36 research outputs found
Optical Properties of Core-Multishell Quantum Dots
During the past decade, colloidal semiconductor nanocrystals or quantum dots (QDs) have become not only a subject of interesting fundamental research, but also a product for real-life applications. Intense activities devoted to enhancement of QDs photoluminescence (PL) quantum yield (QY), starting from early attempts to deposit protective ZnS shells atop CdSe cores, have resulted in novel designs of core-shell QDs with 100% PL QY. In this work we present a detailed analysis of optical properties of core-“multishell” (MS) QDs, whose physical structure is specifically designed to attain maximum localization of excited charge carriers inside luminescent cores, and thereby to achieve 100% PL QY. We have produced samples of core-MS QDs having 3 to 7 shell monolayers, studied the evolution of optical transitions in such QDs during the process of shell deposition, and analyzed the effects of shell thickness on the optical properties of finally obtained QDs. Specifically, studies of PL lifetimes have revealed the possibility of alternative emission mechanism, based on delayed charge carrier transfer from excited outer CdS layer of the multishell into CdSe cores.
Keywords: quantum dots, core-shell, multishell, SILA
Next-generation theranostic agents based on polyelectrolyte microcapsules encoded with semiconductor nanocrystals: development and functional characterization
Solubility of Anthracene in Binary and Ternary Mixtures of Cyclohexanone, Ethyl Acetate, and Methanol at 298.2 K
Highly Stable, Water-Soluble CdSe/ZnS/CdS/ZnS Quantum Dots with Additional SiO2 shell
Quantum dots (QDs) are fluorescent nanocrystals extensively used today in research and applications. They attract much interest due to the high photostability and fluorescence quantum yields close to 100%. The best QDs are made by synthesis in organic media, and they have to be transferred into aqueous solutions if biomedical applications are concerned. An advanced method for rendering QDs water-soluble is to coat them with hydrophilic SiO2 -layer. However, growing a silica shell with a predetermined thickness is a problem, because uncertain values of the molar extinction coefficients (ε) of core/shell QDs made it impossible to calculate precise yields of the chemical reactions involved. Here we suggest an approach to solving this problem by constructing the structural models of per se and silica-coated QDs followed by measuring ε in a course of the QD synthesis, thus carrying out precise quantitative reactions. Proceeding in such a way, we prepared the CdSe/ZnS/CdS/ZnS QDs with the structure predicted by the model and coated by silica shell. Prepared QDs are characterized by a narrow size distribution and the same fluorescence parameters as the original QDs in the organic medium. Developed approach permitted efficient QDs water-solubilisation and preparation of stable nanoparticles for plethora of biomedical applications.
Keywords: Quantum dots, QD, silica shell, core-shel
Fine-tuning of Silica Coating Procedure for Preparation of Biocompatible and Bright Pbs/Sio2 Qds
Near-infrared semiconductor PbS quantum dots (QDs) with emission in biological transparency window are promising material for in vivo biolabelling and deep-tissue imaging of biological specimen. Among various approaches that render initially hydrophobic and toxic QDs biocompatible, the growth of a silica shell on the QD surface represents an efficient method to minimize QD toxicity. Nevertheless, it is important to preserve QDs emission properties after the silica coating procedure. Here we report on the optimal parameters of this procedure which allow to obtain a stable silica shell and maintain the optical properties of initial PbS QDs. Furthermore, we show that PbS QDs with the optimal SiO2 shell retain their luminescence quantum yield even after condensation into a solid film. Thus, our procedure can become a basis in development of bright, receptor-targeted NIR fluorescent probes for in vivo tumor imaging.
Keywords: quantum dot, SiO2 shell, bioimagin
Solubility of Anthracene in Ternary 1,4-Dioxane + Alcohol + 2,2,4-Trimethylpentane Solvent Mixtures at 298.15 K
Solubility of Anthracene in Ternary 1,4-Dioxane + Alcohol + Heptane Solvent Mixtures at 298.15 K
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