A Review on Submarine Groundwater Discharge

海底地下水排泄(Sgd)是全球水循环的一个重要组成部分,是陆—海相互作用的研究热点。首先分析了海底地下水排泄的组成和驱动力,总结了海底地下水排泄的主要评价方法及其优缺点;其次阐述了海底地下水排泄向海洋输送溶解物质的重要作用及其对海洋生态环境的影响,并通过剖析咸淡水混合带的地球化学过程,指出地下河口在研究海底地下水排泄中的重要地位;最后给出未来海底地下水排泄的研究方向。Submarine Groundwater Discharge( SGD),an important part of global water cycle,is recently recognized as a research highlight on the land-ocean interaction in the coastal zone.Firstly,This paper analyzes the components and driving force of SGD,and summarizes the main estimating methods of SGD and its individual strengths and weaknesses.Secondly,the paper describes the important role of SGD in transporting dissolved mass into the costal ocean and significant impacts on the ecological environment of costal ocean,and through analyzing the biogeochemical process in the mixing zone of fresh-salt water,indicates the important position of subterranean estuary in studying submarine groundwater discharge.Finally,the paper points out the major problems currently existing in SGD research,then presents the future research direction.国家自然科学基金面上项目“海底地下水排泄(SGD)的地球化学过程、物质输送及其对海洋的贡献和影响”(编号:41372242)资

ANALYSIS OF ECOSYSTEM INCORPORATED WITH WATER-CIRCLE SYSTEM IN INLAND BASIN OF NORTHWEST CHINA

西北内陆盆地生态环境特别脆弱 ,生态环境与水资源息息相关。该文将内陆河流域作为水循环 -生态复合系统 ,分析了复合系统的结构、功能和水循环特点 ,对于流域水资源开发和生态环境保护有一定指导意义。 【英文摘要】 The ecosystem, closely related to water resources, is very vulnerable in inland basin of northwest China. The paper takes inland basin as a composite ecosystem incorporated with water-circle system. The structure and function of ecosystem are analyzed, simultaneously, the characteristics of water-circle system are discussed, which are helpful for exploiting water resources and protecting eco-environmen

Estimating Submarine Groundwater Discharge into the Jiaozhou Bay Using ~(226)Ra

海底地下水排泄(SGD)是全球水循环的一个组成部分,其输送的溶解物质不仅参与海洋的生物地球化学循环,而且影响近岸海域的生态环境。为了评估胶州湾海底地下水排泄状况,通过建立胶州湾内海水中226Ra的质量平衡模型来计算海底地下水排泄通量。胶州湾海水中226Ra的源主要有河流的输入、沉积物扩散输入和地下水的输入,海水系统在稳定状态下,这几种源应该与湾内海水和湾外海水的混合损失达到平衡。除了将地下水输入作为未知项外,对其他源和汇逐个进行量化,计算得知:2011年9—10月胶州湾的海底地下水排泄通量为7.85×10~6m~3·d~(-1);2012年4—5月胶州湾的海底地下水排泄通量为4.72×106m~3·d~(-1)。在此基础上,对地下水输入胶州湾的营养盐进行了评价。Submarine groundwater discharge( SGD) is a part of global water cycle,which delivers a large amount of solutes to the biogeochemical cycle and affects the coastal ecological environment. The ~(226)Ra mass balance model was established to estimate the submarine groundwater discharge to the Jiaozhou Bay. The ~(226)Ra sources include river transport,sediment diffusion and SGD,these sources should be in balance with the mixing loss of the bay water and open seawater when the seawater system is in the stable state. Except for the SGD was unknown item,other sources and sinks were quantified one by one. Calculated results showed that the SGD fluxes during September to October in 2011 was 7. 85 × 106m~3·d~(-1),April to May in 2012 was 4. 72 × 106m~3·d~(- 1). Based on the SGD fluxes,the SGD derived nutrient fluxes were estimated.国家自然科学基金项目(41072174)~

The Estimation of Submarine Inputs of Groundwater to a Coastal Bay Using Radium Isotopes

