Low work function of the (1000) Ca2N surface

Polymer diodes require cathodes that do not corrode the polymer but do have low work function to minimize the electron injection barrier. First-principles calculations demonstrate that the work function of the (1000) surface of the compound Ca2N is half an eV lower than that of the elemental metal Ca (2.35 vs. 2.87 eV). Moreover its reactivity is expected to be smaller. This makes Ca2N an interesting candidate to replace calcium as cathode material for polymer light emitting diode devices.Comment: 3 pages, 4 figures, accepted by J. Appl. Phy

Liquid-vapor oscillations of water in hydrophobic nanopores

Water plays a key role in biological membrane transport. In ion channels and water-conducting pores (aquaporins), one dimensional confinement in conjunction with strong surface effects changes the physical behavior of water. In molecular dynamics simulations of water in short (0.8 nm) hydrophobic pores the water density in the pore fluctuates on a nanosecond time scale. In long simulations (460 ns in total) at pore radii ranging from 0.35 nm to 1.0 nm we quantify the kinetics of oscillations between a liquid-filled and a vapor-filled pore. This behavior can be explained as capillary evaporation alternating with capillary condensation, driven by pressure fluctuations in the water outside the pore. The free energy difference between the two states depends linearly on the radius. The free energy landscape shows how a metastable liquid state gradually develops with increasing radius. For radii larger than ca. 0.55 nm it becomes the globally stable state and the vapor state vanishes. One dimensional confinement affects the dynamic behavior of the water molecules and increases the self diffusion by a factor of two to three compared to bulk water. Permeabilities for the narrow pores are of the same order of magnitude as for biological water pores. Water flow is not continuous but occurs in bursts. Our results suggest that simulations aimed at collective phenomena such as hydrophobic effects may require simulation times longer than 50 ns. For water in confined geometries, it is not possible to extrapolate from bulk or short time behavior to longer time scales.Comment: 20 pages, 4 figures, 3 tables; to be published in Proc. Natl. Acad. Sci. US

Polarity patterns of stress fibers

Stress fibers are contractile actomyosin bundles commonly observed in the cytoskeleton of metazoan cells. The spatial profile of the polarity of actin filaments inside contractile actomyosin bundles is either monotonic (graded) or periodic (alternating). In the framework of linear irreversible thermodynamics, we write the constitutive equations for a polar, active, elastic one-dimensional medium. An analysis of the resulting equations for the dynamics of polarity shows that the transition from graded to alternating polarity patterns is a nonequilibrium Lifshitz point. Active contractility is a necessary condition for the emergence of sarcomeric, alternating polarity patterns.Comment: 5 pages, 3 figure

Depletion isolation effect in Vertical MOSFETS during transition from partial to fully depleted operation

A simulation study is made of floating-body effects (FBEs) in vertical MOSFETs due to depletion isolation as the pillar thickness is reduced from 200 to 10 nm. For pillar thicknesses between 200–60 nm, the output characteristics with and without impact ionization are identical at a low drain bias and then diverge at a high drain bias. The critical drain bias Vdc for which the increased drain–current is observed is found to decrease with a reduction in pillar thickness. This is explained by the onset of FBEs at progressively lower values of the drain bias due to the merging of the drain depletion regions at the bottom of the pillar (depletion isolation). For pillar thicknesses between 60–10 nm, the output characteristics show the opposite behavior, namely, the critical drain bias increases with a reduction in pillar thickness. This is explained by a reduction in the severity of the FBEs due to the drain debiasing effect caused by the elevated body potential. Both depletion isolation and gate–gate coupling contribute to the drain–current for pillar thicknesses between 100–40 nm

Men Are from Mars, Women Are from Venus: Evaluation and Modelling of Verbal Associations

We present a quantitative analysis of human word association pairs and study the types of relations presented in the associations. We put our main focus on the correlation between response types and respondent characteristics such as occupation and gender by contrasting syntagmatic and paradigmatic associations. Finally, we propose a personalised distributed word association model and show the importance of incorporating demographic factors into the models commonly used in natural language processing.Comment: AIST 2017 camera-read

Observation of two-orbital spin-exchange interactions with ultracold SU(N)-symmetric fermions

