Uniaxial pressure dependencies of the phase boundary of TlCuCl_3

We present a thermal expansion and magnetostriction study of TlCuCl_3, which shows a magnetic-field induced transition from a spin gap phase to a Neel ordered phase. Using Ehrenfest relations we derive huge and strongly anisotropic uniaxial pressure dependencies of the respective phase boundary, e.g. the transition field changes by about $\pm 185$ GPa depending on the direction of uniaxial pressure.Comment: 2 pages, e figures; presented at SCES200

Pressure-Induced Magnetic Quantum Phase Transitions from Gapped Ground State in TlCuCl3

Magnetization maesurements under hydrostatic pressure were performed on an S=1/2 coupled spin system TlCuCl3 with a gapped ground state under magnetic field H parallel to the [2,0,1] direction. With increasing applied pressure P, the gap decreases and closes completely at Pc=0.42 kbar. For P>Pc, TlCuCl3 undergoes antiferromagnetic ordering. A spin-flop transition was observed at Hsf=0.7T. The spin-flop field is approximately independent of pressure, although the sublattice magnetization increases with pressure. The gap and Neel temperature are presented as function is attributed to to the relative enhancement of the interdimer exchange interactions compared with the intradimer exchange interaction.Comment: 4pages,3figures To be published in J. Phys. Soc. Jpn. Vol.73 No.1

Drastic Change of Magnetic Phase Diagram in Doped Quantum Antiferromagnet TlCu1−x_{1-x}Mgx_xCl3_3

TlCuCl$_3$ is a coupled spin dimer system, which has a singlet ground state with an excitation gap of $\Delta/g\mu_{\mathrm B}$ = 5.5 T. TlCu$_{1-x}$Mg$_x$Cl$_3$ doped with nonmagnetic Mg$^{2+}$ ions undergoes impurity-induced magnetic ordering. Because triplet excitation with a finite gap still remains, this doped system can also undergo magnetic-field-induced magnetic ordering. By specific heat measurements and neutron scattering experiments under a magnetic field, we investigated the phase diagram in TlCu$_{1-x}$Mg$_x$Cl$_3$ with $x\sim 0.01$, and found that impurity- and field-induced ordered phases are the same. The gapped spin liquid state observed in pure TlCuCl$_3$ is completely wiped out by the small amount of doping.Comment: 9 pages, 5 figures, jpsj2 class file, to be published in J. Phy. Soc. Jpn. Vol.75 No.3 (2006); layout changed, unrelated figure remove

Renormalized charge in a two-dimensional model of colloidal suspension from hypernetted chain approach

The renormalized charge of a simple two-dimensional model of colloidal suspension was determined by solving the hypernetted chain approximation and Ornstein-Zernike equations. At the infinite dilution limit, the asymptotic behavior of the correlations functions is used to define the effective interactions between the components of the system and these effective interactions were compared to those derived from the Poisson-Boltzmann theory. The results we obtained show that, in contrast to the mean-field theory, the renormalized charge does not saturate, but exhibits a maximum value and then decays monotonically as the bare charge increases. The results also suggest that beyond the counterion layer near to the macroion surface, the ionic cloud is not a diffuse layer which can be handled by means of the linearized theory, as the two-state model claims, but a more complex structure is settled by the correlations between microions

Finite-Width Bundle is Most Stable in a Solution with Salt

We applied the mean-field approach to a columnar bundle assembled by the parallel arrangement of stiff polyelectrolyte rods in a salt bath. The electrostatic potential can be divided into two regions: inside the bundle for condensed counter-ions, and outside the bundle for free small ions. To determine the distribution of condensed counter-ions inside the bundle, we use a local self-consistent condition that depends on the charge density, the electrostatic potential, and the net polarization. The results showed that, upon bundle formation, the electric charge of polyelectrolytes, even those inside the bundle, tend to survive in an inhomogeneous manner, and thus their width remains finite under thermal equilibrium because of the long-range effect of charge instability.Comment: 7 pages, 4 figure

Magentic-Field Induced Quantum Phase Transition and Critical Behavior in a Gapped Spin System TlCuCl3_3

Magnetization measurements were performed on TlCuCl$_3$ with gapped ground state. The critical density and the magnetic phase diagram were obtained. The interacting constant was obtained as $U/k_{\rm B} = 313$ K. The experimental phase boundary for $T < 5$ K agrees perfectly with the magnon BEC theory based on the Hartree-Fock approximation with realistic dispersion relations and $U/k_{\rm B} = 320$ K. The exponent $\phi$ obtained with all the data points for $T < 5$ K is $\phi = 1.99$, which is somewhat larger than theoretical exponent $\phi_{\rm BEC} =3/2$. However, it was found that the exponent converges at $\phi_{\rm BEC} =3/2$ with decreasing fitting window.Comment: 2 pages, 2 figures, Submitted to Proceedings of International Conference on Magnetism (ICM2006

Cloning of the C-terminal cytoplasmic fragment of the tar protein and effects of the fragment on chemotaxis of Escherichia coli

A gene encoding only the C-terminal portion of the receptor-transducer protein Tar of Escherichia coli was constructed. The gene product was detected and localized in the cytoplasmic fraction of the cell by immunoblotting with anti-Tar antibodies. The C-terminal fragments from wild-type and mutant tar genes were characterized in vivo. The C-terminal fragment generated from tar-526, a mutation that results in a dominant "tumble" phenotype, was found to be deamidated and methylated by the CheB and CheR proteins, respectively. The C-terminal fragment derived from a wild-type gene was poorly deamidated, and the C-terminal fragment derived from tar-529, a dominant mutant with a "smooth swimming" phenotype, was not apparently modified. Cells carrying the C-terminal fragment with the tar-526 mutation as the sole receptor-transducer protein showed a high frequency of tumbling and chemotaxis responses to changes in intracellular pH. These results suggest that the cytoplasmic C-terminal fragment of Tar retains some of the functions of the whole protein in vivo

Thermodynamics of the coupled spin-dimer system TlCuCl3 close to a quantum phase transition

We present thermal expansion alpha, magnetostriction and specific heat C measurements of \tal, which shows a quantum phase transition from a spin-gap phase to a Neel-ordered ground state as a function of magnetic field around H_{C0}->4.8T. Using Ehrenfest's relation, we find huge pressure dependencies of the spin gap for uniaxial as well as for hydrostatic pressure. For T->0 and H->H_{C0} we observe a diverging Grueneisen parameter Gamma(T)=alpha/C, in qualitative agreement with theoretical predictions. However, the predicted individual temperature dependencies alpha(T) and C(T) are not reproduced by our experimental data.Comment: 6 pages including 7 figures, contribution to the III Joint European Magnetic Symposia 2006, San Sebastia