27,149 research outputs found

    Quasi-Orthogonal Configuration of Propylene within a Scalable Metal-Organic Framework Enables Its Purification from Quinary Propane Dehydrogenation Byproducts

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    [Image: see text] Propylene production via nonoxidative propane dehydrogenation (PDH) holds great promise in meeting growing global demand for propylene. Effective adsorptive purification of a low concentration of propylene from quinary PDH byproducts comprising methane (CH(4)), ethylene (C(2)H(4)), ethane (C(2)H(6)), propylene (C(3)H(6)), and propane (C(3)H(8)) has been an unsolved academic bottleneck. Herein, we now report an ultramicroporous zinc metal–organic framework (Zn-MOF, termed as 1) underlying a rigid one-dimensional channel, enabling trace C(3)H(6) capture and effective separation from quinary PDH byproducts. Adsorption isotherms of 1 suggest a record-high C(3)H(6) uptake of 34.0/92.4 cm(3) cm(–3) (0.01/0.1 bar) at 298 K. In situ spectroscopies, crystallographic experiments, and modeling have jointly elucidated that the outstanding propylene uptakes at lower pressure are dominated by multiple binding interactions and swift diffusion behavior, yielding quasi-orthogonal configuration of propylene in adaptive channels. Breakthrough tests demonstrate that 30.8 L of propylene with a serviceable purity of 95.0–99.4% can be accomplished from equimolar C(3)H(6)/C(3)H(8) mixtures for 1 kg of activated 1. Such an excellent property is also validated by the breakthrough tests of quinary mixtures containing CH(4)/C(2)H(4)/C(2)H(6)/C(3)H(6)/C(3)H(8) (3/5/6/42/44, v/v/v/v/v). Particularly, structurally stable 1 can be easily synthesized on the kilogram scale using cheap materials (only $167 for per kilogram of 1), which is important in industrial applications

    Ground state fidelity in bond-alternative Ising chains with Dzyaloshinskii-Moriya interactions

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    A systematic analysis is performed for quantum phase transitions in a bond-alternative one-dimensional Ising model with a Dzyaloshinskii-Moriya (DM) interaction by using the fidelity of ground state wave functions based on the infinite matrix product states algorithm. For an antiferromagnetic phase, the fidelity per lattice site exhibits a bifurcation, which shows spontaneous symmetry breaking in the system. A critical DM interaction is inversely proportional to an alternating exchange coupling strength for a quantum phase transition. Further, a finite-entanglement scaling of von Neumann entropy with respect to truncation dimensions gives a central charge c = 0.5 at the critical point.Comment: 6 pages, 4 figure

    Acclimation of morphology and physiology in turf grass to low light environment: A review

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    This short review elucidated the significance of the research on acclimation of the morphology and physiology in turf grass to low light environment, the mechanism of physiological response and the photosynthetic regulation and control of turf grass to suit low light environment. We also discussed current research problems and provided insight into future relevant research.Key words: Low light, morphological change, physiological acclimation, regulation mechanism, turf grass

    New solutions to the Reflection Equation and the projecting method

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    New integrable boundary conditions for integrable quantum systems can be constructed by tuning of scattering phases due to reflection at a boundary and an adjacent impurity and subsequent projection onto sub-spaces. We illustrate this mechanism by considering a gl(m<n)-impurity attached to an open gl(n)-invariant quantum chain and a Kondo spin S coupled to the supersymmetric t-J model.Comment: Latex2e, no figure

    Electromagnetic manipulation for anti-Zeno effect in an engineered quantum tunneling process

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    We investigate the quantum Zeno and anti-Zeno effects for the irreversible quantum tunneling from a quantum dot to a ring array of quantum dots. By modeling the total system with the Anderson-Fano-Lee model, it is found that the transition from the quantum Zeno effect to quantum anti-Zeno effect can happen as the magnetic flux and the gate voltage were adjusted.Comment: 6 pages, 5 figure

    Effects of a near-field rigid sphere scatterer on the performance of linear microphone array beamformers

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    © 2016 Acoustical Society of America. Beamformers enable a microphone array to capture acoustic signals from a sound source with high signal to noise ratio in a noisy environment, and the linear microphone array is of particular importance, in practice, due to its simplicity and easy implementation. A linear microphone array sometimes is used near some scattering objects, which affect its beamforming performance. This paper develops a numerical model with a linear microphone array near a rigid sphere for both far-field plane wave and near-field sources. The effects of the scatterer on two typical beamformers, i.e., the delay-and-sum beamformer and the superdirective beamformer, are investigated by both simulations and experiments. It is found that the directivity factor of both beamformers improves due to the increased equivalent array aperture when the size of the array is no larger than that of the scatter. With the increase of the array size, the directivity factor tends to deteriorate at high frequencies because of the rising side-lobes. When the array size is significantly larger than that of the scatterer, the scattering has hardly any influence on the beamforming performance
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