We report on the direct observation of spin-exchanging interactions in a two-orbital SU(N)-symmetric quantum gas of ytterbium in an optical lattice. The two orbital states are represented by two different (meta-)stable electronic configurations of fermionic Yb-173. A strong spin-exchange between particles in the two separate orbitals is mediated by the contact interaction between atoms, which we characterize by clock shift spectroscopy in a 3D optical lattice. We find the system to be SU(N)-symmetric within our measurement precision and characterize all relevant scattering channels for atom pairs in combinations of the ground and the excited state. Elastic scattering between the orbitals is dominated by the antisymmetric channel, which leads to the strong spin-exchange coupling. The exchange process is directly observed, by characterizing the dynamic equilibration of spin imbalances between two large ensembles in the two orbital states, as well as indirectly in atom pairs via interaction shift spectroscopy in a 3D lattice. The realization of a stable SU(N)-symmetric two-orbital Hubbard Hamiltonian opens the route towards experimental quantum simulation of condensed-matter models based on orbital interactions, such as the Kondo lattice model.Comment: Correction: In the original version of this preprint the assignment of states with symmetric electronic wavefunction (|eg+>) and with antisymmetric electronic wavefunction (|eg->) to the observed spectral lines was inverted. This has been corrected in the current version. The results of the paper remain unchanged, with the exchange coupling being inverted to a ferromagnetic exchang

Entropy-based characterizations of the observable-dependence of the fluctuation-dissipation temperature

The definition of a nonequilibrium temperature through generalized fluctuation-dissipation relations relies on the independence of the fluctuation-dissipation temperature from the observable considered. We argue that this observable independence is deeply related to the uniformity of the phase-space probability distribution on the hypersurfaces of constant energy. This property is shown explicitly on three different stochastic models, where observable-dependence of the fluctuation-dissipation temperature arises only when the uniformity of the phase-space distribution is broken. The first model is an energy transport model on a ring, with biased local transfer rules. In the second model, defined on a fully connected geometry, energy is exchanged with two heat baths at different temperatures, breaking the uniformity of the phase-space distribution. Finally, in the last model, the system is connected to a zero temperature reservoir, and preserves the uniformity of the phase-space distribution in the relaxation regime, leading to an observable-independent temperature.Comment: 15 pages, 7 figure

Dissipative hydrodynamics in 2+1 dimension

In 2+1 dimension, we have simulated the hydrodynamic evolution of QGP fluid with dissipation due to shear viscosity. Comparison of evolution of ideal and viscous fluid, both initialised under the same conditions e.g. same equilibration time, energy density and velocity profile, reveal that the dissipative fluid evolves slowly, cooling at a slower rate. Cooling get still slower for higher viscosity. The fluid velocities on the otherhand evolve faster in a dissipative fluid than in an ideal fluid. The transverse expansion is also enhanced in dissipative evolution. For the same decoupling temperature, freeze-out surface for a dissipative fluid is more extended than an ideal fluid. Dissipation produces entropy as a result of which particle production is increased. Particle production is increased due to (i) extension of the freeze-out surface and (ii) change of the equilibrium distribution function to a non-equilibrium one, the last effect being prominent at large transverse momentum. Compared to ideal fluid, transverse momentum distribution of pion production is considerably enhanced. Enhancement is more at high $p_T$ than at low $p_T$. Pion production also increases with viscosity, larger the viscosity, more is the pion production. Dissipation also modifies the elliptic flow. Elliptic flow is reduced in viscous dynamics. Also, contrary to ideal dynamics where elliptic flow continues to increase with transverse momentum, in viscous dynamics, elliptic flow tends to saturate at large transverse momentum. The analysis suggest that initial conditions of the hot, dense matter produced in Au+Au collisions at RHIC, as extracted from ideal fluid analysis can be changed significantly if the QGP fluid is viscous.Comment: 11 pages, 10 figures (revised). In the revised version, calculations are redone with ADS/CFT and perurbative estimate of viscosity. Comments on the unphysical effects like early reheating of the fluid, in 1st order dissipative theories are added. The particle spectra calculations are redone with modified programm