福建省漳州市隆教湾海水中镭同位素的研究,目的是评价海底地下水排泄量。在2007年6月的航次中,垂直于岸线的9km剖面上布置15个站位,每个站位用潜水泵采集表层海水样60L于塑料桶中。水样运回实验室后,立即用装有锰纤维的PVC管以虹吸的方式富集水样中的镭同位素,水通过PVC管的流速小于300ml/min。224Ra活度用连续射气法测定,测完224Ra后密封7d以上,然后用直接射气法测定226Ra活度。224Ra和226Ra活度都呈现自岸向海逐渐降低的规律,表明扩散控制镭同位素的分布,由224Ra获得68.83km2d-1的扩散系数,同时226Ra形成-0.963dpm100l-1km-1的活度梯度。用扩散系数和活度梯度建立的226Ra的离岸通量为6.62×1011dpmkm-2d-1,这个通量一定是得到SGD输入的镭支持,从而获得隆教湾的海底地下水排泄量是3.03×109m3km-2d-1。该排泄量包括陆源地下淡水排泄量和再循环海水排泄量,绝大部分可能是再循环海水,有待进一步研究。This paper reports the results of initial research on radium isotopes of surface ocean waters in the Longjiao Bay on the western flank of Taiwan Strait. The main objective of this research is to assess the submarine groundwater discharge (SGD). In order to assess the spatial distribution of 224Ra and 226Ra, the authors collected 15 surface ocean water samples (ca. -1 m in depth) during the low tide. The collection was performed within a period of 2 hours in the direction from onshore to 9 km offshore by using 60 L polypropylene buckets. In the laboratory, the water samples were immediately treated through gravity-fed PVC column (4.5 cm in diameter, 50 cm in length), filled with manganese oxide-impregnated acrylic fiber at a flow rate of ~300 ml/min to retain radium. After that, the activities of 224Ra absorbed on the Mn-fiber were measured through the continuous emanation method. Finally, the Mn-fiber was sealed for more than 7 days, and the activities of 226Ra absorbed on the Mn-fiber were measured through the direct emanation method. 226Ra distribution yields an activity gradient of -0.963 dpm100 l-1km-1. The short-lived 224Ra distribution in this region yields an eddy diffusion coefficient of 68.83 km2d-1. The interpretation is that the eddy diffusion is the primary controlling agent for the shore perpendicular distribution of the long-lived 226Ra. In order to estimate the seepage rate of groundwater in the study area, the authors applied the approach developed by Moore. The short-lived radium isotopes, 224Ra, were used to establish the eddy diffusion coefficient for the near-shore study area. The product of the eddy diffusion coefficient and the offshore 226Ra activity gradient established the 226Ra flux of 6.62×1011dpmkm-2d-1. It is expected that this flux must be balanced by Ra input from the submarine groundwater discharge (SGD). On the basis of the flux of SGD within the shore, 226Ra budget was calculated as 3.03×109 m3km-2d-1. This magnitude of SGD includes terrestrially-derived fresh SGD and recirculated seawater SGD, However, further researches should be required to determine the terrestrially-derived fresh SGD on the one hand, and recirculated seawater SGD on the other hand.国家自然科学基金项目(编号:40672166)资

HYDROCHEMICAL COMPONENT AND ITS DYNAMIC TRENDS OF GROUNDWATER IN THE PLAIN OF SANTUN RIVER BASIN

该文依据水文地质条件将三屯河流域平原区划分为单一结构潜水子系统和多层结构潜水 -浅层承压水子系统及深层承压水子系统。通过地下水水质简分析数据 ,分析了各地下水子系统中主要离子 ,TDS和水化学类型的特征及其变化 ,并初步讨论了地下水系统的水循环特点In accordance with hydrogeological condition, three groundwater systems are presented in the paper, they are the phreatic water systems with single-layer structure, phreatic water together with shallow confined groundwater system and deep confined groundwater with multi-layer structures in the plain of Santun river basin The component and distribution of the major ions, TDS and hydrochemical types and their variations of the above-mentioned groundwater systems are analyzed, meanwhile, the circulatory characteristics of groundwater system are discussed preliminarily九五”国家重点科技攻关项目 (96 - 91 2 - 0 1 - 0 3S

Nutrition Content and Indicator Value of Chlorion for Groundwater in Xiamen Island

