High Current Matching over Full-Swing and Low-Glitch Charge Pump Circuit for PLLs

A high current matching over full-swing and low-glitch charge pump (CP) circuit is proposed. The current of the CP is split into two identical branches having one-half the original current. The two branches are connected in source-coupled structure, and a two-stage amplifier is used to regulate the common-source voltage for the minimum current mismatch. The proposed CP is designed in TSMC 0.18µm CMOS technology with a power supply of 1.8 V. SpectreRF based simulation results show the mismatch between the current source and the current sink is less than 0.1% while the current is 40 µA and output swing is 1.32 V ranging from 0.2 V to 1.52 V. Moreover, the transient output current presents nearly no glitches. The simulation results verify the usage of the CP in PLLs with the maximum tuning range from the voltage-controlled oscillator, as well as the low power supply applications

Thermal stability and oxidation of layer-structured rhombohedral In3Se4 nanostructures

The thermal stability and oxidation of layer-structured rhombohedral In3Se4 nanostructures have been investigated. In-situ synchrotron X-ray diffraction in a sealed system reveals that In3Se4 has good thermal stability up to 900 degrees C. In contrast, In3Se4 has lower thermal stability up to 550 or 200 degrees C when heated in an atmosphere flushed with Ar or in air, respectively. The degradation mechanism was determined to be the oxidation of In3Se4 by O-2 in the heating environment. This research demonstrates how thermal processing conditions can influence the thermal stability of In3Se4, suggesting that appropriate heating environment for preserving its structural integrity is required. (C) 2013 AIP Publishing LLC

Magnetotransport properties of Cd3As2 nanostructures

Three-dimensional (3D) topological Dirac semimetal is a new kind of material that has a linear energy dispersion in 3D momentum space and can be viewed as an analog of graphene. Extensive efforts have been devoted to the understanding of bulk materials, but yet it remains a challenge to explore the intriguing physics in low-dimensional Dirac semimetals. Here, we report on the synthesis of Cd3As2 nanowires and nanobelts and a systematic investigation of their magnetotransport properties. Temperature-dependent ambipolar behavior is evidently demonstrated, suggesting the presence of finite-size of bandgap in nanowires. Cd3As2 nanobelts, however, exhibit metallic characteristics with a high carrier mobility exceeding 32,000 cm2V-1s-1 and pronounced anomalous double-period Shubnikov-de Haas (SdH) oscillations. Unlike the bulk counterpart, the Cd3As2 nanobelts reveal the possibility of unusual change of the Fermi sphere owing to the suppression of the dimensionality. More importantly, their SdH oscillations can be effectively tuned by the gate voltage. The successful synthesis of Cd3As2 nanostructures and their rich physics open up exciting nanoelectronic applications of 3D Dirac semimetals.Comment: 18 pages, 5 figure

Suppression of Black-body Radiation Induced Zeeman Shifts in the Optical Clocks due to the Fine-structure Intramanifold Resonances

The roles of the fine-structure intramanifold resonances to the Zeeman shifts caused by the blackbody radiation (BBRz shifts) in the optical clock transitions are analyzed. The clock frequency measurement in the $^1S_0-^3P_0$ clock transition of the singly charged aluminium ion (Al$^+$) has already been reached the $10^{-19}$ level at which the BBRz effect can be significant in determining the uncertainty. In view of this, we probe first the BBRz shift in this transition rigorously and demonstrate the importance of the contributions from the intramanifold resonances explicitly. To carry out the analysis, we determine the dynamic magnetic dipole (M1) polarizabilities of the clock states over a wide range of angular frequencies by employing two variants of relativistic many-body methods. This showed the BBRz shift is highly suppressed due to blue-detuning of the BBR spectrum to the $^3P_0-^3P_1$ fine-structure intramanifold resonance in Al$^+$ and it fails to follow the usually assumed static M1 polarizability limit in the estimation of the BBRz shift. The resonance also leads to a reversal behavior of the temperature dependence and a cancellation in the shift. After learning this behavior, we extended our analyses to other optical clocks and found that these shifts are of the order of micro-hertz leading to fractional shifts in the clock transitions at the $10^{-20}$ level or below

Calibration of Temperature in the Lower Stratosphere from Microwave Measurements Using COSMIC Radio Occultation Data: Preliminary Results

