8 research outputs found
A genetic modifier screen identifies chromosomal intervals harboring potential midline interacting genes
This work investigates the growth of B-C-N layers by chemical vapor
deposition using methylamine borane (MeAB) as single-source precursor. MeAB has
been synthesized and characterized, paying particular attention to the analysis
of its thermolysis products, which are the gaseous precursors for B-C-N growth.
Samples have been grown on Cu foils and transferred onto different substrates
for their morphological, structural, chemical, electronic and optical
characterizations. The results of these characterizations indicate a
segregation of h-BN and Graphene-like (Gr) domains. However, there is an
important presence of B and N interactions with C at the Gr borders, and of C
interacting at the h-BN-edges, respectively, in the obtained nano-layers. In
particular, there is significant presence of C-N bonds, at Gr/h-BN borders and
in the form of N doping of Gr domains. The overall B:C:N contents in the layers
is close to 1:3:1.5. A careful analysis of the optical bandgap determination of
the obtained B-C-N layers is presented, discussed and compared with previous
seminal works with samples of similar composition.Comment: 35 pages, 7 figure
Direct visualization and effects of atomic-scale defects on the optoelectronic properties of hexagonal boron nitride
This is the peer reviewed version of the following article: Advanced Electronic Materials 7.7 (2021): 2001177 which has been published in final form at https://doi.org/10.1002/aelm.202001177. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Version
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Dynamically tuned non-classical light emission from atomic defects in hexagonal boron nitride
Luminescent defects in hexagonal boron nitride (h-BN) have recently emerged as a promising platform for non-classical light emission. On-chip solutions, however, require techniques for controllable in-situ manipulation of quantum light. Here, we demonstrate the dynamic spectral and temporal tuning of the optical emission from h-BN via moving acousto-mechanical modulation induced by stimulated phonons. When perturbed by the propagating acoustic phonon, the optically probed radiative h-BN defects are periodically strained and their sharp emission lines are modulated by the deformation potential coupling. This results in an acoustically driven spectral tuning within a 2.5-meV bandwidth. Our findings, supported by first-principles theoretical calculations, reveal exceptionally high elasto-optic coupling in h-BN of ~50 meV/%. Temporal control of the emitted photons is achieved by combining the acoustically mediated fine-spectral tuning with spectral detection filtering. This study opens the door to the use of sound for scalable integration of h-BN emitters in nanophotonic and quantum information technologies. © 2019, The Author(s)
Dynamically tuned non-classical light emission from atomic defects in hexagonal boron nitride
Luminescent defects in hexagonal boron nitride (h-BN) have recently emerged as a promising platform for non-classical light emission. On-chip solutions, however, require techniques for controllable in-situ manipulation of quantum light. Here, we demonstrate the dynamic spectral and temporal tuning of the optical emission from h-BN via moving acousto-mechanical modulation induced by stimulated phonons. When perturbed by the propagating acoustic phonon, the optically probed radiative h-BN defects are periodically strained and their sharp emission lines are modulated by the deformation potential coupling. This results in an acoustically driven spectral tuning within a 2.5-meV bandwidth. Our findings, supported by first-principles theoretical calculations, reveal exceptionally high elasto-optic coupling in h-BN of ~50 meV/%. Temporal control of the emitted photons is achieved by combining the acoustically mediated fine-spectral tuning with spectral detection filtering. This study opens the door to the use of sound for scalable integration of h-BN emitters in nanophotonic and quantum information technologiesThis work was supported in part by the collaborative project “Single-Photon Generation in 2D Crystals for Quantum Information” (MDM-2014-0377) funded by the Condensed Matter Physics Center (IFIMAC) as well as by the Spanish MINECO under contracts MAT2014-53119-C2-1-R, MAT2016-77608-C3-1-P and MAT2017-83722-R. S.L. is a recipient of the Ramón and Cajal Research Grant (RyC-2011-09528) funded by the Spanish MINECO. J.J.P.B. acknowledges financial support from Spanish MINECO through Grant FIS2016-80434-P, the Fundación Ramón Areces, the Comunidad Autónoma de Madrid through MAD2D-CM Program (S2013/MIT-3007) and the European Union Seventh Framework Programme under Grant agreement No. 604391 Graphene Flagship. W.S.P. was funded by the CNPq Fellowship programme (Pós-doutorado júnior) under grant 405107/2017-0 and acknowledges the computer resources at FinisTerrae2 and the technical support provided by Barcelona Supercomputing Center (RES-FI-2018-2-0036). We thank Eduardo J.H. Lee (UAM) for his help in sample preparatio