Wear prevention characteristics of a palm oil-based TMP (trimethylolpropane) ester as an engine lubricant

This paper presents the experimental results carried out to evaluate wear prevention characteristics of a palm oil-based TMP (trimethylolpropane) ester using a four-ball machine for different regime of lubrication. The TMP ester is produced from palm oil, which is biodegradable and has high lubricity properties such as a higher flash point temperature and VI (viscosity index). Three different regimes of lubrications are investigated, which hydrodynamic, elasto hydrodynamic and boundary lubrications. Under these test conditions, the wear and friction characteristics of different TMP samples are measured and compared. For boundary lubrication, it is found that up to 3% addition of Palm oil-based TMP ester in OL (ordinary lubricant) decreases the maximum amount of WSD (wear scar diameter) and reduces (COF coefficient of friction) up to 30%. Highest amount of load (220 kg) carrying capacity was also found from the contamination of 3% TMP. For hydrodynamic lubrication, addition of 7% of TMP reduces the friction up to 50%. It is well known that mechanical efficiency of machinery component increases with decreasing COF. The results of this investigation will be used to develop new and efficient lubricant to substitute the petroleum-based lubricant partially for automotive engine application

Lubricity of bio-based lubricant derived from different chemically modified fatty acid methyl ester

In this research, polyol ester was used as the source of a biolubricant. The trimethylolpropane (TMP) and pentaerythritol ester (PE) were produced from palm oil methyl ester; they are biodegradable and have high lubricity properties. Two different conditions of lubrication were investigated. Under these test conditions, the wear and friction characteristics of different ester samples were measured and compared. The esters derived from PE and TMP had comparable characteristics to the fully formulated lubricant (FFL) in terms of the coefficient of friction (CoF). In terms of the mixed lubrication condition, the PE ester has the lowest CoF

Using finite volume method for simulating the natural convective heat transfer of nano-fluid flow inside an inclined enclosure with conductive walls in the presence of a constant temperature heat source

In the present work, natural convective heat transfer of water/Al2O3 nano-fluid in an inclined square enclosure is investigated. The side walls of the cavity are cold and the upper and lower ones are insulated. A wall with a thermal-conductivity of 100 and a thickness of 0.5 is located on the cold walls. Moreover, there is a constant temperature heat source in the center of the enclosure. The enclosure is located under the influence of an inclined magnetic field (MF). The governing equations were solved using the finite volume method (FVM) and solved using the SIMPLE algorithm. The results show that the heat transfer rate intensifies up to 3.11 times with intensifying the Rayleigh number (Ra). The maximum heat transfer occurred at weak magnetic fields. By augmenting the angle of the enclosure, the heat transfer rate on the right and left walls intensifies by 33% and declines by 55%, respectively. The heat transfer rate on the right wall intensifies by 14% by augmenting the angle of the MF. The addition of nano-additives also results in intensification in the heat transfer rate

Physicochemical and tribological properties of microalgae oil as biolubricant for hydrogen-powered engine

Hydrogen fuel offers a cleaner fuel alternative to fossil fuel due to more efficient burning as well as reduces the environmental and health issues brought by fossil fuel usage. In engine application, regardless of either pure hydrogen or in combination with air or/and other biofuel, all the moving parts are exposed to friction and wear, and lubricant is used to minimize friction and wear for optimum operation. Thus, in this study, the use of microalgae oil as an alternative biolubricant is evaluated from the physicochemical and tribological aspects. It is found that modified microalgae oil (MMO) has demonstrated great anti-friction and anti-wear potential, particularly the 10% modified microalgae oil blend (MMO-10). The coefficient of friction is reduced (up to 10.1%) and significant reductions of wear loss and surface roughness are obtained in comparison to pure poly-alpha-olefin. Lubricant's heat dissipation is also enhanced with MMO addition, demonstrating great prospect for MMO for hydrogen-powered engine utilization

