12,903 research outputs found
Theory of Resonant Inelastic X-ray Scattering by Collective Magnetic Excitations
I present a tractable theory for the Resonant Inelastic X-ray Scattering
(RIXS) spectral function of magnons. The low-energy transition operator is
written as a product of local spin operators times fundamental x-ray absorption
spectra. This leads to simple selection rules for the magnetic cross section.
The scattering cross section linear (quadratic) in spin operators is
proportional to the magnetic circular (linear) dichroic absorption. RIXS is a
novel tool to measure magnetic quasi particles (magnons) and the incoherent
spectral weight, as well as multiple magnons up to very high energy losses, in
small samples, thin films and multilayers, complementary to Neutron scattering
Angular dependence of core hole screening in LiCoO2: A DFT+U calculation of the oxygen and cobalt K-edge x-ray absorption spectra
Angular dependent core-hole screening effects have been found in the cobalt
K-edge x-ray absorption spectrum of LiCoO2, using high-resolution data and
parameter-free GGA+U calculations. The Co 1s core-hole on the absorber causes
strong local attraction. The core-hole screening on the nearest neighbours
cobalt induces a 2 eV shift in the density of states with respect to the
on-site 1s-3d transitions, as detected in the Co K pre-edge spectrum. Our DFT+U
calculations reveal that the off-site screening is different in the
out-of-plane direction, where a 3 eV shift is visible in both calculations and
experiment. The detailed analysis of the inclusion of the core-hole potential
and the Hubbard parameter U shows that the core-hole is essential for the
off-site screening, while U improves the description of the angular dependent
screening effects. In the case of oxygen K-edge, both the core-hole potential
and the Hubbard parameter improve the relative positions of the spectral
features
Стан збереження та проблеми охорони культурної спадщини на Путивльщині
In a 2010 paper Aziz, Chergui and colleagues observe fluorescence yield (FY) detected X-ray absorption spectra that are concentration-dependent and show both dips and peaks. In this comment I will show that all observed spectral features are a consequence of the relative ratio of background and edge emission, combined with energy-dependent X-ray emission decay channels
Nitrogen doping of TiO2 photocatalyst forms a second eg state in the Oxygen (1s) NEXAFS pre-edge
Close inspection of the pre-edge in oxygen near-edge x-ray absorption fine
structure spectra of single step, gas phase synthesized titanium oxynitride
photocatalysts with 20 nm particle size reveals an additional eg resonance in
the VB that went unnoticed in previous TiO2 anion doping studies. The relative
spectral weight of this Ti(3d)-O(2p) hybridized state with respect to and
located between the readily established t2g and eg resonances scales
qualitatively with the photocatalytic decomposition power, suggesting that this
extra resonance bears co-responsibility for the photocatalytic performance of
titanium oxynitrides at visible light wavelengths
Observation of two-orbital spin-exchange interactions with ultracold SU(N)-symmetric fermions
We report on the direct observation of spin-exchanging interactions in a
two-orbital SU(N)-symmetric quantum gas of ytterbium in an optical lattice. The
two orbital states are represented by two different (meta-)stable electronic
configurations of fermionic Yb-173. A strong spin-exchange between particles in
the two separate orbitals is mediated by the contact interaction between atoms,
which we characterize by clock shift spectroscopy in a 3D optical lattice. We
find the system to be SU(N)-symmetric within our measurement precision and
characterize all relevant scattering channels for atom pairs in combinations of
the ground and the excited state. Elastic scattering between the orbitals is
dominated by the antisymmetric channel, which leads to the strong spin-exchange
coupling. The exchange process is directly observed, by characterizing the
dynamic equilibration of spin imbalances between two large ensembles in the two
orbital states, as well as indirectly in atom pairs via interaction shift
spectroscopy in a 3D lattice. The realization of a stable SU(N)-symmetric
two-orbital Hubbard Hamiltonian opens the route towards experimental quantum
simulation of condensed-matter models based on orbital interactions, such as
the Kondo lattice model.Comment: Correction: In the original version of this preprint the assignment
of states with symmetric electronic wavefunction (|eg+>) and with
antisymmetric electronic wavefunction (|eg->) to the observed spectral lines
was inverted. This has been corrected in the current version. The results of
the paper remain unchanged, with the exchange coupling being inverted to a
ferromagnetic exchang
Mechanisms of kinetic trapping in self-assembly and phase transformation
In self-assembly processes, kinetic trapping effects often hinder the
formation of thermodynamically stable ordered states. In a model of viral
capsid assembly and in the phase transformation of a lattice gas, we show how
simulations in a self-assembling steady state can be used to identify two
distinct mechanisms of kinetic trapping. We argue that one of these mechanisms
can be adequately captured by kinetic rate equations, while the other involves
a breakdown of theories that rely on cluster size as a reaction coordinate. We
discuss how these observations might be useful in designing and optimising
self-assembly reactions
Investigating the interstellar dust through the Fe K-edge
The chemical and physical properties of interstellar dust in the densest
regions of the Galaxy are still not well understood. X-rays provide a powerful
probe since they can penetrate gas and dust over a wide range of column
densities (up to ). The interaction (scattering and
absorption) with the medium imprints spectral signatures that reflect the
individual atoms which constitute the gas, molecule, or solid. In this work we
investigate the ability of high resolution X-ray spectroscopy to probe the
properties of cosmic grains containing iron. Although iron is heavily depleted
into interstellar dust, the nature of the Fe-bearing grains is still largely
uncertain. In our analysis we use iron K-edge synchrotron data of minerals
likely present in the ISM dust taken at the European Synchrotron Radiation
Facility. We explore the prospects of determining the chemical composition and
the size of astrophysical dust in the Galactic centre and in molecular clouds
with future X-ray missions. The energy resolution and the effective area of the
present X-ray telescopes are not sufficient to detect and study the Fe K-edge,
even for bright X-ray sources. From the analysis of the extinction cross
sections of our dust models implemented in the spectral fitting program SPEX,
the Fe K-edge is promising for investigating both the chemistry and the size
distribution of the interstellar dust. We find that the chemical composition
regulates the X-ray absorption fine structures in the post edge region, whereas
the scattering feature in the pre-edge is sensitive to the mean grain size.
Finally, we note that the Fe K-edge is insensitive to other dust properties,
such as the porosity and the geometry of the dust.Comment: 11 pages, 10 figures. Accepted for publication in Astronomy and
Astrophysic
Effect of spectral modification of on shear viscosity of a pion gas
We evaluate the shear viscosity of a pion gas in the relativistic kinetic
theory approach. The in-medium propagator of the meson at finite
temperature is used to evaluate the scattering amplitude in the
medium. The real and imaginary parts of the self-energy calculated from
one-loop diagrams are seen to have noticeable effects on the scattering
cross-section. The consequences on temperature dependence of the shear
viscosity evaluated in the Chapman-Enskog and relaxation time approximations
are studied
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