该文以厦门岛地下水为研究对象 ,研究了地下水中营养盐含量的空间分布和变化。结果表明 2 0 0 1年DIN(无机氮总 -N)含量的变化范围是 2 0 1 2～ 136 8 1μg dm3,PO4 -P含量的变化范围是 9 2～ 1190 0 μg dm3。从 1999年至 2 0 0 0年 ,DIN含量的变化范围是 74～ 2 0 6 8μg dm3,PO4 -P含量的变化范围是 70 9～ 182 5 μg dm3。同时该文将地下水中氯离子作为海水入侵指标 ,根据氯离子背景值确定出海水入侵氯含量指标值。 【英文摘要】 The paper takes the groundwater as research object in Xiamen Island.Regional distributions of the nutrition content (NH 3-N、NO 2-N、NO 3-N and PO 4-P)in the groundwater are studied. The results showed that content of DIN for 2001 year ranges from 201.2μg/dm3 to 1368.1μg/dm3 and content of PO 4-P ranges from 9.2μg/dm3 to 1190.0μg/dm3, in Xiamen Island. From 1999 to 2000 year,in Zengcuoan village, DIN ranges from 74μg/dm3 to 2068μg/dm3 and PO 4-P ranges from 709μg/dm3 to 1825 μg/dm3.Chlorion was used as..

Temporal and spatial variation of nutrients in the rivers around Jiaozhou Bay and its fluxes into the sea

本文选取胶州湾周边5条主要入海河流作为研究对象,于2011秋季和2012年春季,测定了河流中无机营养盐的浓度水平,调查了各河流营养盐的主要来源,分析了营养盐的时空变化及成因,并计算了营养盐的入海通量.结果表明,各流域nO-3-n、SIO2-3-SI、nH+4-n、nO-2-n浓度主要表现为秋季较高,PO3-4-P浓度春季较高.白沙河、洋河流域营养盐主要来源为面源污染;墨水河、李村河流域营养盐主要来源于工业废水和生活污水;大沽河流域营养盐主要来源于农田径流和生活污水.除nH+4-n入海通量为墨水河最高外,其余各项营养盐入海通量均为大沽河最高.dIn、PO3-4-P、SIO2-3-SI入海通量分别为373.74x103MOl·d-1、7.08x103MOl·d-1、73.16x103MOl·d-1,n∶P∶SI数量比约为53∶1∶10.River runoff is the most important discharge pathway from mainland to sea,which is one of the reasons that the eutrophication and red tide occur frequently in parts of Jiaozhou Bay.The nutrient investigations about five relatively big rivers around Jiaozhou Bay were conducted in autumn of 2011 and spring of 2012,respectively.We measured the nutrient concentrations in river water, investigated the main resources of nutrients,analyzed the temporal and spatial variations of nutrients and its causes, and calculated the nutrient fluxes to Jiaozhou Bay.Results show that the concentrations of NO-3-N, SiO2-3-Si, NH+ 4-N and NO-2-N are higher in autumn while the concentration of PO3-4-P is higher in spring.Non-point source pollution is the main source of nutrients in Baisha River and Yang River.Industrial wastewater,urban sewage and household wastes are the main sources of nutrient in Moshui River,and the nutrients originate mainly from farmland runoff and sewage in Dagu river.Except for NH+ 4-N flux which is much higher in Moshui River,all other nutrient fluxes to the sea are comparatively higher in Dagu River.The calculated fluxes for DIN,PO3-4-P and SiO2-3-Si are 373.74 × 103mol·d- 1,7.08 ×103mol·d- 1and 73.16 × 103mol·d- 1, respectively,and the ratio of N,P and Si within the fluxes is 53 ∶ 1 ∶ 10.国家自然科学基金项目资助(41072174)资

Characteristics of Radium Desorption from Sediments in the Salt Water Environment

