Anomalous expansion and phonon damping due to the Co spin-state transition in RCoO_3 with R = La, Pr, Nd and Eu

We present a combined study of the thermal expansion and the thermal conductivity of the perovskite series RCoO_3 with R = La, Nd, Pr and Eu. The well-known spin-state transition in LaCoO_3 is strongly affected by the exchange of the R ions due to their different ionic radii, i.e. chemical pressure. This can be monitored in detail by measurements of the thermal expansion, which is a highly sensitive probe for detecting spin-state transitions. The Co ions in the higher spin state act as additional scattering centers for phonons, therefore suppressing the phonon thermal conductivity. Based on the analysis of the interplay between spin-state transition and heat transport, we present a quantitative model of the thermal conductivity for the entire series. In PrCoO_3, an additional scattering effect is active at low temperatures. This effect arises from the crystal field splitting of the 4f multiplet, which allows for resonant scattering of phonons between the various 4f levels.Comment: 15 pages including 5 figure

Thermal Conductivity, Thermopower, and Figure of Merit of La_{1-x}Sr_xCoO_3

We present a study of the thermal conductivity k and the thermopower S of single crystals of La_{1-x}Sr_xCoO_3 with 0<= x <= 0.3. For all Sr concentrations La_{1-x}Sr_xCoO_3 has rather low k values, whereas S strongly changes as a function of x. We discuss the influence of the temperature- and the doping-induced spin-state transitions of the Co ions on both, S and k. From S, k, and the electrical resistivity rho we derive the thermoelectric figure of merit Z=S^2/(k*rho). For intermediate Sr concentrations we find notably large values of Z indicating that Co-based materials could be promising candidates for thermoelectric cooling.Comment: 7 pages, 5 figures included, submitted to Phys. Rev.

Le marché des stupéfiants dans le canton de Vaud. Partie 1 : les opioïdes

Le projet « Structure et produits du marché des stupéfiants » (MARSTUP) est né d'une volonté de collaboration de trois Instituts de recherche lausannois qui travaillent depuis de nombreuses années sur la question des stupéfiants : Addiction Suisse, l'Ecole des sciences criminelles (ESC) de l'Université de Lausanne et l'Institut universitaire de médecine sociale et préventive (IUMSP) du CHUV. Tous trois ont pris conscience de l'intérêt d'étudier cette dimension souvent ignorée de la problématique des stupéfiants. L'objectif de la collaboration est de développer une compréhension de la structure et de l’organisation du marché des stupéfiants qui puisse contribuer à l'amélioration des politiques publiques et à promouvoir des débats plus factuels à ce sujet. Il s'agit aussi de développer un outil de monitorage qui permette de suivre l’évolution temporelle de ce marché. Le canton de Vaud a accepté de cofinancer ce projet et un groupe d'accompagnement, formé de professionnels de la santé publique et de la sécurité, a été constitué. Le projet a été divisé en trois parties successives: le marché des opioïdes, celui des stimulants et celui des cannabinoïdes. Chacun fait l'objet d'une analyse de marché à quatre niveaux: les produits proposés, les volumes consommés, la structure et organisation du marché, et sa valeur. Les données utilisées comprennent des enquêtes et statistiques existantes, ainsi que de nouvelles études, notamment des entretiens auprès des professionnels concernés par ce marché et avec des usagers de stupéfiants. Les analyses des eaux usées et celles du contenu résiduel des seringues usagées ont aussi été intégrées dans le projet. Il s'agit de la première étude interdisciplinaire de ce type en Suisse. Le présent rapport – le premier du projet – porte sur le marché des opioïdes

Spin-State Transition and Metal-Insulator Transition in La1−x_{1-x}Eux_xCoO3_3}

We present a study of the structure, the electric resistivity, the magnetic susceptibility, and the thermal expansion of La$_{1-x}$Eu$_x$CoO$_3$. LaCoO$_3$ shows a temperature-induced spin-state transition around 100 K and a metal-insulator transition around 500 K. Partial substitution of La$^{3+}$ by the smaller Eu$^{3+}$ causes chemical pressure and leads to a drastic increase of the spin gap from about 190 K in LaCoO$_3$ to about 2000 K in EuCoO$_3$, so that the spin-state transition is shifted to much higher temperatures. A combined analysis of thermal expansion and susceptibility gives evidence that the spin-state transition has to be attributed to a population of an intermediate-spin state with orbital order for $x<0.5$ and without orbital order for larger $x$. In contrast to the spin-state transition, the metal-insulator transition is shifted only moderately to higher temperatures with increasing Eu content, showing that the metal-insulator transition occurs independently from the spin-state distribution of the Co$^{3+}$ ions. Around the metal-insulator transition the magnetic susceptibility shows a similar increase for all $x$ and approaches a doping-independent value around 1000 K indicating that well above the metal-insulator transition the same spin state is approached for all $x$.Comment: 10 pages, 6 figure

МЕТОДИКА ПРОВЕДЕННЯ ІСТОРИКО-КРАЄЗНАВЧИХ ЕКСПЕДИЦІЙ НА ПІВДНІ УКРАЇНИ ІНСТИТУТОМ ЕТНОГРАФІЇ АН СРСР у 50-60-ті рр. ХХ ст.

