X-ray response of tunnel junctions with a trapping layer

The use of trapping layers in superconductive tunnel junctions may drastically improve their functioning as X-ray detectors. Information about these trapping layers can be obtained from I/V-curves and X-ray spectra. The application of a magnetic field causes a substantial reduction of the bandgap in the trapping layer

The Low Quiescent X-Ray Luminosity of the Transient X-Ray Burster EXO 1747-214

We report on X-ray and optical observations of the X-ray burster EXO 1747-214. This source is an X-ray transient, and its only known outburst was observed in 1984-1985 by the EXOSAT satellite. We re-analyzed the EXOSAT data to derive the source position, column density, and a distance upper limit using its peak X-ray burst flux. We observed the EXO 1747-214 field in 2003 July with the Chandra X-ray Observatory to search for the quiescent counterpart. We found one possible candidate just outside the EXOSAT error circle, but we cannot rule out the possibility that the source is unrelated to EXO 1747-214. Our conclusion is that the upper limit on the unabsorbed 0.3-8 keV luminosity is L < 7E31 erg/s, making EXO 1747-214 one of the faintest neutron star transients in quiescence. We compare this luminosity upper limit to the quiescent luminosities of 19 neutron star and 14 black hole systems and discuss the results in the context of the differences between neutron stars and black holes. Based on the theory of deep crustal heating by Brown and coworkers, the luminosity implies an outburst recurrence time of >1300 yr unless some form of enhanced cooling occurs within the neutron star. The position of the possible X-ray counterpart is consistent with three blended optical/IR sources with R-magnitudes between 19.4 and 19.8 and J-magnitudes between 17.2 and 17.6. One of these sources could be the quiescent optical/IR counterpart of EXO 1747-214.Comment: 7 pages, accepted by the Astrophysical Journa

Highly Efficient Semi-Continuous Extraction and In-Line Purification of High β-O-4 Butanosolv Lignin

Innovative biomass fractionation is of major importance for economically competitive biorefineries. Lignin is currently severely underutilized due to the use of high severity fractionation methodologies that yield complex condensed lignin that limits high-value applicability. Mild lignin fractionation conditions can lead to lignin with a more regular C-O bonded structure that has increased potential for higher value applications. Nevertheless, such extraction methodologies typically suffer from inadequate lignin extraction efficiencies and yield. (Semi)-continuous flow extractions are a promising method to achieve improved extraction efficiency of such C-O linked lignin. Here we show that optimized organosolv extraction in a flow-through setup resulted in 93-96% delignification of 40 g walnut shells (40 wt% lignin content) by applying mild organosolv extraction conditions with a 2 g/min flowrate of a 9:1 n-butanol/water mixture with 0.18 M H2SO4 at 120°C in 2.5 h. 85 wt% of the lignin (corrected for alcohol incorporation, moisture content and carbohydrate impurities) was isolated as a powder with a high retention of the β-aryl ether (β-O-4) content of 63 linking motifs per 100 C9 units. Close examination of the isolated lignin showed that the main carbohydrate contamination in the recovered lignin was butyl-xyloside and other butoxylate carbohydrates. The work-up and purification procedure were investigated and improved by the implementation of a caustic soda treatment step and phase separation with a continuous integrated mixer/separator (CINC). This led to a combined 75 wt% yield of the lignin in 3 separate fractions with 3% carbohydrate impurities and a very high β-O-4 content of 67 linking motifs per 100 C9 units. Analysis of all the mass flows showed that 98% of the carbohydrate content was removed with the inline purification step, which is a significant improvement to the 88% carbohydrate removal for the traditional lignin precipitation work-up procedure. Overall we show a convenient method for inline extraction and purification to obtain high β-O-4 butanosolv lignin in excellent yields

Transfusion practice in the bleeding critically ill:An international online survey-The TRACE-2 survey

Background: Transfusion is very common in the intensive care unit (ICU), but practice is highly variable, as has recently been shown in non-bleeding critically ill patients practices survey. Bleeding patients in ICU require different blood products across a range of specific patient categories. We hypothesize that a large variety in transfusion practice exists in bleeding patients. Study design and methods: An international online survey was performed among physicians working in the ICU. Transfusion practice in massively and non-massively bleeding patients was examined, including transfusion ratios, thresholds, and the presence of transfusion guidelines. Results: Six hundred eleven respondents filled in the survey of which 401 could be analyzed, representing 64 countries. Among the respondents, 52% had a massive transfusion protocol (MTP) available at their ICU. In massively bleeding patients, 46% of the respondents used fixed transfusion component ratios. Of those who used fixed blood ratios, the 1:1:1 ratio (red blood cell [RBC] concentrates: plasma: platelet concentrates) was most commonly used (33%). The presence of an MTP was associated with a more frequent use of fixed ratios (p <.001). For RBC transfusion in the general non-massively bleeding ICU population, a hemoglobin (Hb) threshold of 7.0[7.0–7.3] g/dl was reported. In the general ICU population, a platelet count threshold of 50[26–50] × 109/L was applied. Discussion: Half of the centers had no massive transfusion protocol available. Transfusion practice in massively bleeding critically ill patients is highly variable and driven by the presence of an MTP. In the general non-massively bleeding ICU population restrictive transfusion triggers were chosen