Experimental investigation of performance, emissions and tribological characteristics of B20 blend from cottonseed and palm oil biodiesels

Reserves of fossil fuel are being depleted, and its use to generate energy also affects the environment. Sustainable and clean energy sources, therefore, need to be produced to meet the demands. In this research, combined blended fuels were produced from cottonseed and palm oil methyl esters with petroleum diesel fuel. To achieve the benefits of palm oil biodiesel (high calorific value) and cottonseed oil biodiesel (low kinematic viscosity and acid value), the combined biodiesel blend (C05P15, C10P10, and C15P05) has been tested to assess their effect on engine performance, emissions, and tribological properties. The physicochemical properties of all fuels were measured following ASTM D6751 standard. A single-cylinder, 4-stroke, and the natural aspiration diesel engine were used for engine testing. The experimental results showed that all combined blended fuels have low brake thermal efficiency and emitted fewer hydrocarbons, carbon monoxide, and smoke opacity apart from nitrogen oxides compared with petroleum diesel fuel. Based on results, the combined blended fuel can be used as a substitute fuel in diesel engines without any engine modifications

Tribological improvement using ionic liquids as additives in synthetic and bio-based lubricants for steel-steel contacts

This study investigates the performance of three ionic liquids (ILs), trihexyl(tetradecyl)phosphonium bis(2,4,4-trimethylpentyl)phosphinate, trihexyl(tetradecyl)phosphonium decanoate, and 1-butyl-3-methylimidazolium tetrafluoroborate, as lubricant additives in synthetic oil polyalphaolefin (PAO8) and bio-based oil trimethylolpropane trioleate (TMPTO). The ILs were added at 0.5, 1.0, and 1.5 wt% concentrations and evaluated in terms of their miscibility with base oils as well as friction- and wear-reducing abilities. Four-ball and high-frequency reciprocating rig (HFRR) tribotesters were employed to evaluate the tribological performance under a boundary lubrication regime. Worn steel surfaces were characterized using optical microscopy, profilometry, scanning electron microscopy (SEM), and energy-dispersive X-ray (EDX) analysis. The results suggested that the addition of trihexyl(tetradecyl)phosphonium bis(2,4,4-trimethylpentyl)phosphinate and trihexyl(tetradecyl)phosphonium decanoate improved the tribological performance of both PAO8 and TMPTO at an optimum concentration of 1 wt%. They showed good friction reduction, lower overall surface wear, and improved surface finishing. 1-Butyl-3-methylimidazolium tetrafluoroborate managed to improve the tribological performance of both base oils only at 0.5 wt%. A further increase in 1-butyl-3-methylimidazolium tetrafluoroborate concentration caused detrimental effects on the steel surface due to the formation of halogenic compounds

Sustainability of palm biodiesel in transportation: a review on biofuel standard, policy and international collaboration between Malaysia and Colombia

Biodiesel is gaining prominence as a superior alternative source of energy to replace petroleum-based fuel in transportation. As of today, the biodiesel market continuous to rise up as the biofuel has been introduced to more than 60 countries worldwide. The aim of the present review is to highlight on the scenario of the biofuel implementation in transportation sector towards sustainable development in Colombia and Malaysia. Colombia serves as an ideal comparative case for Malaysia in terms of biodiesel development since the country is the main palm oil producer in Latin America region and the pioneer in bioethanol industry. The first section shows an overview on the biodiesel as an alternative fuel in transportation. The next section will focus on a comparative study between Malaysia and Colombia biodiesel sector in terms of energy supply, resource, production and consumption, standards, techno-economic cost and their biodiesel policies. A comprehensive review was studied to discuss on the sustainability of palm cultivation and biodiesel, impact of palm industry and biodiesel policy in transportation sector and potential international collaboration between Malaysia and Colombia to improve their existing policies, strategies and blueprints related to the palm biodiesel industry, thus overcoming the challenges when dealing with global energy issue