Accurate, consistent, and stable observations from different satellite missions are crucial for climate change detection. In this study, we use Global Positioning System (GPS) Radio Occultation (RO) data from the early phase of the FORMOSAT-3/Constellation Observing System for Meteorology, Ionosphere, and Climate (COSMIC) mission, which was successfully launched on 15 April 2006, to inter-calibrate Temperature in the Lower Stratosphere (TLS) taken from Advanced Microwave Sounding Unit (AMSU) microwave measurements from different satellites for potential improvements of stratospheric temperature trend analysis. Because of the limited number of COSMIC soundings in the early phase of the mission, these results are considered preliminary. In this study, we use COSMIC RO data to simulate microwave brightness temperatures for comparison with AMSU Ch9 measurements (e.g., TLS) on board NOAA15, 16, and 18. Excellent correlation was found between synthetic COSMIC brightness temperatures (Tbs) and Tbs from NOAA15, NOAA16, and NOAA18, respectively. However, systematic differences on the order of 0.7 to 2 K were found between COSMIC and AMSU observations over Antarctica. Our results demonstrate that synthetic COSMIC Tbs are very useful in identifying inter-satellite offsets among AMSU measurements from different satellites. To demonstrate the long-term stability of GPS RO data, we compare COSMIC dry temperature profiles to those from collocated CHAMP profiles, where CHAMP was launched in 2001. The fact that the CHAMPand COSMIC dry temperature difference between 500 and 10 hPa ranges from -0.35 K (at 10 hPa) to 0.25 K (at 30 hPa) and their mean difference is about -0.034 K demonstrates the long-term stability of GPS RO signals. In order to demonstrate the potential usage of the GPS RO calibrated AMSU Tbs to inter-calibrate other overlapping AMSU Tbs, we examine the uncertainty of the calibration coefficients derived from AMSU-GPS RO pairs. We found the difference between COSMIC calibrated AMSU Tbs and those from CHAMP to be in the range of __0.07 K with a 0.1 K standard deviation. This demonstrates the robustness of the calibration coefficients found from AMSU-GPS RO pairs and shows the potential to use the calibrated AMSU Tbs to calibrate other overlapping AMSU Tbs where no coincident GPS RO data are available

Dimensionality-confined superconductivity within SrNbO3-SrTiO3 heterostructures

Interfaces between transition-metal oxides are able to host two-dimensional electron gases (2DEGs) and exhibit exotic quantum phenomena. Here we report the observation of superconductivity below 230 mK for the heterostructure composed of SrNbO3 (SNO) and SrTiO3 (STO). Different from some other counterparts with two insulators, the metallic SNO provides a novel mechanism to form a quasi 2DEG by charge transfer from bulk towards interface under strain. The superconductivity, residing within the strained SNO layer near the interface, is contributed by an electron system with record-low carrier density. Notably, although embedded in a normal metallic layer with a carrier density 4 to 5 orders higher, the electron system is still uniquely well-protected to retain high mobility and lies deep in extreme quantum regime

Pretreating anaerobic fermentation liquid with calcium addition to improve short chain fatty acids extraction via in situ synthesis of layered double hydroxides

In situ synthesis of layered double hydroxides (LDHs) was proved to be an effective way to extract short chain fatty acids (SCFAs) from anaerobic fermentation liquid (AFL) as carbon source for biodenitrification, but the SCFAs content in SCFAs-LDH was unsatisfactory because of the existence of much carbonate in AFL. Pretreatment of AFL with calcium addition was investigated to remove carbonate and improve SCFAs extraction via LDHs synthesis. Results of batch tests showed that, the carbonate removal efficiency was as high as 76.6% when the calcium addition was 0.06 mol/L at pH 12. When using the optimal SCFAs/Al3+ ratio of 3.0, the total SCFAs content in SCFAs-LDH with pretreatment was improved to 46.5 mg COD/g LDH, which was 4.5 times of the control (10.4 mg COD/g LDH). These results suggest that adding calcium to AFL was an effective way to eliminate the negative effect of carbonates on SCFAs-LDH synthesis

A new crystal: Layer-structured rhombohedral In3Se4

A new layer-structured rhombohedral In3Se4 crystal was synthesized by a facile and mild solvothermal method. Detailed structural and chemical characterizations using transmission electron microscopy, coupled with synchrotron X-ray diffraction analysis and Rietveld refinement, indicate that In3Se4 crystallizes in a layered rhombohedral structure with lattice parameters of a = 3.964 ± 0.002 Å and c = 39.59 ± 0.02 Å, a space group of R3m, and with a layer composition of Se-In-Se-In-Se-In-Se. The theoretical modeling and experimental measurements indicate that the In3Se4 is a self-doped n-type semiconductor. This study not only enriches the understanding on crystallography of indium selenide crystals, but also paves a way in the search for new semiconducting compounds. This journal i