Laboratory photo-chemistry of pyrene clusters: an efficient way to form large PAHs

In this work, we study the photodissociation processes of small PAH clusters (e.g., pyrene clusters). The experiments are carried out using a quadrupole ion trap in combination with time-of-flight (QIT-TOF) mass spectrometry. The results show that pyrene clusters are converted into larger PAHs under the influence of a strong radiation field. Specifically, pyrene dimer cations (e.g., [C$_{16}$H$_{10}$$-$C$_{16}$H$_{9}$]$^+$ or C$_{32}$H$_{19}$$^+$), will photo-dehydrogenate and photo-isomerize to fully aromatic cations (PAHs) (e.g., C$_{32}$H$_{16}$$^+$) with laser irradiation. The structure of new formed PAHs and the dissociation energy for these reaction pathways are investigated with quantum chemical calculations. These studies provide a novel efficient evolution routes for the formation of large PAHs in the interstellar medium (ISM) in a bottom-up process that will counteract the top-down conversion of large PAHs into rings and chains, and provide a reservoir of large PAHs that can be converted into C$_{60}$ and other fullerenes and large carbon cages

Zero sound in a two-dimensional dipolar Fermi gas

We study zero sound in a weakly interacting 2D gas of single-component fermionic dipoles (polar molecules or atoms with a large magnetic moment) tilted with respect to the plane of their translational motion. It is shown that the propagation of zero sound is provided by both mean field and many-body (beyond mean field) effects, and the anisotropy of the sound velocity is the same as the one of the Fermi velocity. The damping of zero sound modes can be much slower than that of quasiparticle excitations of the same energy. One thus has wide possibilities for the observation of zero sound modes in experiments with 2D fermionic dipoles, although the zero sound peak in the structure function is very close to the particle-hole continuum.Comment: 15 pages, 2 figure

Strongly nonlinear waves in capillary electrophoresis

In capillary electrophoresis, sample ions migrate along a micro-capillary filled with a background electrolyte under the influence of an applied electric field. If the sample concentration is sufficiently high, the electrical conductivity in the sample zone could differ significantly from the background.Under such conditions, the local migration velocity of sample ions becomes concentration dependent resulting in a nonlinear wave that exhibits shock like features. If the nonlinearity is weak, the sample concentration profile, under certain simplifying assumptions, can be shown to obey Burgers' equation (S. Ghosal and Z. Chen Bull. Math. Biol. 2010, 72(8), pg. 2047) which has an exact analytical solution for arbitrary initial condition.In this paper, we use a numerical method to study the problem in the more general case where the sample concentration is not small in comparison to the concentration of background ions. In the case of low concentrations, the numerical results agree with the weakly nonlinear theory presented earlier, but at high concentrations, the wave evolves in a way that is qualitatively different.Comment: 7 pages, 5 figures, 1 Appendix, 2 videos (supplementary material

Stable dilute supersolid of two-dimensional dipolar bosons

We consider two-dimensional bosonic dipoles oriented perpendicularly to the plane. On top of the usual two-body contact and long-range dipolar interactions we add a contact three-body repulsion as expected, in particular, for dipoles in the bilayer geometry with tunneling. The three-body repulsion is crucial for stabilizing the system, and we show that our model allows for stable continuous space supersolid states in the dilute regime and calculate the zero-temperature phase diagram.Comment: revised version, 5 pages, 2 figures, with 3 pages supplementary materia

Effective SU(2)_L x U(1) theory and the Higgs boson mass

We assume the stability of vacuum under radiative corrections in the context of the standard electroweak theory. We find that this theory behaves as a good effective model already at cut off energy scales as low as 0.7 TeV. This stability criterion allows to predict m_H= 318 +- 13 GeV for the Higgs boson mass.Comment: Latex, 5 pages, 1 Postscript figure include