Disorder effects on the superconducting properties of BaFe1.8_{1.8}Co0.2_{0.2}As2_2 single crystals

Single crystals of superconducting BaFe$_{1.8}$Co$_{0.2}$As$_2$ were exposed to neutron irradiation in a fission reactor. The introduced defects decrease the superconducting transition temperature (by about 0.3 K) and the upper critical field anisotropy (e.g. from 2.8 to 2.5 at 22 K) and enhance the critical current densities by a factor of up to about 3. These changes are discussed in the context of similar experiments on other superconducting materials

Disorder Induced Effects on the Critical Current Density of Iron Pnictide BaFe_1.8 Co_0.2 As_2 single crystals

Investigating the role of disorder in superconductors is an essential part of characterizing the fundamental superconducting properties as well as assessing potential applications of the material. In most cases, the information available on the defect matrix is poor, making such studies difficult, but the situation can be improved by introducing defects in a controlled way, as provided by neutron irradiation. In this work, we analyze the effects of neutron irradiation on a Ba(Fe$_{1-x}$Co$_x$)$_2$As$_2$ single crystal. We mainly concentrate on the magnetic properties which were determined by magnetometry. Introducing disorder by neutron irradiation leads to significant effects on both the reversible and the irreversible magnetic properties, such as the transition temperature, the upper critical field, the anisotropy, and the critical current density. The results are discussed in detail by comparing them with the properties in the unirradiated state.Comment: accepted for Ph

Local Measurement of Current Density by Magneto-Optical Current Reconstruction in Normally and Overpressure Processed Bi-2223 Tapes

Magneto-optical current reconstruction has been used for detailed analysis of the local critical current density (Jc) variation in monocore Bi-2223 tapes. We find, even in high quality tapes with bulk transport Jc ~ 40 kA/cm^2 (77K, 0T), that there exist local regions which possess current densities of more than 200 kA/cm^2. Overpressure processing at 148 bar significantly improved Jc to 48 kA/cm^2 by improving the connectivity. For the overpressure-processed sample we find that the current distribution is more uniform and that the maximum local current density at 77 K is increased almost to 300 kA/cm^2.Comment: Presented at Applied Superconductivity Conference, Houston, August 4th -9th, 200

Jabuticaba (Myrciaria jaboticaba) peel as a sustainable source of anthocyanins and ellagitannins delivered by phospholipid vesicles for alleviating oxidative stress in human keratinocytes

The Brazilian berry scientifically known as jabuticaba is a fruit covered by a dark purple peel that is still rich in bioactives, especially polyphenols. Considering that, this work was aimed at obtaining an extract from the peel of jabuticaba fruits, identifying its main components, loading it in phospholipid vesicles specifically tailored for skin delivery and evaluating their biological efficacy. The extract was obtained by pressurized hot water extraction (PHWE), which is considered an easy and low dissipative method, and it was rich in polyphenolic compounds, especially flavonoids (ortho-diphenols and condensed tannins), anthocyanins (cyanidin 3-O-glucoside and delphinidin 3-O-glucoside) and gallic acid, which were responsible for the high antioxidant activity detected using different colorimetric methods (DPPH, FRAP, CUPRAC and metal chelation). To improve the stability and extract effectiveness, it was incorporated into ultradeformable phospholipid vesicles (transfersomes) that were modified by adding two different polymers (hydroxyethyl cellulose and sodium hyaluronate), thus obtaining HEcellulose-transfersomes and hyaluronan-transfersomes. Transfersomes without polymers were the smallest, as the addition of the polymer led to the formation of larger vesicles that were more stable in storage. The incorporation of the extract in the vesicles promoted their beneficial activities as they were capable, to a greater extent than the solution used as reference, of counteracting the toxic effect of hydrogen peroxide and even of speeding up the healing of a wound performed in a cell monolayer, especially when vesicles were enriched with polymers. Given that, polymer enriched vesicles may represent a good strategy to produce cosmetical and cosmeceutical products with beneficial properties for skin

Investigation of Optimal Approaches to Assessing the Megacity Innovative Potential

The authors of the article set a goal to identify the most accurate and economical methods for assessing the innovative potential of megacity in terms of the used resources. For that purpose, methods were selected, calculations were carried out for two of them, which were suitable for the goal and described in detail in the methodological literature. The results of two other methods presented in the public domain for comparable periods of time for three selected regions were used. The study used materials from Russian and foreign sources. Based on the results of the work done, certain conclusions were made that allow a more accurate selection of methods for assessing the innovative potential of cities, considering the objectives of such an assessment, as well as the resource availability of a group of researchers. A critical view is also presented on the further application of all methods, which requires researchers of the local innovation potential to have the accuracy, objectivity in assessments, and independence in their interpretation

Atmospheric conditions and their effect on ball-milled magnesium diboride

Magnesium diboride bulk pellets were fabricated from pre-reacted MgB2 powder ball milled with different amounts of exposure to air. Evidence of increased electron scattering including increased resistivity, depressed Tc, and enhanced Hc2 of the milled and heat treated samples were observed as a result of increased contact with air. These and other data were consistent with alloying with carbon as a result of exposure to air. A less clear trend of decreased connectivity associated with air exposure was also observed. In making the case that exposure to air should be considered a doping process, these results may explain the wide varibability of "undoped" MgB2 properties extant in the literature.Comment: Work presented at ASC 2006 in Seattl