397 research outputs found
Novel Fluorescent Probe Based on Anthryl Dendron Having Oligo(ethyleneoxide) Groups at the Terminals
Amphiphilic anthryl dendrons 5 and 6, which have carboxylate groups or oligo(ethyleneoxide) groups at the terminals, show solvatochromic properties. Reaction efficiency of photodimerization and dynamic light scattering (DLS) experiment of 5 and 6 reveal that formation of the aggregate of dendrons 5 or 6 plays a crucial role in this solvatochromism. Interestingly, solvatochromic property of anthryl dendron 6 was useful for determination of the ratio of methanol/water in solution as a fluorescent probe
Coverage centralities for temporal networks
Structure of real networked systems, such as social relationship, can be
modeled as temporal networks in which each edge appears only at the prescribed
time. Understanding the structure of temporal networks requires quantifying the
importance of a temporal vertex, which is a pair of vertex index and time. In
this paper, we define two centrality measures of a temporal vertex based on the
fastest temporal paths which use the temporal vertex. The definition is free
from parameters and robust against the change in time scale on which we focus.
In addition, we can efficiently compute these centrality values for all
temporal vertices. Using the two centrality measures, we reveal that
distributions of these centrality values of real-world temporal networks are
heterogeneous. For various datasets, we also demonstrate that a majority of the
highly central temporal vertices are located within a narrow time window around
a particular time. In other words, there is a bottleneck time at which most
information sent in the temporal network passes through a small number of
temporal vertices, which suggests an important role of these temporal vertices
in spreading phenomena.Comment: 13 pages, 10 figure
Community detection in directed acyclic graphs
Some temporal networks, most notably citation networks, are naturally
represented as directed acyclic graphs (DAGs). To detect communities in DAGs,
we propose a modularity for DAGs by defining an appropriate null model (i.e.,
randomized network) respecting the order of nodes. We implement a spectral
method to approximately maximize the proposed modularity measure and test the
method on citation networks and other DAGs. We find that the attained values of
the modularity for DAGs are similar for partitions that we obtain by maximizing
the proposed modularity (designed for DAGs), the modularity for undirected
networks and that for general directed networks. In other words, if we neglect
the order imposed on nodes (and the direction of links) in a given DAG and
maximize the conventional modularity measure, the obtained partition is close
to the optimal one in the sense of the modularity for DAGs.Comment: 2 figures, 7 table
Formation of Zwitterionic Fullerodendron Using a New DBN-Focal Dendron
A new poly(amidoamine) dendron having 1,5-diazabicyclo[4.3.0]non-5-ene (DBN) at the focal point was synthesized. Interestingly, formation of zwitterionic fullerodendrons (λmax = 930 nm for C60 and 795 nm for C70) were observed by Vis-NIR spectroscopy upon the reaction of C60 or C70 with the DBN-focal dendron. In particular, the C70 anion was effectively stabilized by the site isolation effect of the dendritic wedge. The half-life of fullerodendron 12b having C70 anion at the focal point reaches 7,345 min, which is 20 times longer than that of complex between C60 and pristine DBN. Furthermore, in order to confirm the structure of the zwitterionic complex, fullerodendron 12a was reprecipitated from benzonitrile/1,2,4-trimethylbenzene, and was observed using IR spectroscopy and APPI-MS
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