Effect of smoke-free legislation on the incidence of sudden circulatory arrest in the Netherlands

Objective To investigate whether smoke-free legislation in the Netherlands led to a decreased incidence of out-of-hospital sudden circulatory arrest (SCA). Smoke-free legislation was implemented in two phases: a workplace ban in 2004 and an extension of this ban to the hospitality sector on 1 July 2008. Design Weekly incidence data on SCA were obtained from the ambulance registry of South Limburg, the Netherlands. Three time periods were distinguished: the pre-ban period (1 January 2002-1 January 2004), the first post-ban period (1 January 2004-1 July 2008) and the second post-ban period (1 July 2008-1 May 2010). Trends in absolute SCA incidence were analysed using Poisson regression, adjusted for population size, ambient temperature, air pollution and influenza rates. Results A total of 2305 SCA cases were observed (mean weekly incidence 5.3 +/- 2.3 SD). The adjusted Poisson regression model showed a small but significant increase in SCA incidence during the pre-ban period (+0.20% cases per week, p = 0.044). This trend changed significantly after implementation of the first ban (with -0.24% cases per week, p = 0.043), translating into a 6.8% (22 cases) reduction in the number of SCA cases after 1 year of smoke-free legislation. No further decrease was seen after the second smoking ban. Conclusions After introduction of a nationwide workplace smoking ban in 2004, a significant decrease in the incidence of out-of-hospital SCA was seen in South Limburg. Poor enforcement of the 2008 hospitality sector ban may account for the fact that no further decrease in the incidence of SCA was seen at this time

Ultrasensitive TES Bolometers for Space Based FIR Astronomy

We present results from the development of a background limited transition edge sensor (TES) bolometer for the wavelength band 30–60 μm. The bolometer consists of a Ti/Au superconducting thermometer and a Ta radiation absorber deposited on a 200μm×300μm200μm×300μm membrane of SixNySixNy suspended on long, narrow legs. This device is voltage biased and the current through the device is measured by a SQUID amplifier. The thermometer has transition temperature Tc = 108 mKTc = 108 mK and the device is operated from a 70 mK base plate. FIR radiation is coupled into a multimodc horn with entrance aperture of 450 μm, length 4.5 mm and exit aperture of 45 μm, which feeds a metal integrating cavity containing the detector. The radiation band is defined by a pair of lowpass and highpass mesh filters in front of the horn. Here we present measurements of optical noise equivalent power (NEP), optical efficiency, dynamic range and time constant. The results show that measured TES detectors are close to meeting the requirement of the “Band 3” of SAFARI FTS imaging instrument [1] on the SPICA mission [2]

Teleworking practice in small and medium-sized firms: Management style and worker autonomy

In an empirical study of teleworking practices amongst small and medium-sized enterprises (SMEs) in West London, organisational factors such as management attitudes, worker autonomy and employment flexibility were found to be more critical than technological provision in facilitating successful implementation. Consequently, we argue that telework in most SMEs appears as a marginal activity performed mainly by managers and specialist mobile workers

Toward Annealing Stable Molybdenum Oxide Based Hole Selective Contacts For Silicon Photovoltaics

Molybdenum oxide MoOX combines a high work function with broadband optical transparency. Sandwiched between a hydrogenated intrinsic amorphous silicon passivation layer and a transparent conductive oxide, this material allows a highly efficient hole selective front contact stack for crystalline silicon solar cells. However, hole extraction from the Si wafer and transport through this stack degrades upon annealing at 190 C, which is needed to cure the screen printed Ag metallization applied to typical Si solar cells. Here, we show that effusion of hydrogen from the adjacent layers is a likely cause for this degradation, highlighting the need for hydrogen lean passivation layers when using such metal oxide based carrier selective contacts. Pre MoOX deposition annealing of the passivating a Si H layer is shown to be a straightforward approach to manufacturing MoOX based devices with high fill factors using screen printed metallization cured at 190

Hardy's inequality for functions vanishing on a part of the boundary

We develop a geometric framework for Hardy's inequality on a bounded domain when the functions do vanish only on a closed portion of the boundary.Comment: 26 pages, 2 figures, includes several improvements in Sections 6-8 allowing to relax the assumptions in the main results. Final version published at http://link.springer.com/article/10.1007%2Fs11118-015-9463-

Direct response of twin-slot antenna-coupled hot-electron bolometer mixers designed for 2.5 THz radiation detection

We measure the direct response of a Nb diffusion-cooled hot-electron bolometer mixer in a frequency range between 0.5 and 3.5 THz. The mixer consists essentially of a twin-slot antenna, a co-planar waveguide transmission line and a Nb superconducting bridge. It is designed for use in receivers with astronomical and atmospherical applications around 2.5 THz. We calculate the impedance of the antenna, the transmission line, and the bridge separately using models which are developed for frequencies below 1 THz and predict the direct response of the mixer. We demonstrate that these models can be applied to much higher frequencies. However, the measured central frequency is 10%-15% lower than predicted. (C) 2000 American Institute of Physics. [S0003-6951(00)02022-2]