews and a participant validation process). The meta-inferences enabled a series of radiotherapy readiness self-assessment requirements to be generated, formalised as a REadiness SElf-Assessment (RESEA) Guide’ for use by LMICs. Findings: The meta-inferences identified a large number of factors that acted as facilitators and/or barriers, depending on the situation, which include: awareness and advocacy; political leadership; epidemiological data; financial resources; basic physical infrastructure; radiation safety legislative and regulatory framework; project management; and radiotherapy workforce training and education. ‘Commitment’, ‘cooperation’, ‘capacity’ and ‘catalyst’ were identified as the key domains enabling development of radiotherapy services. Across these four domains, the RESEA Guide included 37 requirements and 120 readiness questions that LMICs need to consider and answer as part of establishing a new radiotherapy service. Conclusions: The RESEA Guide provides a new resource for LMICs to self-assess their capacity to establish safe and sustainable radiotherapy services. Future evaluation of the acceptability and feasibility of the RESEA Guide is needed to inform its validity. Further work, including field study, is needed to inform further refinements. Exploratory and confirmatory factor analyses are required to reduce the data set and test the fit of the four-factor structure (commitment, cooperation, capacity and catalyst) found in the current study

Consumers behavior, attitudes, and beliefs regarding baobab (Adansonia digitata L.) fruit and pulp consumption in Sudan

There are growing number of empirical studies on the baobab value chain in Sub-Saharan Africa. Most studies focus on nutritional composition, traditional uses, the distribution of baobab trees, and collection. However, there are few studies on the marketing of baobab fruit pulp, especially on consumer behavior, attitudes, and beliefs regarding baobab fruit pulp. In this context, our study aims to explore consumer behavior, attitudes and beliefs regarding baobab fruit pulp. We also evaluate the market development potential of baobab fruit pulp in selected markets in El Obeid and Khartoum in Sudan. The study employs a mixed methods approach that includes a survey (N = 499), focus group discussion (N = 16), stakeholder interviews (N = 2), and a SWOT analysis. The study shows that the consumption of baobab fruit pulp is common among Sudanese consumers. Consumers also show strong positive attitudes and beliefs, as well as social support for baobab consumption. Nutritional and health benefits tend to drive consumer interest in baobab fruit pulp. The study also identified high demand, export opportunities, and extraction of ingredients from baobab as opportunities to develop baobab markets. However, a lack of quality control, regulations, poor distribution, and insufficient fruit supply may limit exploration of these opportunities. Therefore, it is crucial to raise knowledge of the nutritional and functional properties of baobab fruit, as well as its ability to fight health-related diseases, to further develop local markets. Processors must also improve the quality and safety of their goods. Policymakers must also create a regulatory structure that supports Sudan’s baobab value chain.Peer Reviewe

The perception and preference of consumers for local poultry meat in the Kumasi metropolis of Ghana

The study examined the preference for and perception of consumers concerning the locally produced poultry meat in the Kumasi metropolis in the Ashanti Region of Ghana. Fifty consumers were randomly selected. The results demonstrated that most consumers preferred the local poultry meat to the imported meat. The logit estimates indicated that factors such as age, gender, cold store, cut parts, and healthiness significantly influence consumers’ preference for the locally produced poultry meat. Age, gender and healthiness positively influence consumer’s preference, while cold store and cut parts negatively associated with consumer preference for local poultry meat. On the perception, 68 per cent of the consumers strongly agreed that local poultry meat is tough, while 58 per cent alleged that imported poultry meat is rather tough. In terms of affordability, 46 per cent of the consumers disagreed that local poultry meat is affordable, while 52 per cent strongly objected to the idea that imported poultry meat is relatively cheaper. In terms of availability, 54 per cent of the consumers admitted that local poultry meat is not readily available, while 58 per cent indicated that imported poultry meat is readily available and can be obtained at anytime. Sixty per cent of the respondents were of the opinion that local poultry meat taste better, while 46 per cent of the respondents indicated that imported poultry meat do not taste better. This was probably due to long period of refrigeration, which reduced its freshness and taste and made it less healthy for consumption. It is suggested that the government should subsidize the cost of inputs for the local poultry industry, since the results indicated that high cost was the major factor that influenced consumers’ purchasing decision