海底沉积物向上覆水体扩散的镭是海洋水体中镭同位素的重要来源之一。为了研究沉积物中镭同位素的解吸和扩散特点,进行了不同盐度和不同粒度条件下224rA和226rA解吸的模拟实验,并通过多个时间段的沉积物培养实验获取224rA和226rA的扩散通量。实验结果表明:随着水体盐度增大,沉积物中224rA、226rA的解吸量随之增加,在盐度为25时,解吸量基本达到最大值;在同一咸水环境条件下,4个粒级(2000~1000μM、1000~500μM、500~250μM、250~125μM)的沉积物的224rA、226rA解吸量比较接近,粒级>2000μM的224rA、226rA解吸量略高于上述4个粒级,而粒级<125μM的224rA、226rA解吸量远大于上述5个粒级;胶州湾沉积物中224rA和226rA的平均扩散通量分别为0.85 bQ·M–2·d–1和0.022 bQ·M–2·d–1。Radium diffusion from sediments to overlying water is one of the important sources of radium isotopes in ocean water.A series of laboratory desorption/diffusion experiments were conducted to help elucidate the characteristics of sediments on 224 Ra and 226 Ra desorption and diffusion,which included 1) 224 Ra and 226 Ra desorption from sediments in water of different salinities,2) 224 Ra and 226 Ra desorption from sediments of different grain sizes in water of the same salinity,3) 224 Ra and 226 Ra diffusive fluxes by observing Ra enrichment with time in the overlying water of incubated sediments.The experimental results show that there is an increase in the amount of 224 Ra and 226 Ra with the increase of salinity from 5 to 30,and Ra desorption is strongest at the salinity of 25.Under the same salt water condition,224 Ra and 226 Ra desorption activities of the four grain sizes(2000~1000 μm,1000~500 μm,500~250 μm and 250~125 μm) of sediments are very close to each other.When the grain sizes of sediments are larger than 2000μm,the 224 Ra and 226 Ra desorption activities are slightly higher than those of the sediments of the above-mentioned four grain sizes.When the grain sizes of sediments are less than 125 μm,the 224 Ra and 226 Ra desorption activities are much larger than those of the above-mentioned five grain sizes.The average diffusive fluxes of 224 Ra and 226 Ra of sediments from Jiaozhou Bay are 0.85 Bq·m-2·d-1 and 0.022 Bq·m-2·d-1,respectively.国家自然科学基金项目(编号:41072174)资

The Evaluation of Submarine Groundwater Discharge in Jiaozhou Bay Based on ~(222)Rn Mass Balance

海底地下水排泄(Sgd)作为全球水循环的一个组成部分,近年来成为陆海相互作用的研究热点。地球化学示踪法是研究海底地下水排泄的主要手段。本文以环境同位素222rn作为示踪剂,通过构建222rn质量平衡模型来评价胶州湾的海底地下水排泄,并进一步估算地下水输入的营养盐。222rn质量平衡模型的源项考虑了河流的输入、沉积物的扩散、母体226rA的支持,汇项考虑了222rn的自身衰变、222rn散逸到大气的损失以及与湾外海水的混合损失,源汇项的差值则作为地下水输入的222rn通量。结果表明,2011年9—10月胶州湾海底地下水排泄通量为24.2 l？M–2？d–1,2012年4—5月胶州湾海底地下水排泄通量为7.8 l？M–2？d–1。丰水季节地下水输入胶州湾的营养盐低于河流输入的,但是枯水季节地下水输入的营养盐接近河流输入的,特别是输入的活性磷酸盐和硅酸盐很接近。Submarine groundwater discharge(SGD), an important part of global water cycle, has recently been a research focus in the field of land-ocean interaction along the coastal zone.Geochemical tracing is a major tool to study submarine groundwater discharge.Taking natural occurring isotope 222 Rn as a tracer, the authors built 222 Rn mass balance model to estimate groundwater discharge to Jiaozhou Bay, and also evaluated the nutrient fluxes transported via groundwater.River input, dispersion of sediments, and support from parent 226 Ra are considered to be the sources of 222 Rn mass balance model, whereas radioactive decay, escape from sea-water interface to air and loss in mixing with the low activity water from open ocean are considered to be the sink of the model.Thus, the imbalance of budget from the model is attributed to submarine groundwater discharge.Calculations show that submarine groundwater discharge flux to Jiaozhou Bay was 24.2 L·m–2·d–1 from September to October in 2011, and 7.8 L·m–2·d–1 from April to May in 2014, respectively.The results of the study also indicate that the nutrient fluxes derived from groundwater during the wet season are lower than those transported by the local rivers, whereas the nutrient fluxes derived from groundwater during the dry season are close to those transported by the local rivers and, what is more, soluble reactive phosphate and silicate fluxes from both groundwater and river are very close to each other.国家自然科学基金项目(编号:41072174)资