16,055 research outputs found
Near-field spectra of quantum well excitons with non-Markovian phonon scattering
The excitonic absorption spectrum for a disordered quantum well in presence
of exciton-acoustic phonon interaction is treated beyond the Markov
approximation. Realistic disorder exciton states are taken from a microscopic
simulation, and the deformation potential interaction is implemented. The
exciton Green's function is solved with a self energy in second order Born
quality. The calculated spectra differ from a superposition of Lorentzian
lineshapes by enhanced inter-peak absorption. This is a manifestation of pure
dephasing which should be possible to measure in near-field experiments.Comment: 8 pages, 7 figure
Evaluation of non-intrusive flow measurement techniques for a re-entry flight experiment
This study evaluates various non-intrusive techniques for the measurement of the flow field on the windward side of the Space Shuttle orbiter or a similar reentry vehicle. Included are linear (Rayleigh, Raman, Mie, Laser Doppler Velocimetry, Resonant Doppler Velocimetry) and nonlinear (Coherent Anti-Stokes Raman, Laser-Induced Fluorescence) light scattering, electron-beam fluorescence, thermal emission, and mass spectroscopy. Flow-field properties were taken from a nonequilibrium flow model by Shinn, Moss, and Simmonds at the NASA Langley Research Center. Conclusions are, when possible, based on quantitative scaling of known laboratory results to the conditions projected. Detailed discussion with researchers in the field contributed further to these conclusions and provided valuable insights regarding the experimental feasibility of each of the techniques
Path integral evaluation of equilibrium isotope effects
A general and rigorous methodology to compute the quantum equilibrium isotope
effect is described. Unlike standard approaches, ours does not assume
separability of rotational and vibrational motions and does not make the
harmonic approximation for vibrations or rigid rotor approximation for the
rotations. In particular, zero point energy and anharmonicity effects are
described correctly quantum mechanically. The approach is based on the
thermodynamic integration with respect to the mass of isotopes and on the
Feynman path integral representation of the partition function. An efficient
estimator for the derivative of free energy is used whose statistical error is
independent of the number of imaginary time slices in the path integral,
speeding up calculations by a factor of 60 at 500 K. We describe the
implementation of the methodology in the molecular dynamics package Amber 10.
The method is tested on three [1,5] sigmatropic hydrogen shift reactions.
Because of the computational expense, we use ab initio potentials to evaluate
the equilibrium isotope effects within the harmonic approximation, and then the
path integral method together with semiempirical potentials to evaluate the
anharmonicity corrections. Our calculations show that the anharmonicity effects
amount up to 30% of the symmetry reduced reaction free energy. The numerical
results are compared with recent experiments of Doering and coworkers,
confirming the accuracy of the most recent measurement on
2,4,6,7,9-pentamethyl-5-(5,5-H)methylene-11,11a-dihydro-12H-naphthacene
as well as concerns about compromised accuracy, due to side reactions, of
another measurement on
2-methyl-10-(10,10-H)methylenebicyclo[4.4.0]dec-1-ene.Comment: 14 pages, 8 figures, 6 table
Saddle Points and Stark Ladders: Exact Calculations of Exciton Spectra in Superlattices
A new, exact method for calculating excitonic absorption in superlattices is
described. It is used to obtain high resolution spectra showing the saddle
point exciton feature near the top of the miniband. The evolution of this
feature is followed through a series of structures with increasing miniband
width. The Stark ladder of peaks produced by an axial electric field is
investigated, and it is shown that for weak fields the line shapes are strongly
modified by coupling to continuum states, taking the form of Fano resonances.
The calculated spectra, when suitably broadened, are found to be in good
agreement with experimental results.Comment: 9 pages Revtex v3.0, followed by 4 uuencoded postscript figures,
SISSA-CM-94-00
Non-intrusive flow measurements on a reentry vehicle
This study evaluates the utility of various non-intrusive techniques for the measurement of the flow field on the windward side of the Space Shuttle or a similar re-entry vehicle. Included are linear (Rayleigh, Raman, Mie, Laser Doppler Velocimetry, Resonant Doppler Velocimetry) and nonlinear (Coherent Anti-Stokes Raman, Laser Induced Fluorescence) light scattering, electron beam fluorescence, thermal emission and mass spectroscopy. Flow field properties are taken from a nonequilibrium flow model by Shinn, Moss and Simmonds at NASA Langley. Conclusions are, when possible, based on quantitative scaling of known laboratory results to the conditions projected. Detailed discussion with researchers in the field contributed further to these conclusions and provided valuable insights regarding the experimental feasibility of each of the techniques
Observation of Lasing Mediated by Collective Atomic Recoil
We observe the buildup of a frequency-shifted reverse light field in a
unidirectionally pumped high- optical ring cavity serving as a dipole trap
for cold atoms. This effect is enhanced and a steady state is reached, if via
an optical molasses an additional friction force is applied to the atoms. We
observe the displacement of the atoms accelerated by momentum transfer in the
backscattering process and interpret our observations in terms of the
collective atomic recoil laser. Numerical simulations are in good agreement
with the experimental results.Comment: 4 pages, 3 figure
Diffraction of a Bose-Einstein condensate from a Magnetic Lattice on a Micro Chip
We experimentally study the diffraction of a Bose-Einstein condensate from a
magnetic lattice, realized by a set of 372 parallel gold conductors which are
micro fabricated on a silicon substrate. The conductors generate a periodic
potential for the atoms with a lattice constant of 4 microns. After exposing
the condensate to the lattice for several milliseconds we observe diffraction
up to 5th order by standard time of flight imaging techniques. The experimental
data can be quantitatively interpreted with a simple phase imprinting model.
