Structural and dynamical heterogeneities in two-dimensional melting

Using molecular dynamics simulation, we study structural and dynamical heterogeneities at melting in two-dimensional one-component systems with 36000 particles. Between crystal and liquid we find intermediate hexatic states, where the density fluctuations are enhanced at small wave number k as well as those of the six-fold orientational order parameter. Their structure factors both grow up to the smallest wave number equal to the inverse system length. The intermediate scattering function of the density S(k,t) is found to relax exponentially with decay rate Gamma_k ~ k^z with z~2.6 at small k in the hexatic phase.Comment: 6 pages, 8 figure

Belle time-dependent gamma measurements

The Belle experiment has measured the CKM angle $\gamma$ in a variety of ways. In this paper, we focused on the recent progress of time-dependent $\gamma$ analysis and the related measurements in Belle.Comment: 6th International Workshop on the CKM Unitary Triangle, University of Warwick UK, 6-10 September 201

Quantifying Nonequilibrium Behavior with Varying Cooling Rates

We investigate nonequilibrium behavior in (1+1)-dimensional stochastic field theories in the context of Ginzburg-Landau models at varying cooling rates. We argue that a reliable measure of the departure from thermal equilibrium can be obtained from the absolute value of the rate of change of the momentum-integrated structure function, $\Delta S_{\rm{tot}}$. We show that the peak of $\Delta S_{\rm{tot}}$ scales with the cooling, or quench, time-scale, $\tau_q$, in agreement with the prediction by Laguna and Zurek for the scaling of freeze-out time in both over and under-damped regimes. Furthermore, we show that the amplitude of the peak scales as $\tau_q^{-6/5}$ independent of the viscosity.Comment: 4 pages, 4 figures, submitted to Phys. Rev. Let

Spatio-temporal structures in sheared polymer systems

We investigate spatio-temporal structures in sheared polymer systems by solving a time-dependent Ginzburg-Landau model in two dimensions. (i) In polymer solutions above the coexistence curve, crossover from linear to nonlinear regimes occurs with increasing the shear rate. In the nonlinear regime the solution behaves chaotically with large-amplitude composition fluctuations. A characteristic heterogeneity length is calculated in the nonlinear regime. (ii) We also study dynamics of shear-band structures in wormlike micellar solutions under the condition of fixed stress. The average shear rate exhibits large temporal fluctuations with occurrence of large disturbances in the spatial structures.Comment: 16pages, 10figures, to be published in Physica

Spreading with evaporation and condensation in one-component fluids

We investigate the dynamics of spreading of a small liquid droplet in gas in a one-component simple fluid, where the temperature is inhomogeneous around 0.9Tc and latent heat is released or generated at the interface upon evaporation or condensation (with Tc being the critical temperature). In the scheme of the dynamic van der Waals theory, the hydrodynamic equations containing the gradient stress are solved in the axisymmetric geometry. We assume that the substrate has a finite thickness and its temperature obeys the thermal diffusion equation. A precursor film then spreads ahead of the bulk droplet itself in the complete wetting condition. Cooling the substrate enhances condensation of gas onto the advancing film, which mostly takes place near the film edge and can be the dominant mechanism of the film growth in a late stage. The generated latent heat produces a temperature peak or a hot spot in the gas region near the film edge. On the other hand, heating the substrate induces evaporation all over the interface. For weak heating, a steady-state circular thin film can be formed on the substrate. For stronger heating, evaporation dominates over condensation, leading to eventual disappearance of the liquid region.Comment: 12 pages, 14 figure

Solvation Effects in Near-Critical Binary Mixtures

A Ginzburg-Landau theory is presented to investigate solvation effects in near-critical polar fluid binary mixtures. Concentration-dependence of the dielectric constant gives rise to a shell region around a charged particle within which solvation occurs preferentially. As the critical point is approached, the concentration has a long-range Ornstein-Zernike tail representing strong critical electrostriction. If salt is added, strong coupling arises among the critical fluctuations and the ions. The structure factors of the critical fluctuations and the charge density are calculated and the phase transition behavior is discussed.Comment: 12 pages, 8 figures, to be published in J. Chem. Phy

Plastic flow in polycrystal states in a binary mixture

Using molecular dynamics simulation we examine dynamics in sheared polycrystal states in a binary mixture containing 10% larger particles in two dimensions. We find large stress fluctuations arising from sliding motions of the particles at the grain boundaries, which occur cooperatively to release the elastic energy stored. These dynamic processes are visualized with the aid of a sixfold angle $\alpha_j(t)$ representing the local crystal orientation and a disorder variable $D_j(t)$ representing a deviation from the hexagonal order for particle $j$.Comment: 3 pages, 3 figure

Rheology of a Supercooled Polymer Melt

Molecular dynamics simulations are performed for a polymer melt composed of short chains in quiescent and sheared conditions. The stress relaxation function $G(t)$ exhibits a stretched exponential form in a relatively early stage and ultimately follows the Rouse function in quiescent supercooled state. Transient stress evolution after application of shear obeys the linear growth $\int_0^t dt'G(t')$ for strain less than 0.1 and then saturates into a non-Newtonian viscosity. In steady states, strong shear-thinning and elongation of chains into ellipsoidal shapes are found at extremely small shear. A glassy component of the stress is much enhanced in these examples.Comment: 4 pages, 5 figure