22,308 research outputs found
On the parameterization of all admissible pairs in a class of CCF-ILC algorithms
This paper extends some recent results on the parameterization of all admissible pairs in a class of 2-parameter current-cycle-feedback ILC algorithms. In addition, a necessary and sufficient condition is given under which the associated set of equivalent controllers coincides with the set of all stabilizing controller
Rate and Mechanism of the Oxidative Addition of Benzoic Anhydride to Palladium(0) Complexes in DMF
The rate constant of the oxidative addition of the benzoic anhydride (PhCO)2O to [Pd0(PPh3)4] has been determined in DMF and compared to that of phenyl halides and phenyl triflate. The following reactivity order has been established: PhI >> (PhCO)2O > PhOTf > PhBr. The oxidative addition of (PhCO)2O proceeds by activation of one CâO bond. Two acyl-PdII complexes are formed: a neutral complex trans-[(PhCO)Pd(OCOPh)(PPh3)2] and a cationic complex trans-[(PhCO)PdS(PPh3)2]+ (S = DMF) showing that the decarbonylation process is highly endergonic. The exchange of PPh3 by the bidentate ligand dppp does not favor the decarbonylation process.
Massive galaxies with very young AGN
Gigahertz Peaked Spectrum (GPS) radio galaxies are generally thought to be
the young counterparts of classical extended radio sources and live in massive
ellipticals. GPS sources are vital for studying the early evolution of
radio-loud AGN, the trigger of their nuclear activity, and the importance of
feedback in galaxy evolution. We study the Parkes half-Jansky sample of GPS
radio galaxies of which now all host galaxies have been identified and 80% has
their redshifts determined (0.122 < z < 1.539). Analysis of the absolute
magnitudes of the GPS host galaxies show that at z > 1 they are on average a
magnitude fainter than classical 3C radio galaxies. This suggests that the AGN
in young radio galaxies have not yet much influenced the overall properties of
the host galaxy. However their restframe UV luminosities indicate that there is
a low level of excess as compared to passive evolution models.Comment: To appear in the proceedings of "Formation and Evolution of Galaxy
Bulges", IAUS 245; M. Bureau, E. Athanassoula & B. Barbuy, ed
Influence of Phosphoramidites in Copper-Catalyzed Conjugate Borylation Reaction
Copper(I) has become the preferred metal to catalyze the ÎČ-boration of α,ÎČ-unsaturated carbonyl compounds, and now we demonstrate that easily accessible monodentate chiral ligands, such as phosphoramidites and phosphites, can be convenient alternative ligands to induce asymmetry in the enantioselective version of this reaction, particularly in the ÎČ-boration of α,ÎČ-unsaturated imines.
Monte Carlo calculations of energy depositions and radiation transport. Volume 1 - Validation of COHORT codes
Monte Carlo codes for IBM 7090 digital computer to calculate radiation heating in propellant tanks, and radiation environment about nuclear rocket stag
Veranderingsprocessen in ziekenhuizen : de contouren van een antwoord op een complexe problematiek
In de twee voorgaande boeken van dezelfde redactie, die als ondertitel hadden
âbedrijfskundig instrumentarium voor de ziekenhuismanagerâ, worden zowel de
bedrijfskundige instrumenten als de (feitelijke en mogelijke) toepassingen daar
van beschreven, toegespitst op instellingen voor gezondheidszorg c.q. ziekenhui
zen. Het gaat om instrumenten, gericht op de sturing van (zorg)processen en
structurering van de (zorg)organisatie. Kenmerkende themaâs zijn onder andere
(opname- en operatie)planning, werklastmeting, procesbeheersing, rooster
afstemming, coördinatie, kwaliteit, informatievoorziening, prestatiesturing, unitmanagement
en divisiestructuren.
Het bedrijfskundig instrumentarium en de genoemde themaâs zijn in ziekenhuizen
niet aan de orde als doel op zich. De verwachting is dat er hoe dan ook een bij
drage wordt geleverd aan een beter functionerende organisatie. âBeter functione
renâ is op zichzelf een loze kreet; bet gaat om doelstellingen en de mate waarin
doelstellingen worden gerealiseerd. Dit hoofdstuk gaat expliciet in op de samen
hang tussen bedrijfskundig instrumentarium en organisaties in verandering. Daar
naast wordt getracht een kader te geven voor de veranderkundige elementen uit de
overige bijdragen in dit boek
Modeling and prediction of surgical procedure times
Accurate prediction of medical operation times is of crucial importance for cost efficient operation room planning in hospitals. This paper investigates the possible dependence of procedure times on surgeon factors like age, experience, gender, and team composition. The effect of these factors is estimated for over 30 different types of medical operations in two hospitals, by means of ANOVA models for logarithmic case durations. The estimation data set contains about 30,000 observations from 2005 till 2008. The relevance of surgeon factors depends on the type of operation. The factors found most often to be significant are team composition, experience, and daytime. Contrary to widespread opinions among surgeons, gender has nearly never a significant effect. By incorporating surgeon factors, the accuracy of out-of-sample prediction of case durations of about 1,250 surgical operations in 2009 is improved by up to more than 15 percent as compared to current planning procedures.planning;ANOVA model;European hospital;current procedure terminology (CPT);health care management;lognormal distribution;operation room;surgeon factors
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