The demonstrated diffraction grating offers promising perspectives for the
construction of an integrated atom interferometer.Comment: 4 pages, 4 figure
Stripe-hexagon competition in forced pattern forming systems with broken up-down symmetry
We investigate the response of two-dimensional pattern forming systems with a
broken up-down symmetry, such as chemical reactions, to spatially resonant
forcing and propose related experiments. The nonlinear behavior immediately
above threshold is analyzed in terms of amplitude equations suggested for a
and ratio between the wavelength of the spatial periodic forcing
and the wavelength of the pattern of the respective system. Both sets of
coupled amplitude equations are derived by a perturbative method from the
Lengyel-Epstein model describing a chemical reaction showing Turing patterns,
which gives us the opportunity to relate the generic response scenarios to a
specific pattern forming system. The nonlinear competition between stripe
patterns and distorted hexagons is explored and their range of existence,
stability and coexistence is determined. Whereas without modulations hexagonal
patterns are always preferred near onset of pattern formation, single mode
solutions (stripes) are favored close to threshold for modulation amplitudes
beyond some critical value. Hence distorted hexagons only occur in a finite
range of the control parameter and their interval of existence shrinks to zero
with increasing values of the modulation amplitude. Furthermore depending on
the modulation amplitude the transition between stripes and distorted hexagons
is either sub- or supercritical.Comment: 10 pages, 12 figures, submitted to Physical Review
Significance of ventricular late potentials in non-ischaemic dilated cardiomyopathy
To assess the incidence and clinical significance of ventricular late potentials in non-ischaemic dilated cardiomyopathy, 51 consecutive (44 male, seven female, mean age 53± 11 years) patients with dilated cardiomyopathy were studied. Twenty-eight patients (55%) were in New York Heart Association functional class III or IV, 34 out of 51 (76%) had a left ventricular ejection fraction of less than 40%, 10 out of 51 (20%) had a history of sustained ventricular tachycardia ( VT), 24 out of 37 (65%) had runs of non-sustained ventricular tachycardia during Holier monitoring and 15 out of 51 (29%) had a left bundle branch block. A signal-averaged electrocardiogram (gain 106 x, bipolar chest leads, filters 100-300 Hz) was performed in all the patients; late potentials were considered present if the total filtered QRS duration was longer than 118 ms and the interval between the end of QRS and the voltage 40 μV was more than 40 ms in the absence of left bundle branch block (total filtered QRS duration > 140 ms and interval between the end of QRS and the voltage 40 μV>50ms in the presence of left bundle branch block). Ventricular late potentials were detected in 22 out of 51 patients (43%). Late potentials were present in 80% (eight out of 10) of patients with sustained ventricular tachycardia but in only 34% (14 of 41) without sustained ventricular tachycardia (P < 0.01). This difference remained statistically significant even when patients with a left bundle branch block were excluded from the analysis (4 out of 6 vs 4 out of 30, P<0.01). To identify patients with dilated cardiomyopathy and sustained ventricular tachycardia, signal-averaging had a sensitivity of 80%, a specificity of 66%, a positive predictive value of 36% and a negative predictive value of 93%. It is concluded that, in non-ischaemic dilated cardiomyopathy, the signal-averaged electrocardiogram allows the identification of patients with sustained ventricular tachycardia, even in the presence of a left bundle branch bloc
Coherent Control for a Two-level System Coupled to Phonons
The interband polarizations induced by two phase-locked pulses in a
semiconductor show strong interference effects depending on the time tau_1
separating the pulses. The four-wave mixing signal diffracted from a third
pulse delayed by tau is coherently controlled by tuning tau_1. The four-wave
mixing response is evaluated exactly for a two-level system coupled to a single
LO phonon. In the weak coupling regime it shows oscillations with the phonon
frequency which turn into sharp peaks at multiples of the phonon period for a
larger coupling strength. Destructive interferences between the two
phase-locked pulses produce a splitting of the phonon peaks into a doublet. For
fixed tau but varying tau_1 the signal shows rapid oscillations at the
interband-transition frequency, whose amplitude exhibits bursts at multiples of
the phonon period.Comment: 4 pages, 4 figures, RevTex, content change
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