Tribological characteristics comparison of formulated palm trimethylolpropane ester and polyalphaolefin for cam/tappet interface of direct acting valve train system

Purpose There is a continuous drive in automotive sector to shift from conventional lubricants to environmental friendly ones without adversely affecting critical tribological performance parameters. Because of their favorable tribological properties, chemically modified vegetable oils such as palm trimethylolpropane ester (TMP) are one of the potential candidates for the said role. To prove the suitability of TMP for applications involving boundary-lubrication regime such as cam/tappet interface of direct acting valve train system, a logical step forward is to investigate their compatibility with conventional lubricant additives. Design/methodology/approach In this study, extreme pressure and tribological characteristics of TMP, formulated with glycerol mono-oleate (GMO), molybdenum dithiocarbamate (MoDTC) and zinc dialkyldithiophosphate (ZDDP), has been investigated using four-ball wear tester and valve train test rig. For comparison, additive-free and formulated versions of polyalphaolefin (PAO) were used as reference. Moreover, various surface characterization techniques were deployed to investigate mechanisms responsible for a particular tribological behavior. Findings In additive-free form, TMP demonstrated better extreme pressure characteristics compared to PAO and lubricant additives which are actually optimized for conventional base-oils such as PAO, are also proved to be compatible with TMP to some extent, especially ZDDP. During cylinder head tests, additive-free TMP proved to be more effective compared to PAO in reducing friction of cam/tappet interface, but opposite behavior was seen when formulated lubricants were used. Therefore, there is a need to synthesize specialized friction modifiers, anti-wear and extreme pressure additives for TMP before using it as engine lubricant base-oil. Originality/value In this study, additive-free and formulated versions of bio-lubricant are tested for cam/tappet interface of direct acting valve train system of commercial passenger car diesel engine for the very test time. Another important aspect of this research was comparison of important tribological performance parameters (friction torque, wear, rotational speed of tappet) of TMP-based lubricants with conventional lubricant base oil, that is, PAO and its formulated version

Tribological characteristics comparison of formulated palm trimethylolpropane ester and polyalphaolefin for cam/tappet interface of direct acting valve train system

Purpose: There is a continuous drive in automotive sector to shift from conventional lubricants to environmental friendly ones without adversely affecting critical tribological performance parameters. Because of their favorable tribological properties, chemically modified vegetable oils such as palm trimethylolpropane ester (TMP) are one of the potential candidates for the said role. To prove the suitability of TMP for applications involving boundary-lubrication regime such as cam/tappet interface of direct acting valve train system, a logical step forward is to investigate their compatibility with conventional lubricant additives. Design/methodology/approach: In this study, extreme pressure and tribological characteristics of TMP, formulated with glycerol mono-oleate (GMO), molybdenum dithiocarbamate (MoDTC) and zinc dialkyldithiophosphate (ZDDP), has been investigated using four-ball wear tester and valve train test rig. For comparison, additive-free and formulated versions of polyalphaolefin (PAO) were used as reference. Moreover, various surface characterization techniques were deployed to investigate mechanisms responsible for a particular tribological behavior. Findings: In additive-free form, TMP demonstrated better extreme pressure characteristics compared to PAO and lubricant additives which are actually optimized for conventional base-oils such as PAO, are also proved to be compatible with TMP to some extent, especially ZDDP. During cylinder head tests, additive-free TMP proved to be more effective compared to PAO in reducing friction of cam/tappet interface, but opposite behavior was seen when formulated lubricants were used. Therefore, there is a need to synthesize specialized friction modifiers, anti-wear and extreme pressure additives for TMP before using it as engine lubricant base-oil. Originality/value: In this study, additive-free and formulated versions of bio-lubricant are tested for cam/tappet interface of direct acting valve train system of commercial passenger car diesel engine for the very test time. Another important aspect of this research was comparison of important tribological performance parameters (friction torque, wear, rotational speed of tappet) of TMP-based lubricants with conventional lubricant base oil, that is, PAO and its formulated version