Український народ у своїй історії має великий досвід духовного життя, бо з покоління в покоління передає набуті навички, що стали невід’ємною части-ною нашої національності. Але з кожним роком наше покоління, на жаль, втра-чає зв’язок з попередніми поколіннями. Тому, щоб зберегти традиції, націона-льні особливості, в різні часи різноманітні інститути, товариства, окремі дослі-дники намагались створити найоптимальнішу методику організації та прове-дення історико-краєзнавчих експедицій

Identifying and prioritising services in European terrestrial and freshwater ecosystems

Ecosystems are multifunctional and provide humanity with a broad array of vital services. Effective management of services requires an improved evidence base, identifying the role of ecosystems in delivering multiple services, which can assist policy-makers in maintaining them. Here, information from the literature and scientific experts was used to systematically document the importance of services and identify trends in their use and status over time for the main terrestrial and freshwater ecosystems in Europe. The results from this review show that intensively managed ecosystems contribute mostly to vital provisioning services (e.g. agro-ecosystems provide food via crops and livestock, and forests provide wood), while semi-natural ecosystems (e.g. grasslands and mountains) are key contributors of genetic resources and cultural services (e.g. aesthetic values and sense of place). The most recent European trends in human use of services show increases in demand for crops from agro-ecosystems, timber from forests, water flow regulation from rivers, wetlands and mountains, and recreation and ecotourism in most ecosystems, but decreases in livestock production, freshwater capture fisheries, wild foods and virtually all services associated with ecosystems which have considerably decreased in area (e.g. semi-natural grasslands). The condition of the majority of services show either a degraded or mixed status across Europe with the exception of recent enhancements in timber production in forests and mountains, freshwater provision, water/erosion/natural hazard regulation and recreation/ecotourism in mountains, and climate regulation in forests. Key gaps in knowledge were evident for certain services across all ecosystems, including the provision of biochemicals and natural medicines, genetic resources and the regulating services of seed dispersal, pest/disease regulation and invasion resistance

Structural and chemical investigations of adapted Siemens feed rods for an optimized float zone process

The optimization of the float zone process for industrial application is a promising way to crystallize high purity silicon for high efficiency solar cells with reduced process costs. We investigated two differently produced Siemens rods which should be used as feed material for the float zone process. The aim is to identify and to improve material properties of the feed rods which have a high impact to the float zone process. We show here microstructural and chemical analysis comparing feed rods manufactured under standard conditions and under float zone adapted conditions. To resolve the growth behavior of the grains SEM/EBSD mappings are performed at different positions. TEM analyses are used to investigate the interface region between the mono- and the multicrystalline silicon within the Siemens feed rod. Additionally, drilled cores are cut out from the feed rods containing the region of the slim rod. Afterwards, the drilled cores are crystallized with the float zone process. Finally, carbon and oxygen measurements with FT-IR spectrometry on different positions of the crystallized drilled cores of the Siemens feed rods show the influence of the slim rod material to the float zone process

Influence of slim rod material properties to the Siemens feed rod and the float zone process

The identification and understanding of material properties influencing the float zone process is important to crystallize high purity silicon for high efficiency solar cells. Also the knowledge of minimal requirements to crystallize monocrystalline silicon with the float zone process is of interest from an economic point of view. In the present study, feed rods for the float zone process composed of a central slim rod and the deposited silicon from the Siemens process are investigated. Previous studies have shown that the slim rod has a significant impact on the purity and suitability for further crystallization processes. In particular, contaminations like substitutional carbon and the presence of precipitates as well as the formation of oxide layers play an important role and are investigated in detail. For this purpose different slim rod materials were used in deposition and float zone crystallization experiments. Samples were prepared by cross sectioning and core drilling of Siemens rods, which were recrystallized with the float zone process. Recrystallized drilled cores are analyzed with FT-IR spectrometry concerning the carbon and oxygen content. To estimate the grain growth behavior on the slim rod surface in dependence of the used slim rod material, EBSD mappings inside a SEM are performed on squared and circular slim rods. TEM analysis was used to investigate the presence of an oxide layer at the interface between slim rod and deposited polycrystalline silicon. Additionally the influence of a nitrogen-containing gas atmosphere during the slim rod pulling is investigated by IR microscopy and ToF-SIMS regarding Si3N4 precipitation